Showing papers on "Nanosphere lithography published in 2018"

Palladium-Decorated Silicon Nanomesh Fabricated by Nanosphere Lithography for High Performance, Room Temperature Hydrogen Sensing.

Abstract: A hydrogen (H2 ) gas sensor based on a silicon (Si) nanomesh structure decorated with palladium (Pd) nanoparticles is fabricated via polystyrene nanosphere lithography and top-down fabrication processes. The gas sensor shows dramatically improved H2 gas sensitivity compared with an Si thin film sensor without nanopatterns. Furthermore, a buffered oxide etchant treatment of the Si nanomesh structure results in an additional performance improvement. The final sensor device shows fast H2 response and high selectivity to H2 gas among other gases. The sensing performance is stable and shows repeatable responses in both dry and high humidity ambient environments. The sensor also shows high stability without noticeable performance degradation after one month. This approach allows the facile fabrication of high performance H2 sensors via a cost-effective, complementary metal-oxide-semiconductor (CMOS) compatible, and scalable nanopatterning method.

Nanosphere Lithography on Fiber: Towards Engineered Lab-On-Fiber SERS Optrodes

Abstract: In this paper we report on the engineering of repeatable surface enhanced Raman scattering (SERS) optical fiber sensor devices (optrodes), as realized through nanosphere lithography. The Lab-on-Fiber SERS optrode consists of polystyrene nanospheres in a close-packed arrays configuration covered by a thin film of gold on the optical fiber tip. The SERS surfaces were fabricated by using a nanosphere lithography approach that is already demonstrated as able to produce highly repeatable patterns on the fiber tip. In order to engineer and optimize the SERS probes, we first evaluated and compared the SERS performances in terms of Enhancement Factor (EF) pertaining to different patterns with different nanosphere diameters and gold thicknesses. To this aim, the EF of SERS surfaces with a pitch of 500, 750 and 1000 nm, and gold films of 20, 30 and 40 nm have been retrieved, adopting the SERS signal of a monolayer of biphenyl-4-thiol (BPT) as a reliable benchmark. The analysis allowed us to identify of the most promising SERS platform: for the samples with nanospheres diameter of 500 nm and gold thickness of 30 nm, we measured values of EF of 4 × 105, which is comparable with state-of-the-art SERS EF achievable with highly performing colloidal gold nanoparticles. The reproducibility of the SERS enhancement was thoroughly evaluated. In particular, the SERS intensity revealed intra-sample (i.e., between different spatial regions of a selected substrate) and inter-sample (i.e., between regions of different substrates) repeatability, with a relative standard deviation lower than 9 and 15%, respectively. Finally, in order to determine the most suitable optical fiber probe, in terms of excitation/collection efficiency and Raman background, we selected several commercially available optical fibers and tested them with a BPT solution used as benchmark. A fiber probe with a pure silica core of 200 µm diameter and high numerical aperture (i.e., 0.5) was found to be the most promising fiber platform, providing the best trade-off between high excitation/collection efficiency and low background. This work, thus, poses the basis for realizing reproducible and engineered Lab-on-Fiber SERS optrodes for in-situ trace detection directed toward highly advanced in vivo sensing.

Controlled Evaluation of the Impacts of Surface Coatings on Silver Nanoparticle Dissolution Rates.

Abstract: Silver nanoparticles (AgNPs) are increasingly being incorporated into a range of consumer products and as such there is significant potential for the environmental release of either the AgNPs themselves or Ag+ ions. When AgNPs are exposed to environmental systems, the engineered surface coating can potentially be displaced or covered by naturally abundant macromolecules. These capping agents, either engineered or incidental, potentially block reactants from surface sites and can alter nanoparticle transformation rates. We studied how surface functionalization affects the dissolution of uniform arrays of AgNPs fabricated by nanosphere lithography (NSL). Bovine serum albumin (BSA) and two molecular weights of thiolated polyethylene glycol (PEG; 1000 and 5000 Da) were tested as model capping agents. Dissolution experiments were conducted in air-saturated phosphate buffer containing 550 mM NaCl. Tapping-mode atomic force microscopy (AFM) was used to measure changes in AgNP height over time. The measured disso...

Hierarchical CdS Nanorod@SnO2 Nanobowl Arrays for Efficient and Stable Photoelectrochemical Hydrogen Generation.

Abstract: An efficient photoanode based on CdS nanorod@SnO2 nanobowl (CdS NR@SnO2 NB) arrays is designed and fabricated by the preparation of SnO2 nanobowl arrays via nanosphere lithography followed by hydrothermal growth of CdS nanorods on the inner surface of the SnO2 nanobowls. A photoelectrochemical (PEC) device constructed by using this hierarchical CdS NR@SnO2 NB photoanode presents significantly enhanced performance with a photocurrent density of 3.8 mA cm-2 at 1.23 V versus a reversible hydrogen electrode (RHE) under AM1.5G solar light irradiation, which is about 2.5 times higher than that of CdS nanorod arrays. After coating with a thin layer of SiO2 , the photostability of the CdS NR@SnO2 NB arrays is greatly enhanced, resulting in a stable photoanode with a photocurrent density of 3.0 mA cm-2 retained at 1.23 V versus the RHE. The much improved performance of the CdS NR@SnO2 NB arrays toward PEC hydrogen generation can be ascribed to enlarged surface area arising from the hierarchical nanostructures, improved light harvesting owing to the NR@NB architecture containing multiple scattering centers, and enhanced charge separation/collection efficiency due to the favorable CdS-SnO2 heterojunction.

Influence of the long-range ordering of gold-coated Si nanowires on SERS

Abstract: Controlling the location and the distribution of hot spots is a crucial aspect in the fabrication of surface-enhanced Raman spectroscopy (SERS) substrates for bio-analytical applications. The choice of a suitable method to tailor the dimensions and the position of plasmonic nanostructures becomes fundamental to provide SERS substrates with significant signal enhancement, homogeneity and reproducibility. In the present work, we studied the influence of the long-range ordering of different flexible gold-coated Si nanowires arrays on the SERS activity. The substrates are made by nanosphere lithography and metal-assisted chemical etching. The degree of order is quantitatively evaluated through the correlation length (ξ) as a function of the nanosphere spin-coating speed. Our findings showed a linear increase of the SERS signal for increasing values of ξ, coherently with a more ordered and dense distribution of hot spots on the surface. The substrate with the largest ξ of 1100 nm showed an enhancement factor of 2.6 · 103 and remarkable homogeneity over square-millimetres area. The variability of the signal across the substrate was also investigated by means of a 2D chemical imaging approach and a standard methodology for its practical calculation is proposed for a coherent comparison among the data reported in literature.

Hierarchical nanopores formed by block copolymer lithography on the surfaces of different materials pre-patterned by nanosphere lithography

Abstract: Bottom-up patterning techniques allow for the creation of surfaces with ordered arrays of nanoscale features on large areas. Two bottom-up techniques suitable for the formation of regular nanopatterns on different length scales are nanosphere lithography (NSL) and block copolymer (BCP) lithography. In this paper it is shown that NSL and BCP lithography can be combined to easily design hierarchically nanopatterned surfaces of different materials. Nanosphere lithography is used for the pre-patterning of surfaces with antidots, i.e. hexagonally arranged cylindrical holes in thin films of Au, Pt and TiO2 on SiO2, providing a periodic chemical and topographical contrast on the surface suitable for templating in subsequent BCP lithography. PS-b-PMMA BCP is used in the second self-assembly step to form hexagonally arranged nanopores with sub-20 nm diameter within the antidots upon microphase separation. To achieve this the microphase separation of BCP on planar surfaces is studied, too, and it is demonstrated for the first time that vertical BCP nanopores can be formed on TiO2, Au and Pt films without using any neutralization layers. To explain this the influence of surface energy, polarity and roughness on the microphase separation is investigated and discussed along with the wetting state of BCP on NSL-pre-patterned surfaces. The presented novel route for the creation of advanced hierarchical nanopatterns is easily applicable on large-area surfaces of different materials. This flexibility makes it suitable for a broad range of applications, from the morphological design of biocompatible surfaces for life science to complex pre-patterns for nanoparticle placement in semiconductor technology.

Hollow spheres: crucial building blocks for novel nanostructures and nanophotonics

Abstract: Abstract In this review, we summarize the latest developments in research specifically derived from the unique properties of hollow microspheres, in particular, hollow silica spheres with uniform shells. We focus on applications in nanosphere (colloidal) lithography and nanophotonics. The lithography from a layer of hollow spheres can result in nanorings, from a multilayer in unique nano-architecture. In nanophotonics, disordered hollow spheres can result in antireflection coatings, while ordered colloidal crystals (CCs) of hollow spheres exhibit unique refractive index enhancement upon infiltration, ideal for optical sensing. Furthermore, whispering gallery mode (WGM) inside the shell of hollow spheres has also been demonstrated to enhance light absorption to improve the performance of solar cells. These applications differ from the classical applications of hollow spheres, based only on their low density and large surface area, such as catalysis and chemical sensing. We provide a brief overview of the synthesis and self-assembly approaches of the hollow spheres. We elaborate on their unique optical features leading to defect mode lasing, optomicrofluidics, and the existence of WGMs inside shell for light management. Finally, we provide a perspective on the direction towards which future research relevant to hollow spheres might be directed.

Optical properties of ZnO deposited by atomic layer deposition (ALD) on Si nanowires

Abstract: In this work, we report proof-of-concept results on the synthesis of Si core/ ZnO shell nanowires (SiNWs/ZnO) by combining nanosphere lithography (NSL), metal assisted chemical etching (MACE) and atomic layer deposition (ALD). The structural properties of the SiNWs/ZnO nanostructures prepared were investigated by X-ray diffraction, Raman spectroscopy, scanning and transmission electron microscopies. The X-ray diffraction analysis revealed that all samples have a hexagonal wurtzite structure. The grain sizes are found to be in the range of 7–14 nm. The optical properties of the samples were investigated using reflectance and photoluminescence spectroscopy. The study of photoluminescence (PL) spectra of SiNWs/ZnO samples showed the domination of defect emission bands, pointing to deviations of the stoichiometry of the prepared 3D ZnO nanostructures. Reduction of the PL intensity of the SiNWs/ZnO with the increase of SiNWs etching time was observed, depicting an advanced light scattering with the increase of the nanowire length. These results open up new prospects for the design of electronic and sensing devices.

Structurally tunable plasmonic absorption bands in a self-assembled nano-hole array

Abstract: In this paper, we demonstrate a theoretical and experimental study on a nano-hole array that can realize perfect absorption in the visible and near-infrared regions. The absorption spectrum can be easily controlled by adjusting the structural parameters including the radius and period of the nano-hole, and the maximal absorption can reach 99.0% in theory. In order to clarify the physical mechanism of the absorber, we start from the extraordinary optical transmission supported by the nano-hole array in a thin metallic film coated on a glass substrate, and then analyse the perfect absorption in the metal-insulator-metal structure. The surface plasmon modes supported by the nano-hole array are completely clarified and both the FDTD simulation and waveguide theory are used to help us understand the physical mechanism, which can provide a new perspective in designing this kind of perfect absorber. In addition, the nano-hole array can be fabricated by simple and low-cost nanosphere lithography, which makes it a more appropriate candidate for spectroscopy, photovoltaics, photodetectors, sensing, and surface enhanced Raman scattering.

On the Adsorption of DNA Origami Nanostructures in Nanohole Arrays

Abstract: DNA origami nanostructures are versatile substrates for the controlled arrangement of molecular capture sites with nanometer precision and thus have many promising applications in single-molecule bioanalysis. Here, we investigate the adsorption of DNA origami nanostructures in nanohole arrays which represent an important class of biosensors and may benefit from the incorporation of DNA origami-based molecular probes. Nanoholes with well-defined diameter that enable the adsorption of single DNA origami triangles are fabricated in Au films on Si wafers by nanosphere lithography. The efficiency of directed DNA origami adsorption on the exposed SiO2 areas at the bottoms of the nanoholes is evaluated in dependence of various parameters, i.e., Mg2+ and DNA origami concentrations, buffer strength, adsorption time, and nanohole diameter. We observe that the buffer strength has a surprisingly strong effect on DNA origami adsorption in the nanoholes and that multiple DNA origami triangles with 120 nm edge length ca...

Localised detection of thiophenol with gold nanotriangles highly structured as honeycombs by nonlinear sum frequency generation spectroscopy

Abstract: Gold nanotriangles structured as honeycombs and fabricated by nanosphere lithography on a gold film are functionalised by thiophenol molecules in order to be used as plasmonic sensors in nonlinear optical sum frequency generation (SFG) spectroscopy. The monitoring and the characterisation of the surface optical properties are performed by UV–visible differential reflectance spectroscopy showing an absorbance maximum located at 540 nm for p- and s-polarisation beams. SFG spectroscopy proves to be effective for thiophenol detection in ssp-polarisation scheme, while the molecular SFG signal disappears in ppp-configuration due to the strong s–d interband contribution of gold. However, in ssp-configuration, the vibration modes of thiophenol molecules at 3050 and 3071 $${\hbox {cm}}^{-1}$$ are yet observed thanks to the excitation of a transversal plasmon mode by the incident visible laser beam, whereas they are usually very difficult to distinguish by surface-enhanced Raman scattering and other vibrational optical probes.

Localized Surface Plasmonic Resonance and Sensing Properties of Ag–MgF2 Composite Nanotriangles

Abstract: Regular nanotriangular (NT) patterns and thin films composed of a mixture of Ag and MgF2 with different composition ratios are prepared by combining nanosphere lithography and electron beam codeposition. The plasmonic property of Ag–MgF2 composites with a high Ag composition CAg (≥90 at. %) are shown to be a function of CAg as well as the size of the NTs, whereas for samples with low CAg (<90 at. %), a nearly constant localized surface plasmon resonance (LSPR) peak appears in all samples, regardless of CAg, NT size, or thin film, which is confirmed to be because of Ag nanoparticles formed during the deposition. Thus, the LSPR property of the composite NTs can be tuned by CAg when CAg ≥ 90 at. %. The resulting LSPR sensor at CAg = 90 at. % with 500 nm diameter polystyrene nanosphere monolayer can achieve a sensitivity of 696 RIU/nm, as compared to 312 RIU/nm for the same NTs with pure Ag. This significantly improved sensitivity is due to the modified dispersion relationship of the dielectric constant by th...

Polystyrene nanoparticle-templated hollow titania nanosphere monolayers as ordered scaffolds

Abstract: We report a novel multi-step method for the preparation of ordered mesoporous titania scaffolds and show an illustrative example of their application to solar cells. The method is based on (monolayer) colloidal nanosphere lithography that makes use of polystyrene nanoparticles organised at a water–air interface and subsequently transferred onto a solid substrate. A titania precursor solution (titanium(IV) isopropoxide in ethanol) is then drop-cast onto the monolayer and left to “incubate” overnight. Surprisingly, instead of the expected inverse monolayer-structure, a subsequent calcination step of the precursor yields an ordered monolayer of hollow titania nanospheres with a wall thickness of ∼30–50 nm, and a slightly larger diameter than that of the starting spheres. X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) characterization of such scaffolds confirm that they consist of nanocrystalline anatase titania, and that any polystyrene/carbon residues in the scaffolds are below the XPS detection level. As an illustrative application we prepared perovskite solar cells incorporating the templated-nanoparticle scaffolds displaying a respectable power conversion efficiency of ∼9%, twice as large as that of our unoptimized “reference” cells (i.e. incorporating conventional mesoporous or compact titania scaffolds), thereby also demonstrating that the process is relatively robust with respect to optimization of the process parameters.

Tailoring Optical Properties of a Large-Area Plasmonic Gold Nanoring Array Pattern

Abstract: A new fabrication route, which combines nanosphere lithography with silicon-based clean-room microfabrication processes, has been developed to produce large-area long-range ordered gold nanoring array patterns in a controllable fashion. Both the experimentation and the finite-difference time-domain (FDTD) simulation show that the surface plasmon resonance peak (SPR) of the nanoring array pattern can be tuned systematically in a large spectral range by varying the geometry parameters such as the ring thickness, the ring height, the ringer outer diameter, and the gap between neighboring rings. For the Au nanoring arrays with a large gap in the absence of plasmon coupling between neighboring rings, the local electromagnetic (EM) field enhancement occurs at both the outer and inner surfaces of individual nanorings; and the periodicity of Au nanoring array has no any effect on the plasmonic properties. For the Au nanoring arrays with a small gap, plasmon coupling takes place between neighboring rings. As a res...

Surface plasmon modes of nanomesh-on-mirror nanocavities prepared by nanosphere lithography.

Abstract: Metal–insulator–metal (MIM) structures show great potential for numerous photonic applications due to their ability to confine light energy to volumes with deeply sub-wavelength dimensions. Here, MIM structures comprising hexagonal gold nanohole arrays were prepared by nanosphere lithography. Angle-resolved UV-vis-NIR spectroscopy revealed a series of narrow, dispersive and non-dispersive modes, which were attributed to the excitation of surface plasmon polariton (SPP) modes. Applying finite-difference time-domain (FDTD) simulations and analytical diffraction phase-matching theory all resonances can be ascribed to only two SPP modes traveling at the outer gold surface and in the gap layer sandwiched between two metal films. Metamaterial resonances, as reported in the literature for similar structures, are not needed to fully explain the reflectance spectra. Bragg scattering of the symmetric gap SPP mode results in a gap resonance, which is insensitive to the angle of incidence over a broad angular range. The spectral position of this flat band can be controlled by tuning the grating period of the nanohole array as well as the thickness and the refractive index of the dielectric gap.

Enhanced photoelectrochemical water splitting of BiVO4 photonic crystal photoanode by decorating with MoS2 nanosheets

Abstract: Bismuth vanadate (BiVO4) has been considered as one of the promising Photoelectrochemical (PEC) photoanode materials. However, the performances remain poorly rated due to inefficient carrier separation, short carrier diffusion length, and sluggish water oxidation kinetics. Herein, a photoanode consisting of MoS2 nanosheet coating on the three-dimensional ordered BiVO4 inverse opal is fabricated by a facile combination of nanosphere lithography and hydrothermal methods. By taking advantage of the photonic crystal and two-dimensional material, the optimized MoS2/BiVO4 inverse opal photoanode exhibits a 560% improvement of the photocurrent density and threefold enhancement of the incident photon-to-current efficiency than that of the pristine BiVO4 film photoanode. Systematic studies reveal that the excellent PEC activity should be attributed to enhanced light harvesting and charge separation efficiency.

Novel Nanofabricated Mo Field-Emitter Array for Low-Cost and Large-Area Application

Abstract: This paper demonstrates a novel nanofabrication technology for producing high-density gated molybdenum (Mo) field-emitter array (FEA) based on modified nanosphere lithography (NSL). The arc-shaped side wall of gate apertures introduced by the conventional NSL process put obstacles in the formation of sharp cone-type emitters. In this paper, a two-method solution was employed to facilitate the realization of gate apertures with sharper cutting side wall which are beneficial for the formation of sharper gated Mo emitters. One method was softening nanosphere to enlarge the contact area between nanosphere and substrate. The other was optimizing gate film deposition conditions to dramatically reduce the diffraction effects. Due to the improvements in the geometrical shape of gated Mo emitters, a low-voltage working high-density gated Mo FEA was demonstrated in this paper. This is the first observation of remarkable electron emission from high-density gated Mo FEA fabricated using such as low-cost, high-throughput, and high-efficiency technique which is expected to substantially overcome the challenges in the traditional fabrication process and promotes the low-cost and large-area application of high-density gated field-emitter devices. In addition, the novel nanofabricating method is expected to offer a simple and scalable route which allows fabrication of many gated field-emission devices.

Effect of ribbon width on electrical transport properties of graphene nanoribbons

Abstract: There has been growing interest in developing nanoelectronic devices based on graphene because of its superior electrical properties. In particular, patterning graphene into a nanoribbon can open a bandgap that can be tuned by changing the ribbon width, imparting semiconducting properties. In this study, we report the effect of ribbon width on electrical transport properties of graphene nanoribbons (GNRs). Monolayer graphene sheets and Si nanowires (NWs) were prepared by chemical vapor deposition and a combination of nanosphere lithography and metal-assisted electroless etching from a Si wafer, respectively. Back-gated GNR field-effect transistors were fabricated on a heavily p-doped Si substrate coated with a 300 nm-thick SiO2 layer, by O2 reactive ion etching of graphene sheets using etch masks based on Si NWs aligned on the graphene between the two electrodes by a dielectrophoresis method. This resulted in GNRs with various widths in a highly controllable manner, where the on/off current ratio was inversely proportional to ribbon width. The field-effect mobility decreased with decreasing GNR widths due to carrier scattering at the GNR edges. These results demonstrate the formation of a bandgap in GNRs due to enhanced carrier confinement in the transverse direction and edge effects when the GNR width is reduced.

Interplay of Nanoparticle Resonance Frequency and Array Surface Coverage in Live-Cell Plasmon-Enhanced Single-Molecule Imaging

Abstract: Super-resolution imaging has provided new insights into nanoscale optics. Plasmonic gold nanotriangle arrays created by nanosphere lithography can enhance single-molecule fluorescence intensity to further improve imaging. Here, gold nanotriangle arrays on glass coverslips were used as inexpensive, facile, and broadly applicable imaging substrates for living Vibrio cholerae cells expressing photoactivatable fluorescent proteins—the red PAmCherry or the green PAGFP—and resulted in fluorescence enhancements upon coupling living cells to nanotriangle arrays. Within the requirements for this wide-field coupling geometry, we analyze and optimize the coupling as a function of local surface plasmon resonance frequency and particle coverage.

Silver films over silica microspheres (AgFOSM) as SERS substrates

Abstract: Through the years, nanosphere lithography (NSL) has attracted a growing interest because of its potential to manufacture a wide variety of homogeneous arrays of nanostructures. In this work, NSL was used for the fabrication of Surface-Enhanced Raman Spectroscopy (SERS) substrates. The proposed Raman-SERS substrates consist of 50 nm or 120 nm thick silver thin films evaporated over a monolayer of silica microspheres (AgFOSM) onto silicon or quartz substrates. The samples were tested as SERS substrates using Rhodamine 6G as analyte. As a comparison and to determine the Raman enhancement factor, not only the AgFOSM samples were measured, but also we studied similar samples obtained when the Ag film is directly deposited onto the silicon or quartz substrate. Our results show that the R6G Raman signal is always more intense by two or three orders of magnitude for the AgFOSM samples than for the Ag maskless ones. In the case of the 120 nm thick Ag films, the calculated enhancement factors for the AgFOSM samples are of the order of 10 4 for both silicon and quartz substrates.

Nanosphere Lithography of Chitin and Chitosan with Colloidal and Self-Masking Patterning.

Abstract: Complex surface topographies control, define, and determine the properties of insect cuticles. In some cases, these nanostructured materials are a direct extension of chitin-based cuticles. The cellular mechanisms that generate these elaborate chitin-based structures are unknown, and involve complicated cellular and biochemical "bottom-up" processes. We demonstrated that a synthetic "top-down" fabrication technique-nanosphere lithography-generates surfaces of chitin or chitosan that mimic the arrangement of nanostructures found on the surface of certain insect wings and eyes. Chitin and chitosan are flexible and biocompatible abundant natural polymers, and are a sustainable resource. The fabrication of nanostructured chitin and chitosan materials enables the development of new biopolymer materials. Finally, we demonstrated that another property of chitin and chitosan-the ability to self-assemble nanosilver particles-enables a novel and powerful new tool for the nanosphere lithographic method: the ability to generate a self-masking thin film. The scalability of the nanosphere lithographic technique is a major limitation; however, the silver nanoparticle self-masking enables a one-step thin-film cast or masking process, which can be used to generate nanostructured surfaces over a wide range of surfaces and areas.

Easily Accessible Protein Nanostructures via Enzyme Mediated Addressing.

Abstract: Site-specific formation of nanoscaled protein structures is a challenging task. Most known structuring methods are either complex and hardly upscalable or do not apply to biological matter at all. The presented combination of enzyme mediated autodeposition and nanosphere lithography provides an easy-to-apply approach for the buildup of protein nanostructures over a large scale. The key factor is the tethering of enzyme to the support in designated areas. Those areas are provided via prepatterning of enzymatically active antidots with variable diameters. Enzymatically triggered protein addressing occurs exclusively at the intended areas and continues until the entire active area is coated. After this, the reaction self-terminates. The major advantage of the presented method lies in its easy applicability and upscalability. Large-area structuring of entire support surfaces with features on the nanometer scale is performed efficiently and without the necessity of harsh conditions. These are valuable premises...

Surface plasmons excited from close-packed nanoring tube arrays produced by nanosphere lithography

Abstract: Two-dimensional (2D) periodical close-packed nanoring tube arrays (RTAs) composed of metal and dielectric materials with unique surface plasmon properties have been investigated. A new fabrication route, which uses conventional semiconductor fabrication methods, has been developed to produce large-area highly ordered close-packed RTAs in a controllable and inexpensive way. Optical properties of this structure, as well as its replica, are investigated by both the finite-difference-time-domain (FDTD) algorithm and experiments. The simulation results show that both BW-SPP modes and coupled cavity modes at separate wavelengths are excited in RTAs, in accordance with experimental results. These modes are dependent on the geometry of RTAs. Ag RTAs with high absorption over the visible and near IR range has been experimentally demonstrated, which can be used in solar cells and as chemical/biological sensors with miniature size. The RTAs can also be employed as templates for producing other nanostructures by the nano-imprint methods, such as non-close-packed cylindrical column arrays that can be applied to surface-enhanced Raman scattering (SERS) substrates.

Self-diffusion in single crystalline silicon nanowires

Abstract: Self-diffusion experiments in single crystalline isotopically controlled silicon nanowires with diameters of 70 and 400 nm at 850 and 1000 °C are reported. The isotope structures were first epitaxially grown on top of silicon substrate wafers. Nanowires were subsequently fabricated using a nanosphere lithography process in combination with inductively coupled plasma dry reactive ion etching. Three-dimensional profiling of the nanosized structure before and after diffusion annealing was performed by means of atom probe tomography (APT). Self-diffusion profiles obtained from APT analyses are accurately described by Fick's law for self-diffusion. Data obtained for silicon self-diffusion in nanowires are equal to the results reported for bulk silicon crystals, i.e., finite size effects and high surface-to-volume ratios do not significantly affect silicon self-diffusion. This shows that the properties of native point defects determined from self-diffusion in bulk crystals also hold for nanosized silicon structures with diameters down to 70 nm.Self-diffusion experiments in single crystalline isotopically controlled silicon nanowires with diameters of 70 and 400 nm at 850 and 1000 °C are reported. The isotope structures were first epitaxially grown on top of silicon substrate wafers. Nanowires were subsequently fabricated using a nanosphere lithography process in combination with inductively coupled plasma dry reactive ion etching. Three-dimensional profiling of the nanosized structure before and after diffusion annealing was performed by means of atom probe tomography (APT). Self-diffusion profiles obtained from APT analyses are accurately described by Fick's law for self-diffusion. Data obtained for silicon self-diffusion in nanowires are equal to the results reported for bulk silicon crystals, i.e., finite size effects and high surface-to-volume ratios do not significantly affect silicon self-diffusion. This shows that the properties of native point defects determined from self-diffusion in bulk crystals also hold for nanosized silicon struc...

Controllable Fabrication of Non-Close-Packed Colloidal Nanoparticle Arrays by Ion Beam Etching.

Abstract: Polystyrene (PS) nanoparticle films with non-close-packed arrays were prepared by using ion beam etching technology. The effects of etching time, beam current, and voltage on the size reduction of PS particles were well investigated. A slow etching rate, about 9.2 nm/min, is obtained for the nanospheres with the diameter of 100 nm. The rate does not maintain constant with increasing the etching time. This may result from the thermal energy accumulated gradually in a long-time bombardment of ion beam. The etching rate increases nonlinearly with the increase of beam current, while it increases firstly then reach its saturation with the increase of beam voltage. The diameter of PS nanoparticles can be controlled in the range from 34 to 88 nm. Based on the non-close-packed arrays of PS nanoparticles, the ordered silicon (Si) nanopillars with their average diameter of 54 nm are fabricated by employing metal-assisted chemical etching technique. Our results pave an effective way to fabricate the ordered nanostructures with the size less than 100 nm.