Monolithic Perovskite Tandem Solar Cells: A Review of the Present Status and Advanced Characterization Methods Toward 30% Efficiency
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This article is published in Advanced Energy Materials.The article was published on 2020-07-01 and is currently open access. It has received 266 citations till now. The article focuses on the topics: Perovskite (structure).read more
Citations
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Journal ArticleDOI
Monolithic perovskite/silicon tandem solar cell with >29% efficiency by enhanced hole extraction
Amran Al-Ashouri,Eike Köhnen,Bor Li,Artiom Magomedov,Hannes Hempel,Pietro Caprioglio,Pietro Caprioglio,José A. Márquez,Anna Belen Morales Vilches,Ernestas Kasparavicius,Joel A. Smith,Joel A. Smith,Nga Phung,Dorothee Menzel,Max Grischek,Max Grischek,Lukas Kegelmann,Dieter Skroblin,Christian Gollwitzer,Tadas Malinauskas,Marko Jošt,Marko Jošt,Gašper Matič,Bernd Rech,Bernd Rech,Rutger Schlatmann,Rutger Schlatmann,Marko Topič,Lars Korte,Antonio Abate,Bernd Stannowski,Bernd Stannowski,Dieter Neher,Martin Stolterfoht,Thomas Unold,Vytautas Getautis,Steve Albrecht,Steve Albrecht +37 more
TL;DR: A monolithic perovskite/silicon tandem with a certified power conversion efficiency of 29.15% is reported, made possible by a self-assembled, methyl-substituted carbazole monolayer as the hole-selective layer in the perovSKite cell.
Journal ArticleDOI
All-perovskite tandem solar cells with 24.2% certified efficiency and area over 1 cm2 using surface-anchoring zwitterionic antioxidant
Ke Xiao,Renxing Lin,Qiaolei Han,Yi Hou,Zhenyuan Qin,Hieu T. Nguyen,Jin Wen,Mingyang Wei,Vishal Yeddu,Makhsud I. Saidaminov,Yuan Gao,Xin Luo,Y.N. Wang,Han Gao,Chunfeng Zhang,Jun Xu,Jia Zhu,Edward H. Sargent,Hairen Tan +18 more
TL;DR: Xiao et al. as mentioned in this paper used strongly reductive surface-anchoring zwitterionic molecules to suppress Sn2+ oxidation and passivate defects at the grain surfaces in mixed lead-tin perovskite films, enabling an efficiency of 21.7% (certified 20.7%).
Journal ArticleDOI
All-perovskite tandem solar cells with improved grain surface passivation
Renxing Lin,Jian Xu,Mingyang Wei,Yurui Wang,Zhengyuan Qin,Zhou Liu,Jinlong Wu,Ke Xiao,Bin Chen,So Min Park,Gang Chen,H.Y.R. Atapattu,Kenneth R. Graham,Jun Xu,Jia Zhu,Ludong Li,Chunfeng Zhang,Edward H. Sargent,Hairen Tan +18 more
TL;DR: An ammonium-cation-passivated Pb-Sn perovskites with long diffusion lengths are developed, enabling subcells having an absorber thickness of ~1.2 μm, and a certified efficiency of 26.4% in all-perovskite tandem solar cells is reported, exceeding that of the best-performing single-junction perovSKite solar cells.
Journal ArticleDOI
Recent progress in tin-based perovskite solar cells
Jiupeng Cao,Feng Yan +1 more
TL;DR: In this paper, the authors summarized the device design of PSCs and the physical properties of tin-based perovskites and discussed the major challenges for this field and discuss the essential techniques in film preparation.
Journal ArticleDOI
Tin Oxide Electron‐Selective Layers for Efficient, Stable, and Scalable Perovskite Solar Cells
Cesur Altinkaya,Erkan Aydin,Esma Ugur,Furkan Halis Isikgor,Anand S. Subbiah,Michele De Bastiani,Jiang Liu,Aslihan Babayigit,Aslihan Babayigit,Aslihan Babayigit,Thomas Allen,Frédéric Laquai,Abdullah Yildiz,Stefaan De Wolf +13 more
TL;DR: In this article, the development of tin oxide (SnO2 ) as a perovskite-relevant electron selective layer (ESL) is reviewed with emphasis placed on the various fabrication methods and interfacial passivation routes toward champion solar cells with high stability.
References
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Journal ArticleDOI
Understanding the rate-dependent J–V hysteresis, slow time component, and aging in CH3NH3PbI3 perovskite solar cells: the role of a compensated electric field
Wolfgang Tress,Nevena Marinova,Thomas Moehl,Shaik M. Zakeeruddin,Mohammad Khaja Nazeeruddin,Michael Grätzel +5 more
TL;DR: In this paper, the rate-dependent hysteresis seen in current-voltage scans of CH3NH3PbI3 perovskite solar cells is related to a slow field-induced process that tends to cancel the electric field in the device at each applied bias voltage.
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Hysteresis and transient behavior in current–voltage measurements of hybrid-perovskite absorber solar cells
Eva L. Unger,Eric T. Hoke,Eric T. Hoke,Colin D. Bailie,William H. Nguyen,Andrea R. Bowring,Thomas Heumüller,Mark G. Christoforo,Michael D. McGehee +8 more
TL;DR: In this article, the authors observe slow transient effects causing hysteresis in the current-voltage characterization of hybrid organo-metal halide perovskites that can lead to an over- or underestimation of the solar cell device efficiency.
Journal ArticleDOI
Organometal Halide Perovskite Solar Cell Materials Rationalized: Ultrafast Charge Generation, High and Microsecond-Long Balanced Mobilities, and Slow Recombination
Carlito S. Ponseca,Tom J. Savenije,Mohamed Abdellah,Mohamed Abdellah,Kaibo Zheng,Arkady Yartsev,Tobjorn Pascher,Tobias Harlang,Pavel Chábera,Tõnu Pullerits,Andrey L. Stepanov,Jean-Pierre Wolf,Villy Sundström +12 more
TL;DR: Photoluminescence, transient absorption, time-resolved terahertz and microwave conductivity measurements are applied to determine the time scales of generation and recombination of charge carriers as well as their transport properties in solution-processed CH3NH3PbI3 perovskite materials to unravel the remarkable intrinsic properties of the material.
Journal ArticleDOI
Perovskite-perovskite tandem photovoltaics with optimized band gaps
Giles E. Eperon,Giles E. Eperon,Tomas Leijtens,Kevin A. Bush,Rohit Prasanna,Thomas Green,Jacob Tse-Wei Wang,David P. McMeekin,George Volonakis,Rebecca L. Milot,Richard May,Axel F. Palmstrom,Daniel J. Slotcavage,Rebecca A. Belisle,Jay B. Patel,Elizabeth S. Parrott,Rebecca J. Sutton,Wen Ma,Farhad Moghadam,Bert Conings,Bert Conings,Aslihan Babayigit,Aslihan Babayigit,Hans-Gerd Boyen,Stacey F. Bent,Feliciano Giustino,Laura M. Herz,Michael B. Johnston,Michael D. McGehee,Henry J. Snaith +29 more
TL;DR: This device architecture and materials set will enable “all-perovskite” thin-film solar cells to reach the highest efficiencies in the long term at the lowest costs.
Journal ArticleDOI
Methylammonium Chloride Induces Intermediate Phase Stabilization for Efficient Perovskite Solar Cells
Minjin Kim,Minjin Kim,Gi-Hwan Kim,Tae Kyung Lee,In Woo Choi,Hye Won Choi,Yimhyun Jo,Yung Jin Yoon,Jae Won Kim,Jiyun Lee,Daihong Huh,Heon Lee,Sang Kyu Kwak,Jin Young Kim,Dong Suk Kim +14 more
TL;DR: In this article, the function of methylammonium chloride (MACl) additive in formamidinium lead iodide (FAPbI3)-based perovskite was studied.
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