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Recent advances and challenges in designing stimuli-responsive polymers

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TLDR
In this article, a review examines physico-chemical requirements necessary to achieve stimuli-responsiveness in heterogeneous polymer networks as well as discusses recent developments and future trends while individual structural components of polymeric networks are responsible for localized chainresponsiveness, desirable spatial and energetic network properties are necessary for collective and orchestrated responsiveness to external or internal stimuli.
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This article is published in Progress in Polymer Science.The article was published on 2010-01-01. It has received 866 citations till now.

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Citations
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Using the dynamic bond to access macroscopically responsive structurally dynamic polymers

TL;DR: The emergence of a new trend in the design of adaptive materials that involves the use of reversible chemistry to programme a response that originates at the most fundamental (molecular) level is described.
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Self-healing polymeric materials

TL;DR: This review outlines the recent advances in the field of self-healing polymers, and the primary classes are the covalent bonding, supramolecular assemblies, ionic interactions, chemo-mechanical self- healing, and shape memory polymers.
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New directions in thermoresponsive polymers.

TL;DR: By highlighting recent examples of newly developed thermoresponsive polymer systems, it is hoped to promote the development of new generations of smart materials.
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Recent progress in shape memory polymer: New behavior, enabling materials, and mechanistic understanding

TL;DR: Progress in new shape memory enabling mechanisms and triggering methods, variations of in shape memory forms (shape memory surfaces, hydrogels, and microparticles), newshape memory behavior (multi-SME and two-way-S ME), and novel fabrication methods are reviewed.
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A review of stimuli-responsive shape memory polymer composites

TL;DR: An up-to-date review on shape memory polymer composites with potential applications in biomedical devices, aerospace, textiles, civil engineering, bionics engineering, energy, electronic engineering, and household products is presented.
References
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Journal ArticleDOI

Light-induced shape-memory polymers

TL;DR: Polymers containing cinnamic groups can be deformed and fixed into pre-determined shapes—such as elongated films and tubes, arches or spirals—by ultraviolet light illumination and can recover their original shape at ambient temperatures when exposed to ultraviolet light of a different wavelength.
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Micellization of poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) triblock copolymers in aqueous solutions: Thermodynamics of copolymer association

TL;DR: In this article, a closed association model was used to describe the copolymer micellization process for the majority of the Pluronics and used to obtain the standard free energies, enthalpies, and entropies of micellisation.
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Synthetic matrix metalloproteinase-sensitive hydrogels for the conduction of tissue regeneration: Engineering cell-invasion characteristics

TL;DR: Gels used to deliver recombinant human bone morphogenetic protein-2 to the site of critical defects in rat cranium were completely infiltrated by cells and remodeled into bony tissue within 4 wk at a dose of 5 μg per defect.
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Force-induced activation of covalent bonds in mechanoresponsive polymeric materials

TL;DR: It is found that pronounced changes in colour and fluorescence emerge with the accumulation of plastic deformation, indicating that in these polymeric materials the transduction of mechanical force into the ring-opening reaction is an activated process.
Journal ArticleDOI

Light-driven motion of liquids on a photoresponsive surface

TL;DR: The light-driven motion of a fluid substance in a surface-modified glass tube suggests potential applicability to microscale chemical process systems.
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