Book ChapterDOI
The Coordination and Bioinorganic Chemistry of Molybdenum
Edward I. Stiefel
- pp 1-223
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The article was published on 2007-03-09. It has received 78 citations till now. The article focuses on the topics: Bioorganometallic chemistry & Bioinorganic chemistry.read more
Citations
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Journal ArticleDOI
Molybdenum in natural waters: A review of occurrence, distributions and controls
TL;DR: The 2011 WHO Guidelines for Drinking-Water Quality (fourth edition) advised a health-based value of 70μg/L for Mo but this is no longer promulgated as a formal guideline value as WHO consider such concentrations to be rarely found in drinking water as discussed by the authors.
Journal ArticleDOI
Structure and Function of Xanthine Oxidoreductase
TL;DR: An overview of the current state of our understanding of the molybdenum-containing enzyme xanthine oxidoreductase is presented, with an emphasis on work done in the past five years.
Journal ArticleDOI
Synthetic approaches to the molybdenum sulfide materials
TL;DR: In this article, synthetic aspects of molybdenum sulfide-based materials were reviewed, with emphasis on the catalytic materials, and a number of preparation methods were critically compared, including molecular precursor decomposition, hydrothermal, soft chemistry aqueous, surfactant-aided, intercalation-exfoliation, and solid gas reactions.
Journal ArticleDOI
Reduction of Carbon Dioxide by a Molybdenum-Containing Formate Dehydrogenase: A Kinetic and Mechanistic Study.
TL;DR: The ability of Desulfovibrio desulfuricans formate dehydrogenase (DdFDH) to reduce carbon dioxide was kinetically and mechanistically characterized and a kinetic model of a hysteretic enzyme is proposed to interpret and predict the progress curves of the Dd FDH-catalyzed reactions.
Journal ArticleDOI
Synthesis and characterization of molybdenum complexes with bidentate Schiff base ligands within nanoreactors of MCM-41 as epoxidation catalysts
TL;DR: The mesoporous molecular sieve MCM-41 was covalently grafted with 3-aminopropyl trimethoxysilane (AmpMCM41) in this article.
References
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Journal ArticleDOI
Crystal and molecular structure of tetrachloro-di-µ3-oxo-tetra-µ-prop-oxo-tetraoxodipropoxotetramolybdenum(2MO–MO)
TL;DR: The triclinic tetramer of the title compound was determined from diffractometer X-ray data by Patterson and Fourier methods and refined by full-matrix least-squares techniques to R 0·063 for 1366 independent reflections as discussed by the authors.
Journal ArticleDOI
Halides and oxide halides of molybdenum and tungsten. III. Oxo-bridged species of tungsten(IV) and molybdenum(V)
TL;DR: The compound formulated in the literature as K2W(OH)Cl5 has been shown to be the oxo-bridged dimer K4[WT2Ocl10], and the diamagnetic dimer formed by the partial hydrolysis of the Mo2O3Cl8]4 ion has been isolated for the first time as mentioned in this paper.
Journal ArticleDOI
Reductive nitrosation of molybdenum and tungsten halides II. One-stage synthesis of phosphine oxide substituted mononitrosyltrichloro-, and dinitrosyldichloro-molybdenum derivatives
TL;DR: The reductive nitrosation of MoCl5 with NO in the presence of PPh3 in CH2Cl2 solution gives Mo(NO)Cl3 (OPPh3)2 as an intermediate and Mo( NO)2 Cl2(OPPh 3)2·2C6H6 as discussed by the authors.
Journal ArticleDOI
CO2 reductase from Clostridium pasteurianum: molybdenum dependence of synthesis and inactivation by cyanide.
TL;DR: Evidence is presented indicating that the CO 2 reductase from CI.