Strong light-matter interactions in heterostructures of atomically thin films.
L. Britnell,Ricardo M. Ribeiro,Ricardo M. Ribeiro,Axel Eckmann,Rashid Jalil,Branson D. Belle,Artem Mishchenko,Yong-Jin Kim,Yong-Jin Kim,Roman V. Gorbachev,Thanasis Georgiou,Sergey V. Morozov,Alexander N. Grigorenko,Andre K. Geim,Cinzia Casiraghi,Cinzia Casiraghi,A. H. Castro Neto,K. S. Novoselov +17 more
TLDR
Transition metal dichalcogenides sandwiched between two layers of graphene produce an enhanced photoresponse, which allows development of extremely efficient flexible photovoltaic devices with photoresponsivity above 0.1 ampere per watt (corresponding to an external quantum efficiency of above 30%).Abstract:
The isolation of various two-dimensional (2D) materials, and the possibility to combine them in vertical stacks, has created a new paradigm in materials science: heterostructures based on 2D crystals. Such a concept has already proven fruitful for a number of electronic applications in the area of ultrathin and flexible devices. Here, we expand the range of such structures to photoactive ones by using semiconducting transition metal dichalcogenides (TMDCs)/graphene stacks. Van Hove singularities in the electronic density of states of TMDC guarantees enhanced light-matter interactions, leading to enhanced photon absorption and electron-hole creation (which are collected in transparent graphene electrodes). This allows development of extremely efficient flexible photovoltaic devices with photoresponsivity above 0.1 ampere per watt (corresponding to an external quantum efficiency of above 30%).read more
Citations
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2D materials and van der Waals heterostructures
TL;DR: Two-dimensional heterostructures with extended range of functionalities yields a range of possible applications, and spectrum reconstruction in graphene interacting with hBN allowed several groups to study the Hofstadter butterfly effect and topological currents in such a system.
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Recent Advances in Ultrathin Two-Dimensional Nanomaterials
Chaoliang Tan,Xiehong Cao,Xiehong Cao,Xue-Jun Wu,Qiyuan He,Jian Yang,Xiao Zhang,Junze Chen,Wei Zhao,Shikui Han,Gwang-Hyeon Nam,Melinda Sindoro,Hua Zhang +12 more
TL;DR: The unique advances on ultrathin 2D nanomaterials are introduced, followed by the description of their composition and crystal structures, and the assortments of their synthetic methods are summarized.
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Photodetectors based on graphene, other two-dimensional materials and hybrid systems
Frank H. L. Koppens,Thomas Mueller,Phaedon Avouris,Andrea C. Ferrari,Miriam S. Vitiello,Marco Polini +5 more
TL;DR: An overview and evaluation of state-of-the-art photodetectors based on graphene, other two-dimensional materials, and hybrid systems based on the combination of differentTwo-dimensional crystals or of two- dimensional crystals and other (nano)materials, such as plasmonic nanoparticles, semiconductors, quantum dots, or their integration with (silicon) waveguides are provided.
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Rediscovering black phosphorus as an anisotropic layered material for optoelectronics and electronics
Fengnian Xia,Han Wang,Yichen Jia +2 more
TL;DR: Black phosphorus (BP), the most stable allotrope of phosphorus with strong intrinsic in-plane anisotropy, is reintroduced to the layered-material family and shows great potential for thin-film electronics, infrared optoelectronics and novel devices in which anisotropic properties are desirable.
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Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage
Francesco Bonaccorso,Francesco Bonaccorso,Luigi Colombo,Guihua Yu,Meryl D. Stoller,Valentina Tozzini,Andrea C. Ferrari,Rodney S. Ruoff,Vittorio Pellegrini +8 more
TL;DR: Graphene and related two-dimensional crystals and hybrid systems showcase several key properties that can address emerging energy needs, in particular for the ever growing market of portable and wearable energy conversion and storage devices.
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