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Alcohol combustion chemistry

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TLDR
A detailed overview of recent results on alcohol combustion can be found in this paper, with a particular emphasis on butanols and other linear and branched members of the alcohol family, from methanol to hexanols.
About
This article is published in Progress in Energy and Combustion Science.The article was published on 2014-10-01. It has received 676 citations till now. The article focuses on the topics: Alcohol fuel & Combustion.

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Citations
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Methanol as a fuel for internal combustion engines

TL;DR: In this paper, the use of methanol as a pure fuel or a blend component for internal combustion engines (ICEs) is discussed, highlighting the differences with fuels such as ethanol and gasoline.
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Alternative fuels for internal combustion engines

TL;DR: In this article, a review of potential alternative fuels for automotive engine application for both spark ignition (SI) and compression ignition (CI) engines is presented, which includes applications of alternative fuels in advanced combustion research applications.
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A review of the combustion and emissions properties of advanced transportation biofuels and their impact on existing and future engines

TL;DR: In this paper, the fundamental combustion and emissions properties of advanced biofuels are reviewed, and their impact on engine performance is discussed, in order to guide the selection of optimal conversion routes for obtaining desired fuel combustion properties.
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A comprehensive review of measurements and data analysis of laminar burning velocities for various fuel+air mixtures

TL;DR: In this article, a brief review of spherical flame propagation method, counterflow/stagnation burner method, heat-flux method, annular stepwise method, externally heated diverging channel method, and Bunsen method is presented.
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Recent progress in gasoline surrogate fuels

TL;DR: A comprehensive review of the available experimental and chemical kinetic studies which have been performed to better understand the combustion properties of gasoline fuels and their surrogates can be found in this paper, where a detailed analysis is presented for the various classes of compounds used in formulating gasoline surrogate fuels, including n-paraffins, isoparaffin, olefins, naphthenes and aromatics.
References
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Detailed Kinetic Modeling Study of n-Pentanol Oxidation

TL;DR: In this article, a detailed kinetic model for n-pentanol based on modeling rules was presented, which was validated using quantum chemistry calculations to verify the most stable npentanol conformation and to obtain C-H and C-C bond dissociation energies.
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Detailed Chemistry Promotes Understanding of Octane Numbers and Gasoline Sensitivity

TL;DR: In this paper, a two-zone model of a spark ignition engine, coupled with the detailed chemistry of combustion processes, was developed and utilized for the predictions of octane numbers and octane sensitivity.
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Gas phase reactions of C1???C4 alcohols with the OH radical: A quantum mechanical approach

TL;DR: In this article, a complex mechanism involving the formation of a stable pre-reactive complex is proposed and the temperature dependence of the rate coefficients is studied over the temperature range of 290-500 K, using conventional transition state theory (CTST).
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Ignition delay times of ethanol-containing multi-component gasoline surrogates: Shock-tube experiments and detailed modeling

TL;DR: In this paper, a detailed kinetics model was proposed for multicomponent mixtures that is based on the reference fuels (PRF) model as a kernel and incorporates sub-mechanisms to account for the chemistry of ethanol, toluene and diisobutylene.
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