Book ChapterDOI
The Coordination and Bioinorganic Chemistry of Molybdenum
Edward I. Stiefel
- pp 1-223
About:
The article was published on 2007-03-09. It has received 78 citations till now. The article focuses on the topics: Bioorganometallic chemistry & Bioinorganic chemistry.read more
Citations
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Journal ArticleDOI
Molybdenum in natural waters: A review of occurrence, distributions and controls
TL;DR: The 2011 WHO Guidelines for Drinking-Water Quality (fourth edition) advised a health-based value of 70μg/L for Mo but this is no longer promulgated as a formal guideline value as WHO consider such concentrations to be rarely found in drinking water as discussed by the authors.
Journal ArticleDOI
Structure and Function of Xanthine Oxidoreductase
TL;DR: An overview of the current state of our understanding of the molybdenum-containing enzyme xanthine oxidoreductase is presented, with an emphasis on work done in the past five years.
Journal ArticleDOI
Synthetic approaches to the molybdenum sulfide materials
TL;DR: In this article, synthetic aspects of molybdenum sulfide-based materials were reviewed, with emphasis on the catalytic materials, and a number of preparation methods were critically compared, including molecular precursor decomposition, hydrothermal, soft chemistry aqueous, surfactant-aided, intercalation-exfoliation, and solid gas reactions.
Journal ArticleDOI
Reduction of Carbon Dioxide by a Molybdenum-Containing Formate Dehydrogenase: A Kinetic and Mechanistic Study.
TL;DR: The ability of Desulfovibrio desulfuricans formate dehydrogenase (DdFDH) to reduce carbon dioxide was kinetically and mechanistically characterized and a kinetic model of a hysteretic enzyme is proposed to interpret and predict the progress curves of the Dd FDH-catalyzed reactions.
Journal ArticleDOI
Synthesis and characterization of molybdenum complexes with bidentate Schiff base ligands within nanoreactors of MCM-41 as epoxidation catalysts
TL;DR: The mesoporous molecular sieve MCM-41 was covalently grafted with 3-aminopropyl trimethoxysilane (AmpMCM41) in this article.
References
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Journal ArticleDOI
Nuclear magnetic resonance studies of 8-quinolinol complexes of molybdenum(VI.V) and of vanadium(V), as models for molybdenum-flavin interactions
Larry W. Amos,Donald T. Sawyer +1 more
On the structure and function of nitrogen'ase from clostridium pasteurianum w5
TL;DR: Native MoFd is a tetramer composed of two 50,000 and two 60,000 dalton subunits and at low protein concentrations the tetramer is in equilibrium with a dimer and under low ionic strength and atLow pH further dissociation into monomers occurs.
Journal ArticleDOI
The hydrogenase of clostridium pasteurianum kinetic studies and the role of molybdenum
D. Kleiner,Robert H. Burris +1 more
TL;DR: Partially purified hydrogenase from Clostridium pasteurianum was used for kinetic studies and investigations of its activation by molybdenum, suggesting that hydrogenase has separate sites for the activation of H2 and for activation of the electron carrier, and that moly bdenum is loosely bound to the carrier site.