Book ChapterDOI
The Coordination and Bioinorganic Chemistry of Molybdenum
Edward I. Stiefel
- pp 1-223
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The article was published on 2007-03-09. It has received 78 citations till now. The article focuses on the topics: Bioorganometallic chemistry & Bioinorganic chemistry.read more
Citations
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Journal ArticleDOI
Molybdenum in natural waters: A review of occurrence, distributions and controls
TL;DR: The 2011 WHO Guidelines for Drinking-Water Quality (fourth edition) advised a health-based value of 70μg/L for Mo but this is no longer promulgated as a formal guideline value as WHO consider such concentrations to be rarely found in drinking water as discussed by the authors.
Journal ArticleDOI
Structure and Function of Xanthine Oxidoreductase
TL;DR: An overview of the current state of our understanding of the molybdenum-containing enzyme xanthine oxidoreductase is presented, with an emphasis on work done in the past five years.
Journal ArticleDOI
Synthetic approaches to the molybdenum sulfide materials
TL;DR: In this article, synthetic aspects of molybdenum sulfide-based materials were reviewed, with emphasis on the catalytic materials, and a number of preparation methods were critically compared, including molecular precursor decomposition, hydrothermal, soft chemistry aqueous, surfactant-aided, intercalation-exfoliation, and solid gas reactions.
Journal ArticleDOI
Reduction of Carbon Dioxide by a Molybdenum-Containing Formate Dehydrogenase: A Kinetic and Mechanistic Study.
TL;DR: The ability of Desulfovibrio desulfuricans formate dehydrogenase (DdFDH) to reduce carbon dioxide was kinetically and mechanistically characterized and a kinetic model of a hysteretic enzyme is proposed to interpret and predict the progress curves of the Dd FDH-catalyzed reactions.
Journal ArticleDOI
Synthesis and characterization of molybdenum complexes with bidentate Schiff base ligands within nanoreactors of MCM-41 as epoxidation catalysts
TL;DR: The mesoporous molecular sieve MCM-41 was covalently grafted with 3-aminopropyl trimethoxysilane (AmpMCM41) in this article.
References
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Journal ArticleDOI
Purification and Properties of Xanthine Dehydrogenase from Micrococcus lactilyticus
TL;DR: Observations of Xanthine dehydrogenase strengthen the hypothesis that molybdenum serves as a hydroxyl acceptor and donor in the normal catalytic function of molyBdo-iron-flavoproteins.
Book ChapterDOI
Hydride Complexes of the Transition Metals
Malcolm L. H. Green,D.J. Jones +1 more
TL;DR: In this paper, the physical properties of the metal-hydrogen bond are discussed, and the role of transition metal hydrides in homogeneous catalysis has also been discussed.
Journal ArticleDOI
Spectroscopic and magnetic properties of heptacyanomolybdate(III). Evidence for pentagonal-bipyramidal and monocapped trigonal-prismatic structures
TL;DR: In this paper, a pentagonal-bipyramidal (D_(Sh)) ground state for Mo(CN)_7^(4-) in aqueous solutions of K_4Mo(CN)-7•2H_2O was found.
Journal ArticleDOI
Ligand Hyperfine Interactions in Molybdenyl and Chromyl Halide Complexes
TL;DR: In this article, a configuration-interaction treatment has been used to account for the spin densities in the ligand px and s orbitals, revealing moderately strong inplane π bonding involving the metal dxy orbital and the ligands py orbital.