Journal ArticleDOI
Chemical Cleavage of Layered Carbon Nitride with Enhanced Photoluminescent Performances and Photoconduction
TLDR
Bulk polymeric carbon nitride could be utilized as a layered precursor to preparecarbon nitride nanostructures such as nanorods, nanoleaves and quantum dots by chemical tailoring to open up an avenue for doped nanocarbon in developing photoelectrical devices and sensors.Abstract:
Graphene quantum dots (GQDs) and carbon dots (C-dots) have various alluring properties and potential applications, but they are often limited by unsatisfied optical performance such as low quantum yield, ambiguous fluorescence emission mechanism, and narrow emission wavelength Herein, we report that bulk polymeric carbon nitride could be utilized as a layered precursor to prepare carbon nitride nanostructures such as nanorods, nanoleaves and quantum dots by chemical tailoring As doped carbon materials, these carbon nitride nanostructures not only intrinsically emitted UV lights but also well inherited the explicit photoluminescence mechanism of the bulk pristine precursor, both of which were rarely reported for GQDs and C-dots Especially, carbon nitride quantum dots (CNQDs) had a photoluminescence quantum yield (QY) up to 46%, among the highest QY for metal-free quantum dots so far As examples, the CNQDs were utilized as a photoluminescence probe for rapid detection of Fe3+ with a detection limit of 1read more
Citations
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Graphitic Carbon Nitride (g-C3N4)-Based Photocatalysts for Artificial Photosynthesis and Environmental Remediation: Are We a Step Closer To Achieving Sustainability?
TL;DR: It is anticipated that this review can stimulate a new research doorway to facilitate the next generation of g-C3N4-based photocatalysts with ameliorated performances by harnessing the outstanding structural, electronic, and optical properties for the development of a sustainable future without environmental detriment.
Journal ArticleDOI
A review on g-C3N4-based photocatalysts
TL;DR: In this paper, the fundamental mechanism of heterogeneous photocatalysis, advantages, challenges and the design considerations of g-C3N4-based photocatalysts are summarized, including their crystal structural, surface phisicochemical, stability, optical, adsorption, electrochemical, photoelectrochemical and electronic properties.
Journal ArticleDOI
Semiconductor polymeric graphitic carbon nitride photocatalysts: the “holy grail” for the photocatalytic hydrogen evolution reaction under visible light
TL;DR: A panorama of the latest advancements in the rational design and development of semiconductor polymeric graphitic carbon nitride (g-C3N4) photocatalysts for visible-light-induced hydrogen evolution reaction (HER) is presented in this paper.
Journal ArticleDOI
Molecular engineering of polymeric carbon nitride: advancing applications from photocatalysis to biosensing and more
TL;DR: This review summarizes and highlights a panorama of the latest advancements related to the design and construction of the molecular structure of CN, such as by doping and copolymerization, engineering of the polymerization degree, coordination interaction, covalent and noncovalent functionalization, and modulation of intralayer hydrogen bonding.
Journal ArticleDOI
Quantum dots derived from two-dimensional materials and their applications for catalysis and energy
TL;DR: The synthesis methods and the properties of quantum dots derived from the atomically-thin two-dimensional sheets are discussed and their applications in electrocatalysis, photocatalysis, supercapacitors, batteries, and photovoltaics are emphasized.
References
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Quantum-sized carbon dots for bright and colorful photoluminescence.
Ya-Ping Sun,Bing Zhou,Yi Lin,Wei Wang,K. A. Shiral Fernando,Pankaj Pathak,Mohammed J. Meziani,Barbara A. Harruff,Xin Wang,Haifang Wang,Pengju G. Luo,Hua Yang,Muhammet E. Köse,Bailin Chen,L. Monica Veca,Su-Yuan Xie +15 more
TL;DR: It is reported that nanoscale carbon particles (carbon dots) upon simple surface passivation are strongly photoluminescent in both solution and the solid state.
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Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway
Juan Liu,Yang Liu,Naiyun Liu,Yuzhi Han,Xing Zhang,Hui Huang,Yeshayahu Lifshitz,Yeshayahu Lifshitz,Shuit-Tong Lee,Jun Zhong,Zhenhui Kang +10 more
TL;DR: The design and fabrication of a metal-free carbon nanodot–carbon nitride (C3N4) nanocomposite is reported and its impressive performance for photocatalytic solar water splitting is demonstrated.
Journal ArticleDOI
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Shoujun Zhu,Qingnan Meng,Lei Wang,Junhu Zhang,Yubin Song,Han Jin,Kai Zhang,Hongchen Sun,Hai-Yu Wang,Bai Yang +9 more
TL;DR: A facile and highoutput strategy for the fabrication of CDs, which is suitable for industrial-scale production and is almost equal to fluorescent dyes, is discussed.
Journal ArticleDOI
Hydrothermal route for cutting graphene sheets into blue-luminescent graphene quantum dots
TL;DR: This work reports on a novel and simple hydrothermal approach for the cutting of GSs into surface-functionalized GQDs, which were found to exhibit bright blue photoluminescence (PL), which has never been observed in GSs and GNRs owing to their large lateral sizes.
Journal ArticleDOI
Exfoliated Graphitic Carbon Nitride Nanosheets as Efficient Catalysts for Hydrogen Evolution Under Visible Light
Shubin Yang,Yongji Gong,Jinshui Zhang,Liang Zhan,Lulu Ma,Zheyu Fang,Robert Vajtai,Xinchen Wang,Pulickel M. Ajayan +8 more
TL;DR: Graphitic carbon nitride nanosheets are extracted via simple liquid-phase exfoliation of a layered bulk material, g-C3N4, to exhibit excellent photocatalytic activity for hydrogen evolution under visible light.