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Alcohol combustion chemistry

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TLDR
A detailed overview of recent results on alcohol combustion can be found in this paper, with a particular emphasis on butanols and other linear and branched members of the alcohol family, from methanol to hexanols.
About
This article is published in Progress in Energy and Combustion Science.The article was published on 2014-10-01. It has received 676 citations till now. The article focuses on the topics: Alcohol fuel & Combustion.

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Citations
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Methanol as a fuel for internal combustion engines

TL;DR: In this paper, the use of methanol as a pure fuel or a blend component for internal combustion engines (ICEs) is discussed, highlighting the differences with fuels such as ethanol and gasoline.
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Alternative fuels for internal combustion engines

TL;DR: In this article, a review of potential alternative fuels for automotive engine application for both spark ignition (SI) and compression ignition (CI) engines is presented, which includes applications of alternative fuels in advanced combustion research applications.
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A review of the combustion and emissions properties of advanced transportation biofuels and their impact on existing and future engines

TL;DR: In this paper, the fundamental combustion and emissions properties of advanced biofuels are reviewed, and their impact on engine performance is discussed, in order to guide the selection of optimal conversion routes for obtaining desired fuel combustion properties.
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A comprehensive review of measurements and data analysis of laminar burning velocities for various fuel+air mixtures

TL;DR: In this article, a brief review of spherical flame propagation method, counterflow/stagnation burner method, heat-flux method, annular stepwise method, externally heated diverging channel method, and Bunsen method is presented.
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Recent progress in gasoline surrogate fuels

TL;DR: A comprehensive review of the available experimental and chemical kinetic studies which have been performed to better understand the combustion properties of gasoline fuels and their surrogates can be found in this paper, where a detailed analysis is presented for the various classes of compounds used in formulating gasoline surrogate fuels, including n-paraffins, isoparaffin, olefins, naphthenes and aromatics.
References
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Autoignition of ethanol in a rapid compression machine

TL;DR: In this paper, a chemical kinetic mechanism that can accurately predict the autoignition characteristics of ethanol at low temperatures and elevated pressures has been developed and this mechanism is compared with other models available in the literature.
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Rate constants for the thermal decomposition of ethanol and its bimolecular reactions with OH and D: reflected shock tube and theoretical studies.

TL;DR: The thermal decomposition of ethanol and its reactions with OH and D have been studied with both shock tube experiments and ab initio transition state theory-based master equation calculations, and a consistent description of both the decomposition (1-3) and abstraction kinetics (4 and 5) is yielded.
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Tailoring HCCI heat-release rates with partial fuel stratification: Comparison of two-stage and single-stage-ignition fuels

TL;DR: In this paper, partial fuel stratification was used, where most fuel was premixed with intake air and the rest of the fuel was directly injected during the compression stroke to overcome the problem of overly rapid combustion at high load conditions, which can lead to engine knock and potential engine damage.
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A computational tool for the detailed kinetic modeling of laminar flames: Application to C2H4/CH4 coflow flames

TL;DR: In this article, a new computational framework for modeling multi-dimensional laminar flames with detailed gas-phase kinetic mechanisms is presented, which is suitable both for steady-state and unsteady flows and for structured and unstructured meshes.
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A Comprehensive Study of Methanol Kinetics in Freely-Propagating and Burner-Stabilized Flames, Flow and Static Reactors, and Shock Tubes

TL;DR: In this paper, a detailed kinetic scheme was compiled which closely predicts properties of mixtures of methanol, oxygen, and inert for a variety of experimental configurations and conditions and was tested against experimental data for the propagation speeds and structure of laminar flames as well as the species concentration evolutions in flow reactors, static reactors, and shock tubes.
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