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An electron acceptor challenging fullerenes for efficient polymer solar cells.

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TLDR
A novel non-fullerene electron acceptor (ITIC) that overcomes some of the shortcomings of fullerene acceptors, for example, weak absorption in the visible spectral region and limited energy-level variability, is designed and synthesized.
Abstract
A novel non-fullerene electron acceptor (ITIC) that overcomes some of the shortcomings of fullerene acceptors, for example, weak absorption in the visible spectral region and limited energy-level variability, is designed and synthesized. Fullerene-free polymer solar cells (PSCs) based on the ITIC acceptor are demonstrated to exhibit power conversion effi ciencies of up to 6.8%, a record for fullerene-free PSCs.

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Citations
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Journal ArticleDOI

A–D–A small molecule acceptors with ladder-type arenes for organic solar cells

TL;DR: In this article, the authors collected the reported high-efficiency A-D-A SMAs according to the ring number of the ladder-type donor core in their centers and summarized the evolution process of these molecular structures and their photovoltaic parameters.
Journal ArticleDOI

High-Performance Fused Ring Electron Acceptor–Perovskite Hybrid

TL;DR: Time-resolved photoluminescence and transient absorption measurements reveal that FREA facilitates efficient electron extraction and collection and suggest faster charge transfer and reduced charge recombination in solar cells based on FREA-perovskite hybrid films.
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Small Molecules Based on Alkyl/Alkylthio-thieno[3,2-b]thiophene-Substituted Benzo[1,2-b:4,5-b′]dithiophene for Solution-Processed Solar Cells with High Performance

TL;DR: In this paper, two acceptor-donor-acceptor small molecules based on thieno[3,2b]thiophene-substituted benzo[1,2-b:4,5-b′]dithiophene were designed and synthesized.
References
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Journal ArticleDOI

Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
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Enhanced power-conversion efficiency in polymer solar cells using an inverted device structure

TL;DR: In this article, the authors showed that PFN can be incorporated into polymer light-emitting devices (PLEDs) to enhance electron injection from high-work-function metals such as aluminium (work function w of 4.3 eV) and gold (w ¼ 5.2 eV).
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Semiconducting π-conjugated systems in field-effect transistors: a material odyssey of organic electronics.

TL;DR: The focus of this review will be on the performance analysis of π-conjugated systems in OFETs, a kind of device consisting of an organic semiconducting layer, a gate insulator layer, and three terminals that provide an important insight into the charge transport of ρconjugate systems.
Journal ArticleDOI

A polymer tandem solar cell with 10.6% power conversion efficiency

TL;DR: The development of a high-performance low bandgap polymer that enables a solution processed tandem solar cell with certified 10.6% power conversion efficiency under standard reporting conditions, which is the first certified polymer solar cell efficiency over 10%.
Journal ArticleDOI

Molecular design of photovoltaic materials for polymer solar cells: toward suitable electronic energy levels and broad absorption.

TL;DR: This Account discusses the basic requirements and scientific issues in the molecular design of high efficiency photovoltaic molecules, and summarizes recent progress in electronic energy level engineering and absorption spectral broadening of the donor and acceptor photvoltaic materials by my research group and others.
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