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Alcohol combustion chemistry

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TLDR
A detailed overview of recent results on alcohol combustion can be found in this paper, with a particular emphasis on butanols and other linear and branched members of the alcohol family, from methanol to hexanols.
About
This article is published in Progress in Energy and Combustion Science.The article was published on 2014-10-01. It has received 676 citations till now. The article focuses on the topics: Alcohol fuel & Combustion.

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Citations
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Methanol as a fuel for internal combustion engines

TL;DR: In this paper, the use of methanol as a pure fuel or a blend component for internal combustion engines (ICEs) is discussed, highlighting the differences with fuels such as ethanol and gasoline.
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Alternative fuels for internal combustion engines

TL;DR: In this article, a review of potential alternative fuels for automotive engine application for both spark ignition (SI) and compression ignition (CI) engines is presented, which includes applications of alternative fuels in advanced combustion research applications.
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A review of the combustion and emissions properties of advanced transportation biofuels and their impact on existing and future engines

TL;DR: In this paper, the fundamental combustion and emissions properties of advanced biofuels are reviewed, and their impact on engine performance is discussed, in order to guide the selection of optimal conversion routes for obtaining desired fuel combustion properties.
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A comprehensive review of measurements and data analysis of laminar burning velocities for various fuel+air mixtures

TL;DR: In this article, a brief review of spherical flame propagation method, counterflow/stagnation burner method, heat-flux method, annular stepwise method, externally heated diverging channel method, and Bunsen method is presented.
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Recent progress in gasoline surrogate fuels

TL;DR: A comprehensive review of the available experimental and chemical kinetic studies which have been performed to better understand the combustion properties of gasoline fuels and their surrogates can be found in this paper, where a detailed analysis is presented for the various classes of compounds used in formulating gasoline surrogate fuels, including n-paraffins, isoparaffin, olefins, naphthenes and aromatics.
References
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Thermal Decomposition of 2-Butanol as a Potential Nonfossil Fuel: A Computational Study

TL;DR: The results indicated that dehydration to 1- and 2-butene through four-center transition states is the most dominant channel at low to moderate temperatures (T ≤ 700 K), where formation of butenes is kinetically and thermodynamically more favorable than other complex and simple bond scission reactions.
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Comparison of Different Gasoline Alternative Fuels in Terms of Laminar Burning Velocity at Increased Gas Temperatures and Exhaust Gas Recirculation Rates

TL;DR: In this paper, a self-designed liquid fuel evaporation system has been combined with a precise droplet generator, which allows for measurements of adiabatic laminar burning velocity at elevated gas temperatures.
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Experimental and Detailed Kinetic Modeling Study of the Oxidation of 1-Propanol in a Pressurized Jet-Stirred Reactor (JSR) and a Combustion Bomb

TL;DR: In this article, the authors used a combustion bomb to measure burning velocities of 1-propanol/air mixtures at pressures of P = 1-10 bar and T = 423 K, over a range of equivalence ratios (0.7 ≤ φ ≤ 1.4) and at 1 bar for temperatures in the range of 323-473 K.
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Rate constant measurements for the overall reaction of OH + 1-butanol → products from 900 to 1200 K.

TL;DR: The current work improves upon previous experimental studies of the title rate constant by utilizing a rigorously generated kinetic model to describe secondary reactions and extends the temperature range of experimental data in the literature for the title reaction under combustion-relevant conditions.
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