Eindhoven University of Technology

About: Eindhoven University of Technology is a education organization based out in Eindhoven, Noord-Brabant, Netherlands. It is known for research contribution in the topics: Catalysis & Computer science. The organization has 22309 authors who have published 52936 publications receiving 1584164 citations. The organization is also known as: Technische Hogeschool Eindhoven & TU/e.

Engineering bunched Pt-Ni alloy nanocages for efficient oxygen reduction in practical fuel cells

Abstract: Development of efficient and robust electrocatalysts is critical for practical fuel cells. We report one-dimensional bunched platinum-nickel (Pt-Ni) alloy nanocages with a Pt-skin structure for the oxygen reduction reaction that display high mass activity (3.52 amperes per milligram platinum) and specific activity (5.16 milliamperes per square centimeter platinum), or nearly 17 and 14 times higher as compared with a commercial platinum on carbon (Pt/C) catalyst. The catalyst exhibits high stability with negligible activity decay after 50,000 cycles. Both the experimental results and theoretical calculations reveal the existence of fewer strongly bonded platinum-oxygen (Pt-O) sites induced by the strain and ligand effects. Moreover, the fuel cell assembled by this catalyst delivers a current density of 1.5 amperes per square centimeter at 0.6 volts and can operate steadily for at least 180 hours.

Unified Description of Charge-Carrier Mobilities in Disordered Semiconducting Polymers

Abstract: From a numerical solution of the master equation for hopping transport in a disordered energy landscape with a Gaussian density of states, we determine the dependence of the charge-carrier mobility on temperature, carrier density, and electric field. Experimental current-voltage characteristics in devices based on semiconducting polymers are excellently reproduced with this unified description of the mobility. At room temperature it is mainly the dependence on carrier density that plays an important role, whereas at low temperatures and high fields the electric field dependence becomes important. Omission in the past of the carrier-density dependence has led to an underestimation of the hopping distance and the width of the density of states in these polymers.

Controller Area Network (CAN) schedulability analysis: Refuted, revisited and revised

Abstract: Controller Area Network (CAN) is used extensively in automotive applications, with in excess of 400 million CAN enabled microcontrollers manufactured each year. In 1994 schedulability analysis was developed for CAN, showing how worst-case response times of CAN messages could be calculated and hence guarantees provided that message response times would not exceed their deadlines. This seminal research has been cited in over 200 subsequent papers and transferred to industry in the form of commercial CAN schedulability analysis tools. These tools have been used by a large number of major automotive manufacturers in the design of in-vehicle networks for a wide range of cars, millions of which have been manufactured during the last decade. This paper shows that the original schedulability analysis given for CAN messages is flawed. It may provide guarantees for messages that will in fact miss their deadlines in the worst-case. This paper provides revised analysis resolving the problems with the original approach. Further, it highlights that the priority assignment policy, previously claimed to be optimal for CAN, is not in fact optimal and cites a method of obtaining an optimal priority ordering that is applicable to CAN. The paper discusses the possible impact on commercial CAN systems designed and developed using flawed schedulability analysis and makes recommendations for the revision of CAN schedulability analysis tools.