University of Stuttgart

About: University of Stuttgart is a education organization based out in Stuttgart, Germany. It is known for research contribution in the topics: Laser & Finite element method. The organization has 27715 authors who have published 56370 publications receiving 1363382 citations. The organization is also known as: Universität Stuttgart.

Thermal Degradation of Acylated and Nonacylated Anthocyanins

Abstract: The thermal degradation pathways of acylated and nonacylated anthocyanins from 3 commercial sources have been investigated. Strawberry, elderberry, and black carrot concentrates were purified on XAD-16-HP and Sephadex-LH-20 columns to remove sugars, amino acids, salts, and phenolic compounds, respectively. The so obtained anthocyanin isolates were heated at 95 °C at pH 1, the optimum stability condition for the flavylium cation. During 7 h of thermal exposure, the samples were monitored by HPLC-DAD-MS3 at 280, 320, and 520 nm, respectively, together with spectrophotometric color and anthocyanin assessment. Total anthocyanin content lightness, and chroma, but not hue angle, were appropriate parameters to monitor anthocyanin loss on a statistically significant level. Anthocyanin glycosides were generally cleaved by successive loss of sugar moieties and pentoses were more readily split off than hexoses. Anthocyanin aglycones were further degraded by scission into phloroglucinaldehyde (cyanidin, pelargonidin), 4-hydroxybenzoic acid (pelargonidin), and protocatechuic acid (cyanidin), the residues of the A- and B-rings, respectively. Most interestingly, acylated cyanidin-triglycosides from black carrot were degraded into their corresponding diglycoside derivatives, which are not genuine carrot pigments. Moreover, hydroxycinnamic acid glycosides were generated. It is therefore assumed that the thermal burden during processing of anthocyanic food can be deduced by monitoring the colored and colorless compound profiles.

New Generation of Biocatalysts for Organic Synthesis

Abstract: The use of enzymes as catalysts for the preparation of novel compounds has received steadily increasing attention over the past few years. High demands are placed on the identification of new biocatalysts for organic synthesis. The catalysis of more ambitious reactions reflects the high expectations of this field of research. Enzymes play an increasingly important role as biocatalysts in the synthesis of key intermediates for the pharmaceutical and chemical industry, and new enzymatic technologies and processes have been established. Enzymes are an important part of the spectrum of catalysts available for synthetic chemistry. The advantages and applications of the most recent and attractive biocatalysts--reductases, transaminases, ammonia lyases, epoxide hydrolases, and dehalogenases--will be discussed herein and exemplified by the syntheses of interesting compounds.

Evaluation of Reservation Mechanisms for Optical Burst Switching

Abstract: Summary In this paper, we give an overview and classification of optical burst switching schemes and present burst reservation concepts. The performance of various basic reservation mechanisms proposed in literature is compared. Furthermore, a new analysis is introduced that allows to calculate the loss probabilities of a two-class system based on the reservation mechanism just-enough-time (JET) for arbitrary offsets. Finally, a variety of new results is presented including the dependence of burst loss probabilities on offset, burst length distribution, and interarrival distribution.

Mole – Concepts of a mobile agent system

Abstract: Due to its salient properties, mobile agent technology has received a rapidly growing attention over the last few years. Many developments of mobile agent systems are under way in both academic and industrial environments. In addition, there are already various efforts to standardize mobile agent facilities and architectures. Mole is the first mobile agent system that has been developed in the Java language. The first version was finished in 1995, and since then Mole has been constantly improved. Mole provides a stable environment for the development and usage of mobile agents in the area of distributed applications. In this paper we describe the basic concepts of a mobile agent system, i.e., mobility, communication and security, discuss different implementation techniques, present the decisions made in Mole and give an overview of the system services implemented in Mole.

An experimental and theoretical guide to strongly interacting Rydberg gases

Abstract: We review experimental and theoretical tools to excite, study and understand strongly interacting Rydberg gases. The focus lies on the excitation of dense ultracold atomic samples close to, or within quantum degeneracy, high-lying Rydberg states. The major part is dedicated to highly excited S-states of rubidium, which feature an isotropic van der Waals potential. Nevertheless, the setup and the methods presented are also applicable to other atomic species used in the field of laser cooling and atom trapping. (Some figures may appear in colour only in the online journal)