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An electron acceptor challenging fullerenes for efficient polymer solar cells.

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TLDR
A novel non-fullerene electron acceptor (ITIC) that overcomes some of the shortcomings of fullerene acceptors, for example, weak absorption in the visible spectral region and limited energy-level variability, is designed and synthesized.
Abstract
A novel non-fullerene electron acceptor (ITIC) that overcomes some of the shortcomings of fullerene acceptors, for example, weak absorption in the visible spectral region and limited energy-level variability, is designed and synthesized. Fullerene-free polymer solar cells (PSCs) based on the ITIC acceptor are demonstrated to exhibit power conversion effi ciencies of up to 6.8%, a record for fullerene-free PSCs.

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Citations
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Journal ArticleDOI

Recent advances in stability of organic solar cells

TL;DR: The mechanisms of the instability in OSC devices are discussed, a series of solutions that improve the stability are proposed and some guidelines to address the instability of OSCs for feasible commercialization in the future are provided.
Journal ArticleDOI

Conjugated polymer acceptors based on fused perylene bisimides with a twisted backbone for non-fullerene solar cells

TL;DR: In this paper, a new strategy to use fused and twisted conjugated backbones to construct conjugations small molecules and polymers as electron acceptors for non-fullerene solar cells was presented.
Journal ArticleDOI

Effect of Side-Chain Engineering of Bithienylbenzodithiophene-alt-fluorobenzotriazole-Based Copolymers on the Thermal Stability and Photovoltaic Performance of Polymer Solar Cells

TL;DR: Wang et al. as discussed by the authors designed and synthesized three new 2D-conjugated polymers J62, J63, and J64 with different types of side chains to further investigate the effect of side chain on their physicochemical and photovoltaic properties.
Journal ArticleDOI

Multi-component non-fullerene acceptors with tunable bandgap structures for efficient organic solar cells

TL;DR: A ternary organic solar cell, consisting of two compatible non-fullerene acceptors and one wide band-gap donor, with a high efficiency of over 14% is reported in this paper.
Journal ArticleDOI

Isomeric Effects of Solution Processed Ladder-Type Non-Fullerene Electron Acceptors

TL;DR: In this paper, the role of electronic structure and thin film morphology is investigated in determining charge transfer and electron coupling due to orbital interactions in two isomeric non-fullerene acceptors with the structure of acceptor-donor acceptor.
References
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Journal ArticleDOI

Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
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Enhanced power-conversion efficiency in polymer solar cells using an inverted device structure

TL;DR: In this article, the authors showed that PFN can be incorporated into polymer light-emitting devices (PLEDs) to enhance electron injection from high-work-function metals such as aluminium (work function w of 4.3 eV) and gold (w ¼ 5.2 eV).
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Semiconducting π-conjugated systems in field-effect transistors: a material odyssey of organic electronics.

TL;DR: The focus of this review will be on the performance analysis of π-conjugated systems in OFETs, a kind of device consisting of an organic semiconducting layer, a gate insulator layer, and three terminals that provide an important insight into the charge transport of ρconjugate systems.
Journal ArticleDOI

A polymer tandem solar cell with 10.6% power conversion efficiency

TL;DR: The development of a high-performance low bandgap polymer that enables a solution processed tandem solar cell with certified 10.6% power conversion efficiency under standard reporting conditions, which is the first certified polymer solar cell efficiency over 10%.
Journal ArticleDOI

Molecular design of photovoltaic materials for polymer solar cells: toward suitable electronic energy levels and broad absorption.

TL;DR: This Account discusses the basic requirements and scientific issues in the molecular design of high efficiency photovoltaic molecules, and summarizes recent progress in electronic energy level engineering and absorption spectral broadening of the donor and acceptor photvoltaic materials by my research group and others.
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