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The Coordination and Bioinorganic Chemistry of Molybdenum

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The article was published on 2007-03-09. It has received 78 citations till now. The article focuses on the topics: Bioorganometallic chemistry & Bioinorganic chemistry.

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Journal ArticleDOI

Molybdenum in natural waters: A review of occurrence, distributions and controls

TL;DR: The 2011 WHO Guidelines for Drinking-Water Quality (fourth edition) advised a health-based value of 70μg/L for Mo but this is no longer promulgated as a formal guideline value as WHO consider such concentrations to be rarely found in drinking water as discussed by the authors.
Journal ArticleDOI

Structure and Function of Xanthine Oxidoreductase

TL;DR: An overview of the current state of our understanding of the molybdenum-containing enzyme xanthine oxidoreductase is presented, with an emphasis on work done in the past five years.
Journal ArticleDOI

Synthetic approaches to the molybdenum sulfide materials

TL;DR: In this article, synthetic aspects of molybdenum sulfide-based materials were reviewed, with emphasis on the catalytic materials, and a number of preparation methods were critically compared, including molecular precursor decomposition, hydrothermal, soft chemistry aqueous, surfactant-aided, intercalation-exfoliation, and solid gas reactions.
Journal ArticleDOI

Reduction of Carbon Dioxide by a Molybdenum-Containing Formate Dehydrogenase: A Kinetic and Mechanistic Study.

TL;DR: The ability of Desulfovibrio desulfuricans formate dehydrogenase (DdFDH) to reduce carbon dioxide was kinetically and mechanistically characterized and a kinetic model of a hysteretic enzyme is proposed to interpret and predict the progress curves of the Dd FDH-catalyzed reactions.
Journal ArticleDOI

Synthesis and characterization of molybdenum complexes with bidentate Schiff base ligands within nanoreactors of MCM-41 as epoxidation catalysts

TL;DR: The mesoporous molecular sieve MCM-41 was covalently grafted with 3-aminopropyl trimethoxysilane (AmpMCM41) in this article.
References
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Journal ArticleDOI

The Synthesis of Di-μ-thio-dithio-bis (dialkyldithiocarbamates) Dimolybdenum (V) and Their Effects on Boundary Lubrication

TL;DR: In this article, the mechanism of pyrolysis of molybdenum disulfide crystals was investigated, and a new compound, the analytical result of which showed (R2NCSS)2Mo2S4 (where R=ethyl, isopropyl, n-butyl, and isobutyl), was obtained by phosphorus pentasulfide treatment of a xylene solution of sulfurized moly bdenum dialkyldithiocarbamate.
Journal ArticleDOI

Stereochemical Control of Valence and Its Application to the Reduction of Coordinated NO and N(2).

TL;DR: Evidence indicates that complexes of (NO)(+) and N(2) are electronically similar, and the principles of stereochemical control of valence may be applied to metal complexes of N( 2).
Journal ArticleDOI

Die Kristallstruktur von Molybdännitridchlorid, MoNCI3

TL;DR: MoNCl3 as mentioned in this paper is a triklinic space group PI with 4 formula units per unit cell, the lattice constants being a = 9.14, b = 7.67, c = 8.15 A, α = 108.8°, β = 99.3° and γ = 0.6°.
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