Book ChapterDOI
The Coordination and Bioinorganic Chemistry of Molybdenum
Edward I. Stiefel
- pp 1-223
About:
The article was published on 2007-03-09. It has received 78 citations till now. The article focuses on the topics: Bioorganometallic chemistry & Bioinorganic chemistry.read more
Citations
More filters
Journal ArticleDOI
Synthesis and Characterizations of Dinuclear Dioxomolybdenum(VI) Complexes with Thiocarbohydrazides of Salicylaldehyde, Bridged by 4,4'-Dipyridyl or Its Derivatives
TL;DR: The tauto-merism of these ligands as well as the tendency of sulfur donors to act as bridging ligands allows various structural possibilities for the corresponding metal complexes.
Journal ArticleDOI
Synthesis and Characterization of New Diorganotin(IV) Complexes with Dithiocarbamate Derivative of Glycine
Tahereh Sedaghat,Karam Goodarzi +1 more
TL;DR: The first organotin IV complexes were synthesized by reaction of SnR 2 Cl 2 (R = Me or Bu) with the dithiocarbamate derivative of glycine (dtc-gly) as mentioned in this paper.
Journal ArticleDOI
Molybdenum(V) complexes with formate: Geometric isomerism of the [Mo2O4Cl2(Py)2(HCOO)]− ion
Barbara Modec,Darko Dolenc +1 more
TL;DR: In this paper, the stability of the [Mo2O4Cl2(Py)2(HCOO)]− ion was analyzed and it was shown that the pyridine ligands on each metal ion are either trans or cis to each other.
Journal ArticleDOI
Oxidative cleavage of 3-phenyllactic acid in presence of molybdenum complexes
Barbara Modec,Darko Dolenc +1 more
TL;DR: In this paper, Molybdenum(V) starting material, (PyH)5[MoVOCl4(H2O)]3Cl2, reacted in acetonitrile with 3-phenyllactic acid (2-hydroxy-3-phenylpropanoic acid) in the presence of tetraphenylphosphonium counterions to {(C6H5)4P}2[(MoVIO2Cl2)2(C2O4)] (C 2O42−−= oxalate
Journal ArticleDOI
Oxidative route to polyoxomolybdates from quadruply bonded [MoIIMoII] precursor: Structural characterization of a tetranuclear cluster [Mo4Cl5O8(pyNP)2] (pyNP = (2-(2-pyridyl)1,8-naphthyridine))
TL;DR: In this paper, the tetranuclear molybdenum cluster [Mo4Cl5O8(pyNP)2] is described as a compound with a molecular structure of [Mo2Cl3O2Cl2(μ2-O)(η3-pyNP), the fusion of two oxochlorodimolybdates linked through a μ3-oxo linkage.
References
More filters
Journal ArticleDOI
Hard and soft acids and bases
TL;DR: In this paper, the rate data for the generalized nucleophilic displacement reaction were reviewed, and the authors presented a method to estimate the rate of the generalized displacement reaction in terms of the number of nucleophiles.
Journal ArticleDOI
Principles of structure, bonding, and reactivity for metal nitrosyl complexes
Journal ArticleDOI
The relative affinities of ligand atoms for acceptor molecules and ions
Journal ArticleDOI
Alkyl and aryl derivatives of π-cyclopentadienyl compounds of chromium, molybdenum, tungsten, and iron
T.S. Piper,G. Wilkinson +1 more
TL;DR: In this article, the preparation of alkyl and aryl π-cyclopentadienyl carbon monoxide or nitric oxide compounds of Cr, Mo, W, and Fe is described.