Studies on some chemical aspects of kusum oil

An ideal feedstock, kusum (Schleichera triguga) for preparation of biodiesel: Optimization of parameters

Abstract: Kusum (Schleichera triguga), a non-edible oil bearing plant has been used as an ideal feedstock for biodiesel development in the present study. Various physical and chemical parameters of the raw oil and the fatty acid methyl esters derived have been tested to confirm its suitability as a biodiesel fuel. The fatty acid component of the oil was tested by gas chromatography. The acid value of the oil was determined by titration and was found to 21.30 mg KOH/g which required two step transesterification. Acid value was brought down by esterification using sulfuric acid (H2SO4) as a catalyst. Thereafter, alkaline transesterification was carried out using potassium hydroxide (KOH) as catalyst for conversion of kusum oil to its methyl esters. Various parameters such as molar ratio, amount of catalyst and reaction time were optimized and a high yield (95%) of biodiesel was achieved. The high conversion of the feedstock into esters was confirmed by analysis of the product on gas chromatograph–mass spectrometer (GC–MS). Viscosity and acid value of the product biodiesel were determined and found to be within the limits of ASTM D 6751 specifications. Elemental analysis of biodiesel showed presence of carbon, hydrogen, oxygen and absence of nitrogen and sulfur after purification. Molar ratio of methanol to oil was optimized and found to be 10:1 for acid esterification, and 8:1 for alkaline transesterification. The amounts of H2SO4 and KOH, 1% (v/v) and 0.7% (w/w), respectively, were found to be optimum for the reactions. The time duration of 1 h for acid esterification followed by another 1 h for alkaline transesterification at 50 ± 0.5 °C was optimum for synthesis of biodiesel.

Recent Advances in the Chemistry of Cyanogenic Glycosides

Abstract: The cyanogenic glycosides, here defined as glycosidic derivatives of α-hydroxynitriles, represent a rather limited class of natural products, which are widely distributed in the plant kingdom and, to a small extent, even in animals. A characteristic feature of these glycosides is their ability to release hydrocyanic acid on treatment with dilute acids or appropriate enzymes. The term “cyanogenic” is used to designate this property, regardless of whether pure substances, plants, or animals, are serving as the source. In the latter cases the term “cyanophoric” is occasionally employed synonymously.

Ultrasound assisted two-stage biodiesel synthesis from non-edible Schleichera triguga oil using heterogeneous catalyst: Kinetics and thermodynamic analysis.

Abstract: Present work deals with the ultrasound-assisted biodiesel production from low cost, substantial acid value kusum (Schleichera triguga) oil using a two-step method of esterification in presence of acid (H2SO4) catalyst followed by transesterification using a basic heterogeneous barium hydroxide (Ba(OH)2) catalyst. The initial acid value of kusum oil was reduced from 21.65 to 0.84 mg of KOH/g of oil, by acid catalyzed esterification with 4:1 methanol to oil molar ratio, catalyst concentration 1% (v/v), ultrasonic irradiation time 20 min at 40 °C. Then, Ba(OH)2 concentration of 3% (w/w), methanol to oil molar ratio of 9:1, ultrasonic irradiation time of 80 min, and temperature of 50 °C was found to be the optimum conditions for transesterification step and triglyceride conversion of 96.8% (wt) was achieved. This paper also examined the kinetics as well as the evaluation of thermodynamic parameters for both esterification and transesterification reactions. The lower value of activation energy and higher values of kinetic constants indicated a fast rate of reaction, which could be attributed to the physical effect of emulsification, in which the microturbulence generated due to radial motion of bubbles, creates an intimate mixing of the immiscible reactants causing the increase in the interfacial area, giving faster reaction kinetics. The positive values of Gibbs-free energy (ΔG), enthalpy (ΔH) and negative value of entropy (ΔS) revealed that both the esterification and transesterification were non-spontaneous, endothermic and endergonic reactions. Therefore, the present work has not only established the escalation obtained due to ultrasonication but also exemplified the two-step approach for synthesis of biodiesel from non-edible kusum oil based on the use of heterogeneous catalyst for the transesterification step.

Cyanolipids ofCardiospermum halicacabum L. and other sapindaceous seed oils

Abstract: A number of sapindaceous seed oils have been investigated with respect to their cyanolipid constituents. All but one of the oils have this new class of lipids in amounts ranging from 13% to 55%. These cyanolipids are of four different types, but all consist of long-chain fatty acids esterified with an unsaturated isoprenoid hydroxy- or dihydroxynitrile. The large amounts of C20 acids usually found in these oils indicate an appreciable cyanolipid content because such acids are preferentially incorporated in nitrile-containing fractions.Cardiospermum halicacabum L. seed oil was shown to contain 49% of a diester having two fatty acid moieties esterified with 1-cyano-2-hydroxymethylprop-2-ene-1-ol and 6% of another diester derived from 1-cyano-2-hydroxymethylprop-1-ene-3-ol. Treatment of the latter diester with methanolic hydrogen chloride produces methyl 4,4-dimethoxy-3-(methoxymethyl) butyrate from the dihydroxynitrile moiety.

Analysis of complex lipid mixtures by thin-layer chromatography and complementary methods

Abstract: Further work has been done on the application of thin-layer adsorption chromatography to the fractionation of complex lipid mixtures into classes.

The quantitative analysis of triglyceride mixtures by thin layer chromatography on silica impregnated with silver nitrate

Abstract: The paper describes a procedure involving thin layer chromatography on silica impregnated with silver nitrate, which makes possible the separation of synthetic and natural glyceride mixtures into classes according to their degree of unsaturation, and within those classes the resolution of certain isomeric unsaturated glycerides. The separations depend upon the ability of compounds having an olefinic double bond to form co-ordination complexes with the silver ion.

Chemical technology and analysis of oils, fats, and waxes

Abstract: THE well-known work of the late Dr. Lewkowitsch was reviewed at some length in these columns on the appearance of the fourth edition some four years ago (NATURE, August 19, 1909). In view of the stage of transition through which the subject of fat analysis is now passing, the author would have preferred to wait a little longer before bringing out the present edition, but the exhaustion of the previous issue precluded further delay.Chemical Technology and Analysis of Oils, Fats, and Waxes.By Dr. J. Lewkowitsch. Fifth edition, entirely re-written and enlarged. Vol. i. Pp. xxiii + 668. (London: Macmillan and Co., Ltd.) Price 25s. net.

Neuere Ergebnisse auf dem Gebiet der Isolierung und Analytik von Phosphatiden und Glykolipiden

Abstract: Mit Hilfe eines neuen papierchromatographischen Verfahrens, unter Einsatz der bisher auf diesem Gebiet noch nicht angewendeten Dunnschicht-Chromatographie und durch die gezielte Verwendung der Craig-Verteilung und IR-Spektroskopie konnten neue Verbindungen nachgewiesen, isoliert und identifiziert werden. Die Papier-Chromatographie gestattet neben der qualitativen Analyse von Lipoidgesamtextrakten die quantitative Bestimmung aller in diesen Extrakten enthaltenen Phosphatide und Glykolipide, so das nunmehr systematische vergleichende Untersuchungen moglich sind. New Results in the Isolating and Analysis of Phosphatides and Glycolipids With the help of thin layer chromatography and paperchromatography and applying the Craig-distribution and IR-spectroscopy new compounds could be proved, isolated and identified. Paper chromatography allows the qualitative analysis of the lipid extracts and the quantitative determination of the phosphatides and glycolipids, contained in the lipid extracts, so that systematic comparative studies are now possible.