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Recent advances and challenges in designing stimuli-responsive polymers

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TLDR
In this article, a review examines physico-chemical requirements necessary to achieve stimuli-responsiveness in heterogeneous polymer networks as well as discusses recent developments and future trends while individual structural components of polymeric networks are responsible for localized chainresponsiveness, desirable spatial and energetic network properties are necessary for collective and orchestrated responsiveness to external or internal stimuli.
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This article is published in Progress in Polymer Science.The article was published on 2010-01-01. It has received 866 citations till now.

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Citations
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Using the dynamic bond to access macroscopically responsive structurally dynamic polymers

TL;DR: The emergence of a new trend in the design of adaptive materials that involves the use of reversible chemistry to programme a response that originates at the most fundamental (molecular) level is described.
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Self-healing polymeric materials

TL;DR: This review outlines the recent advances in the field of self-healing polymers, and the primary classes are the covalent bonding, supramolecular assemblies, ionic interactions, chemo-mechanical self- healing, and shape memory polymers.
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New directions in thermoresponsive polymers.

TL;DR: By highlighting recent examples of newly developed thermoresponsive polymer systems, it is hoped to promote the development of new generations of smart materials.
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Recent progress in shape memory polymer: New behavior, enabling materials, and mechanistic understanding

TL;DR: Progress in new shape memory enabling mechanisms and triggering methods, variations of in shape memory forms (shape memory surfaces, hydrogels, and microparticles), newshape memory behavior (multi-SME and two-way-S ME), and novel fabrication methods are reviewed.
Journal ArticleDOI

A review of stimuli-responsive shape memory polymer composites

TL;DR: An up-to-date review on shape memory polymer composites with potential applications in biomedical devices, aerospace, textiles, civil engineering, bionics engineering, energy, electronic engineering, and household products is presented.
References
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Journal ArticleDOI

Switching of Polymer Brushes

TL;DR: In this paper, a brush-like monolayers composed of two different polymers, polystyrene and poly(2-vinylpyridine), are grafted by radical polymerization on the surface of silicon wafers.
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Synthesis and application of thermally reversible heterogels for drug delivery

TL;DR: In this paper, a new heterogeneous, thermally reversible hydrogel has been synthesized by γ-irradiation of solutions of N-isopropylacrylamide (NIPAAm) and bis-vinyl-terminated polydimethylsiloxane (VTPDMS).
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Peptide-directed self-assembly of hydrogels.

TL;DR: Structural factors governing the self-assembly of molecules into precisely defined three-dimensional structures (hydrogels) are reviewed and the incorporation of peptide motifs into hybrid systems enhances design opportunities for new biomaterials when compared to individual components.
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Hydration and Phase Behavior of Poly(N-vinylcaprolactam) and Poly(N-vinylpyrrolidone) in Water

TL;DR: In this article, the phase transitions of poly(N-vinylcaprolactam) (PVCL) and poly(nvinylpyrrolidone)(PVPy) in H2O and D2O were investigated by turbidimetry, differential scanning calorimetry (DSC), and Fourier transform infrared (FTIR) spectroscopy.
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Lateral versus perpendicular segregation in mixed polymer brushes.

TL;DR: Grafting of incompatible polymers on a substrate prevents macrophase separation and the chains self-assemble laterally, in which the unfavored component forms clusters.
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