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Journal ArticleDOI

Thermal stability and electrical characteristics of ultrathin hafnium oxide gate dielectric reoxidized with rapid thermal annealing

TLDR
In this article, the dielectric properties of ultrathin hafnium oxide reoxidized with rapid thermal annealing (RTA) have been investigated and the leakage current was found to be less than 3×10−2 ǫA/cm2 at −1.5 V (i.e., ∼2 V below VFB).
Abstract
Dielectric properties of ultrathin hafnium oxide reoxidized with rapid thermal annealing (RTA) have been investigated. Capacitance equivalent oxide thickness (CET) of 45 A hafnium oxide was scaled down to ∼10 A with a leakage current less than 3×10−2 A/cm2 at −1.5 V (i.e., ∼2 V below VFB). Leakage current increase due to crystallization was not observed even after 900 °C rapid thermal annealing (RTA), but CET did increase after high temperature RTA due to the interfacial layer growth and possible silicate formation in the HfO2 film.

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Citations
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Journal ArticleDOI

High-κ gate dielectrics: Current status and materials properties considerations

TL;DR: In this paper, a review of the literature in the area of alternate gate dielectrics is given, based on reported results and fundamental considerations, the pseudobinary materials systems offer large flexibility and show the most promise toward success.
Journal ArticleDOI

High dielectric constant gate oxides for metal oxide Si transistors

TL;DR: In this article, a review of the development of high-k gate oxides such as hafnium oxide (HFO) and high-K oxides is presented, with the focus on the work function control in metal gate electrodes.
Journal ArticleDOI

High dielectric constant oxides

TL;DR: In this article, the choice of oxides, their structural and metallurgical behaviour, atomic diffusion, their deposition, interface structure and reactions, their electronic structure, bonding, band offsets, mobility degradation, flat band voltage shifts and electronic defects are discussed.
Journal ArticleDOI

High-K materials and metal gates for CMOS applications

TL;DR: In this article, a review of the high-K gate stack is presented, including the choice of oxides, their deposition, their structural and metallurgical behaviour, atomic diffusion, interface structure, their electronic structure, band offsets, electronic defects, charge trapping and conduction mechanisms, reliability, mobility degradation and oxygen scavenging.
Journal ArticleDOI

Thermal stability and structural characteristics of HfO2 films on Si (100) grown by atomic-layer deposition

TL;DR: The thermal stability and structural characteristics for gate stack structure of HfO2 dielectrics deposited by atomic-layer deposition (ALD) were investigated in this article, where an interfacial layer of hafnium silicate with an amorphous structure was grown on the oxidized Si substrate at an initial growth stage.
References
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Journal ArticleDOI

Thermodynamic stability of binary oxides in contact With silicon

TL;DR: In this paper, a comprehensive investigation of the thermo-dynamic stability of binary oxides in contact with silicon at 1000 K was conducted, including those involving ternary phases.
Journal ArticleDOI

Chemical vapor deposition and characterization of HfO2 films from organo-hafnium compounds

TL;DR: In this paper, fine-grained monoclinic HfO 2 films were characterized by using transmission electron microscopy, X-ray diffraction, electron microprobe analysis and measurements of dielectric and optical properties.
Journal ArticleDOI

The impact of high-/spl kappa/ gate dielectrics and metal gate electrodes on sub-100 nm MOSFETs

TL;DR: In this paper, the potential impact of high/spl kappa/ gate dielectrics on device short-channel performance is studied over a wide range of dielectric permittivities using a two-dimensional (2D) simulator implemented with quantum mechanical models.
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