Showing papers on "Smart material published in 2018"

Additive manufacturing — A review of 4D printing and future applications

Abstract: 3D printing will revolutionize the manufacturing industry. Significant advances in computer aided design, additive manufacturing and materials science have opened up the possibilities of self-assembly systems, self-healing and material property alterations. Printing layer by layer allows complex geometries to be built, previously difficult under conventional manufacturing routes. This paper is a review of the current materials available for 3D printing that enable the emergence of 4D printing, a ‘smart material’ that responds in a programmed way to an external stimuli. The outlook is towards potential space applications, in all areas including deployable structures, antennas and medical supplies.

Conductive Hydrogels as Smart Materials for Flexible Electronic Devices.

Abstract: Flexible conductive materials have gained considerable research interest in recent years because of their potential applications in flexible energy storage devices, sensors, touch panels, electronic skins, etc. With excellent flexibility, outstanding electric properties and tunable mechanical properties, conductive hydrogels as conductive materials offer plentiful insights and opportunities for flexible electronic devices. Numerous synthetic strategies have been developed to obtain various conductive hydrogels, and high-performance flexible electronic devices based on these conductive hydrogels have been realized. This review provides a comprehensive overview of conductive-hydrogel-based flexible electronics, ranging from conductive hydrogels synthesis to several important flexible devices applications, including touch panels, sensors and energy storage. Finally, we provide new future research directions and perspectives for conductive-hydrogel-based flexible and portable electronic devices.

Fluorinated polymers as smart materials for advanced biomedical applications

Abstract: Fluorinated polymers constitute a unique class of materials that exhibit a combination of suitable properties for a wide range of applications, which mainly arise from their outstanding chemical resistance, thermal stability, low friction coefficients and electrical properties. Furthermore, those presenting stimuli-responsive properties have found widespread industrial and commercial applications, based on their ability to change in a controlled fashion one or more of their physicochemical properties, in response to single or multiple external stimuli such as light, temperature, electrical and magnetic fields, pH and/or biological signals. In particular, some fluorinated polymers have been intensively investigated and applied due to their piezoelectric, pyroelectric and ferroelectric properties in biomedical applications including controlled drug delivery systems, tissue engineering, microfluidic and artificial muscle actuators, among others. This review summarizes the main characteristics, microstructures and biomedical applications of electroactive fluorinated polymers.

Advanced smart biomaterials and constructs for hard tissue engineering and regeneration.

Abstract: Hard tissue repair and regeneration cost hundreds of billions of dollars annually worldwide, and the need has substantially increased as the population has aged. Hard tissues include bone and tooth structures that contain calcium phosphate minerals. Smart biomaterial-based tissue engineering and regenerative medicine methods have the exciting potential to meet this urgent need. Smart biomaterials and constructs refer to biomaterials and constructs that possess instructive/inductive or triggering/stimulating effects on cells and tissues by engineering the material's responsiveness to internal or external stimuli or have intelligently tailored properties and functions that can promote tissue repair and regeneration. The smart material-based approaches include smart scaffolds and stem cell constructs for bone tissue engineering; smart drug delivery systems to enhance bone regeneration; smart dental resins that respond to pH to protect tooth structures; smart pH-sensitive dental materials to selectively inhibit acid-producing bacteria; smart polymers to modulate biofilm species away from a pathogenic composition and shift towards a healthy composition; and smart materials to suppress biofilms and avoid drug resistance. These smart biomaterials can not only deliver and guide stem cells to improve tissue regeneration and deliver drugs and bioactive agents with spatially and temporarily controlled releases but can also modulate/suppress biofilms and combat infections in wound sites. The new generation of smart biomaterials provides exciting potential and is a promising opportunity to substantially enhance hard tissue engineering and regenerative medicine efficacy.

A state of art on magneto-rheological materials and their potential applications:

Abstract: Smart materials are kinds of designed materials whose properties are controllable with the application of external stimuli such as the magnetic field, electric field, stress, and heat. Smart materials whose rheological properties are controlled by externally applied magnetic field are known as magneto-rheological materials. Magneto-rheological materials actively used for engineering applications include fluids, foams, grease, elastomers, and plastomers. In the last two decades, magneto-rheological materials have gained great attention of researchers significantly because of their salient controllable properties and potential applications to various fields such as automotive industry, civil environment, and military sector. This article offers a recent progressive review on the magneto-rheological materials technology, especially focusing on numerous application devices and systems utilizing magneto-rheological materials. Conceivable limitations, challenges, and comparable advantages of applying these magn...

Vanadium Dioxide: The Multistimuli Responsive Material and Its Applications

Abstract: The reversible, ultrafast, and multistimuli responsive phase transition of vanadium dioxide (VO2 ) makes it an intriguing "smart" material. Its crystallographic transition from the monoclinic to tetragonal phases can be triggered by diverse stimuli including optical, thermal, electrical, electrochemical, mechanical, or magnetic perturbations. Consequently, the development of high-performance smart devices based on VO2 grows rapidly. This review systematically summarizes VO2 -based emerging technologies by classifying different stimuli (inputs) with their corresponding responses (outputs) including consideration of the mechanisms at play. The potential applications of such devices are vast and include switches, memories, photodetectors, actuators, smart windows, camouflages, passive radiators, resonators, sensors, field effect transistors, magnetic refrigeration, and oscillators. Finally, the challenges of integrating VO2 into smart devices are discussed and future developments in this area are considered.

Smart Biomaterials: Recent Advances and Future Directions.

Abstract: Smart biomaterials have the ability to respond to changes in physiological parameters and exogenous stimuli and continue to impact many aspects of modern medicine. Smart materials can promote promi...

Polymer-based smart materials by printing technologies: Improving application and integration

Abstract: Smart and functional materials processed by printing technologies reveal an increasing interest due to reduced cost of assembly, easy integration into devices and the possibility to obtain multifunctional materials over flexible and large areas. After introducing smart materials, printing technologies and inks, this review discusses the materials that are already being printed, mainly piezoelectric, piezoresistive, magnetostrictive, shape memory polymers (SMP), pH sensitive and chromic system materials. Since polymer-based smart materials are particularly attractive for device implementation, this review will focus on printed polymer-based smart materials. Finally, critical challenges and future research directions will be addressed.

Multifunctional smart hydrogels: potential in tissue engineering and cancer therapy

Abstract: In recent years, clinical applications have been proposed for various hydrogel products. Hydrogels can be derived from animal tissues, plant extracts and/or adipose tissue extracellular matrices; each type of hydrogel presents significantly different functional properties and may be used for many different applications, including medical therapies, environmental pollution treatments, and industrial materials. Due to complicated preparation techniques and the complexities associated with the selection of suitable materials, the applications of many host-guest supramolecular polymeric hydrogels are limited. Thus, improvements in the design and construction of smart materials are highly desirable in order to increase the lifetimes of functional materials. Here, we summarize different functional hydrogels and their varied preparation methods and source materials. The multifunctional properties of hydrogels, particularly their unique ability to adapt to certain environmental stimuli, are chiefly based on the incorporation of smart materials. Smart materials may be temperature sensitive, pH sensitive, pH/temperature dual sensitive, photoresponsive or salt responsive and may be used for hydrogel wound repair, hydrogel bone repair, hydrogel drug delivery, cancer therapy, and so on. This review focuses on the recent development of smart hydrogels for tissue engineering applications and describes some of the latest advances in using smart materials to create hydrogels for cancer therapy.

Softer is Harder: What Differentiates Soft Robotics from Hard Robotics?

Abstract: This paper reports on what differentiates the field of soft (i.e. soft-bodied) robotics from the conventional hard (i.e. rigid-bodied) robotics. The main difference centres on seamlessly combining the actuation, sensing, motion transmission and conversion mechanism elements, electronics and power source into a continuum body that ideally holds the properties of morphological computation and programmable compliance (i.e. softness). Another difference is about the materials they are made of. While the hard robots are made of rigid materials such as metals and hard plastics with a bulk elastic modulus of as low as 1 GPa, the monolithic soft robots should be fabricated from soft and hard materials or from a strategic combination of them with a maximum elasticity modulus of 1 GPa. Soft smart materials with programmable mechanical, electrical and rheological properties, and conformable to additive manufacturing based on 3D printing are essential to realise soft robots. Selecting the actuation concept and its power source, which is the first and most important step in establishing a robot, determines the size, weight, performance of the soft robot, the type of sensors and their location, control algorithm, power requirement and its associated flexible and stretchable electronics. This paper outlines how crucial the soft materials are in realising the actuation concept, which can be inspired from animal and plant movements.

Searching for a Stable High-Performance Magnetorheological Suspension.

Abstract: Magnetorheological (MR) fluids are a type of smart material with rheological properties that may be controlled through mesostructural transformations MR fluids form solid-like fibril structures along the magnetic field direction upon application of a magnetic field due to magnetopolarization of soft-magnetic particles when suspended in an inert medium A reverse structural transition occurs upon removal of the applied field The structural changes are very fast on the order of milliseconds The rheological properties of MR fluids vary with the application of a magnetic field, resulting in non-Newtonian viscoplastic flow behaviors Recent applications have increased the demand for MR materials with better performance and good long-term stability A variety of industrial MR materials have been developed and tested in numerous experimental and theoretical studies Because modeling and analysis are essential to optimize material design, a new macroscale structural model has been developed to distinguish between static yield stress and dynamic yield stress and describe the flow behavior over a wide range of shear rates Herein, this recent progress in the search for advanced MR fluid materials with good stability is described, along with new approaches to MR flow behavior analysis Several ways to improve the stability and efficiency of the MR fluids are also summarized

HCI meets Material Science: A Literature Review of Morphing Materials for the Design of Shape-Changing Interfaces

Abstract: With the proliferation of flexible displays and the advances in smart materials, it is now possible to create interactive devices that are not only flexible but can reconfigure into any shape on demand. Several Human Computer Interaction (HCI) and robotics researchers have started designing, prototyping and evaluating shape-changing devices, realising, however, that this vision still requires many engineering challenges to be addressed. On the material science front, we need breakthroughs in stable and accessible materials to create novel, proof-of-concept devices. On the interactive devices side, we require a deeper appreciation for the material properties and an understanding of how exploiting material properties can provide affordances that unleash the human interactive potential. While these challenges are interesting for the respective research fields, we believe that the true power of shape-changing devices can be magnified by bringing together these communities. In this paper we therefore present a review of advances made in shape-changing materials and discuss their applications within an HCI context.

Network Topology in Soft Gels: Hardening and Softening Materials.

Abstract: The structural complexity of soft gels is at the origin of a versatile mechanical response that allows for large deformation, controlled elastic recovery, and toughness in the same material. A limit to exploiting the potential of such materials is the insufficient fundamental understanding of the microstructural origin of the bulk mechanical properties. Here we investigate the role of the network topology in a model gel through 3D numerical simulations. Our study links the topology of the network organization in space to its nonlinear rheological response preceding yielding and damage: our analysis elucidates how the network connectivity alone could be used to modify the gel mechanics at large strains, from strain-softening to hardening and even to a brittle response. These findings provide new insight for smart material design and for understanding the nontrivial mechanical response of a potentially wide range of technologically relevant materials.

Progress in internal/external stimuli responsive fluorescent carbon nanoparticles for theranostic and sensing applications.

Abstract: In the past decade, fluorescent carbon nanoparticles (FNPs) prepared from natural resources and biomaterials have been attractive due to their various properties, such as unique optical properties, great biocompatibility, water dispersion, and facile surface functionalization. Depending on the properties of the carbon sources and the subsequent carbonization processes, internal/external stimuli responsive carbon nanoparticles have been generated that are useful for theranostic and sensing applications. In this review, we highlight the recent developments in the use of FNPs in nanomedicine in great detail, particularly for FNPs responding to internal stimuli, including redox, pH, and enzymes, and external stimuli, including temperature, light, and magnetic fields, for drug delivery and sensing applications. Furthermore, we hope to provide insight that could stimulate further research aiming for unparalleled useful applications. As a result, there are many possibilities that can be explored from this smart material.

Machining of NiTi-shape memory alloys-A review

Abstract: The emerging trends in the development of advanced smart materials with better unique properties under different environments for a particular application fascinate the researchers and industrialis...

Advanced Material Strategies for Next-Generation Additive Manufacturing

Abstract: Additive manufacturing (AM) has drawn tremendous attention in various fields. In recent years, great efforts have been made to develop novel additive manufacturing processes such as micro-/nano-scale 3D printing, bioprinting, and 4D printing for the fabrication of complex 3D structures with high resolution, living components, and multimaterials. The development of advanced functional materials is important for the implementation of these novel additive manufacturing processes. Here, a state-of-the-art review on advanced material strategies for novel additive manufacturing processes is provided, mainly including conductive materials, biomaterials, and smart materials. The advantages, limitations, and future perspectives of these materials for additive manufacturing are discussed. It is believed that the innovations of material strategies in parallel with the evolution of additive manufacturing processes will provide numerous possibilities for the fabrication of complex smart constructs with multiple functions, which will significantly widen the application fields of next-generation additive manufacturing.

Smart nanoporous metal-organic frameworks by embedding photochromic molecules - state of the art and future perspectives.

Abstract: Smart, molecularly structured materials with remote-controllable properties and functionalities attract particular attention and may enable advanced applications. In this respect, the embedment of stimuli-responsive molecules, such as azobenzenes, spiropyrans or diarylethenes, in metal-organic frameworks (MOFs) is a very fascinating approach, resulting in easily accessible photoswitchable, nanoporous hybrid materials. It is an attractive alternative to the incorporation of the smart moieties in the MOF scaffold, which usually demands complex synthetic efforts. Here, the opportunities, properties and perspectives of the embedment of photochromic molecules in MOF pores are reviewed. In addition to presenting a straightforward route to prepare smart materials with, e.g., photoswitchable adsorption properties that can be used for remote-controllable membrane separation, the photoswitch@MOF compounds also represent unique model systems to investigate the dye as well as the MOF properties and their interactions with each other. For instance, the MOF pores possess a polarity similar to a solvent, so that the optical properties of the resulting materials may be influenced by a careful choice of the respective host material.

Smart bricks for strain sensing and crack detection in masonry structures

Abstract: The paper proposes the novel concept of smart bricks as a durable sensing solution for structural health monitoring of masonry structures. The term smart bricks denotes piezoresistive clay bricks with suitable electronics capable of outputting measurable changes in their electrical properties under changes in their state of strain. This feature can be exploited to evaluate stress at critical locations inside a masonry wall and to detect changes in loading paths associated with structural damage, for instance following an earthquake. Results from an experimental campaign show that normal clay bricks, fabricated in the laboratory with embedded electrodes made of a special steel for resisting the high baking temperature, exhibit a quite linear and repeatable piezoresistive behavior. That is a change in electrical resistance proportional to a change in axial strain. In order to be able to exploit this feature for strain sensing, highresolution electronics are used with a biphasic DC measurement approach to eliminate any resistance drift due to material polarization. Then, an enhanced nanocomposite smart brick is proposed, where titania is mixed with clay before baking, in order to enhance the brick's mechanical properties, improve its noise rejection, and increase its electrical conductivity. Titania was selected among other possible conductive nanofillers due to its resistance to high temperatures and its ability to improve the durability of construction materials while maintaining the aesthetic appearance of clay bricks. An application of smart bricks for crack detection in masonry walls is demonstrated by laboratory testing of a small-scale wall specimen under different loading conditions and controlled damage. Overall, it is demonstrated that a few strategically placed smart bricks enable monitoring of the state of strain within the wall and provide information that is capable of crack detection.

Smart coatings of epoxy based CNTs designed to meet practical expectations in aeronautics

Abstract: A smart coating exhibiting self-diagnostic capability is designed to meet industrial requirements in aeronautics. The coating made of epoxy-based carbon nanotubes (CNTs) has been applied on industrial Carbon Fiber Reinforced Plastics (CFRPs) currently employed in aeronautics. The correlations between mechanical strain and electrical properties of coated CFRPs highlights the feasibility in manufacturing CFRPs having integrated high sensitivity in providing an effective real-time structural health monitoring. The reliability of the developed CFRPs, in the normal operational temperature range of aircrafts, opens new perspectives in the field of self-responsive structures in aeronautics. Self-responsive panels can simultaneously act as sensor and structural element.

Photoactivated Polymeric Bilayer Actuators Fabricated via 3D Printing.

Abstract: 4D printing is an emerging additive manufacturing technology that combines the precision of 3D printing with the versatility of smart materials. 4D printed objects can change their shape over time with the application of a stimulus (i.e., heat, light, moisture). Light driven smart materials are attractive because light is wireless, remote, and can induce a rapid shape change. Herein, we present a method for fabricating polymeric bilayer actuators via 3D printing which reversibly change their shape upon exposure to light. The photoactive layer consists of a poly(siloxane) containing pendant azobenzene groups. Two different photoactive polymers were synthesized, and the photomechanical effect displayed by the bilayers was evaluated. These bilayers exhibit rapid actuation with full cycles completed within seconds, and photo generated stresses ranging from 1.03 to 1.70 MPa.

A State-of-the-Art Review on Robots and Medical Devices Using Smart Fluids and Shape Memory Alloys

Abstract: Over the last two decades, smart materials have received significant attention over a broad range of engineering applications because of their unique and inherent characteristics for actuating and sensing aspects. In this review article, recent research works on various robots, medical devices and rehabilitation mechanisms whose main functions are activated by smart materials are introduced and discussed. Among many smart materials, electro-rheological fluids, magneto-rheological fluids, and shape memory alloys are considered since there are mostly appropriate application candidates for the robot and medical devices. Many different types of robots proposed to date, such as parallel planar robots, are investigated focusing on design configuration and operating principles. In addition, specific mechanism and operating principles of medical devices and rehabilitation systems are introduced and commented in terms of practical realization.