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Recent advances and challenges in designing stimuli-responsive polymers

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TLDR
In this article, a review examines physico-chemical requirements necessary to achieve stimuli-responsiveness in heterogeneous polymer networks as well as discusses recent developments and future trends while individual structural components of polymeric networks are responsible for localized chainresponsiveness, desirable spatial and energetic network properties are necessary for collective and orchestrated responsiveness to external or internal stimuli.
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This article is published in Progress in Polymer Science.The article was published on 2010-01-01. It has received 866 citations till now.

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Citations
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Using the dynamic bond to access macroscopically responsive structurally dynamic polymers

TL;DR: The emergence of a new trend in the design of adaptive materials that involves the use of reversible chemistry to programme a response that originates at the most fundamental (molecular) level is described.
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Self-healing polymeric materials

TL;DR: This review outlines the recent advances in the field of self-healing polymers, and the primary classes are the covalent bonding, supramolecular assemblies, ionic interactions, chemo-mechanical self- healing, and shape memory polymers.
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New directions in thermoresponsive polymers.

TL;DR: By highlighting recent examples of newly developed thermoresponsive polymer systems, it is hoped to promote the development of new generations of smart materials.
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Recent progress in shape memory polymer: New behavior, enabling materials, and mechanistic understanding

TL;DR: Progress in new shape memory enabling mechanisms and triggering methods, variations of in shape memory forms (shape memory surfaces, hydrogels, and microparticles), newshape memory behavior (multi-SME and two-way-S ME), and novel fabrication methods are reviewed.
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A review of stimuli-responsive shape memory polymer composites

TL;DR: An up-to-date review on shape memory polymer composites with potential applications in biomedical devices, aerospace, textiles, civil engineering, bionics engineering, energy, electronic engineering, and household products is presented.
References
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Journal ArticleDOI

Fluoromethacrylate-Containing Colloidal Dispersions: Phospholipid-Assisted Synthesis, Particle Morphology, and Temperature-Responsive Stratification

TL;DR: In this paper, the morphologies of F-containing colloidal particles synthesized in an aqueous phase in the presence of bioactive dispersing agents are investigated and morphologies depend upon MMA/nBA ratios and lead to significantly different surface properties.
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Electroresponsive Behavior of Gelatin/Alginate Semi‐interpenetrating Polymer Network Membranes Under Direct‐Current Electric Field

TL;DR: In this paper, a semi-interpenetrating polymer network (semi-IPN) was prepared by the introduction of linear alginate into a crosslinked gelatin hydrogel network, and their swelling properties and electroresponsive behavior were studied.
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From nematic emulsions to polymer dispersed liquid crystals

TL;DR: In this paper, the polymerization process which converts nematic emulsions in polymer dispersed liquid crystals has been investigated, in particular, the electro-optica properties of the resulting polymer.
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New Thermal Transitions in Stimuli-Responsive Copolymer Films

TL;DR: In this article, a new thermal relaxations in stimuli-responsive solid-phase copolymers detected by differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA) were reported.
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Intelligent Polymeric Coatings; Current and Future Advances

TL;DR: In this paper, the physicico-chemical aspects of the process associated with the film formation are discussed, and the design of responsive and proactive polymeric chains mimicking biological systems are essential building blocks for future developments of smart coatings.
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