Uzhhorod National University

About: Uzhhorod National University is a education organization based out in Uzhhorod, Ukraine. It is known for research contribution in the topics: Raman spectroscopy & Laser. The organization has 1089 authors who have published 1056 publications receiving 5187 citations. The organization is also known as: State Higher Education Establishment "Uzhhorod National University" & Uzhhorod State University.

New Indicators for Determination of Acid Number in Diesel Fuel Containing Biodiesel

Abstract: A simple and green visual method for determination of Total Acid Number (TAN) is proposed for analysis of different engine fuels, especially biodiesel, its raw materials and blends with petroleum fuels. Two 4-hydroxystyryl N-octylpyridinium bromides dyes: 4-[-2-(4-hydroxy-3-methoxyphenyl) ethenyl]-1-octylpyridinium bromide and 4-[-2-(4-hydroxy-3,5-dymethylphenyl) ethenyl]-1-octylpyridinium bromide were used as indicators. Determination of TAN in butanol medium in the presence of 10−5–10−4 mol/L of the indicator have shown a high color contrast. Well-marked transition from pale yellow to blue/violet merocyanine form provides for determination of more than 0.01 mg/g of free fatty acids and more strong acids with RSD 1–5%. For the vast majority of samples, the value of the acid numbers found by the proposed method is in good agreement with the data obtained according to the standard ASTM D664-11 method. The optimal conditions for analysis of TAN in diesel samples were found. Particular attention is paid to the FTIR-spectrometric determination of biodiesel content in commercial diesel fuel samples. The content of biodiesel with a characteristic peak in the region that is responsible for the carbonyl group (1730–1750 cm−1) can be seen on the IR spectra.

Pressure Effect on Sn2P2Se6 Type Incommensurate Crystals

Abstract: A theoretical analysis of pressure dependence of the incommensurate phase temperature interval and wavevector modulation in Sn2P2Se6 incommensurate ferroelectric is performed within the framework of phenomenological approach.

A criterion for testing hypotheses about the covariance function of a stationary Gaussian stochastic process

Abstract: We consider a measurable stationary Gaussian stochastic process. A criterion for testing hypotheses about the covariance function of such a process using estimates for its norm in the space $L_p(\mathbb {T}),\,p\geq1$, is constructed.

Spectral Characteristics of a Barrier Discharge in Cadmium Dihalide Vapor-Inert Gas Mixtures

Abstract: Spectral characteristics of a barrier-discharge plasma produced in atmospheric-pressure mixtures of cadmium diiodide and cadmium dibromide vapors with neon, krypton, and xenon at a repetition rate of sine voltage pulses up to 130 kHz are studied. The emission from the discharge is studied within the spectral range 200–900 nm with a resolution of 0.05 nm. Emission of exciplex molecules CdI(B → X) and CdBr(C, B → X), and cadmium and inert gas atoms is revealed, as well as emission of exciplex molecules XeI(B → X, A) and XeBr(B → X, A) in xenon-containing mixtures. The emission of xenon halides prevails in the spectra at a mixture temperature up to 200°C. With a further temperature increase, the emission of cadmium halides becomes dominating. It is ascertained that the most intense emissions of CdI(B → X) and CdI2/CdBr2/Xe/Kr and CdBr(B → X) molecules are observed, respectively, in CdI2/CdBr2/Xe/Kr and CdI2/CdBr2/Xe mixtures. The cadmium dihalide-inert gas mixtures are of interest for the use as a radiating gas in a multiwavelength and broadband excilamp emitting in the UV and visible spectral ranges.

Excimer source of radiation for photobiology

Abstract: A gas-discharge excimer source of visible radiation employing a mixture of mercury diiodide vapor, mercury dibromide vapor, and helium is studied. The emission spectrum of the source covers the range from 370 to 510 nm. About 90% of the radiation power is concentrated in the blue-green spectral region.