Showing papers by "Ames Research Center published in 2001"

Life in Extreme Environments

Abstract: Each recent report of liquid water existing elsewhere in the Solar System has reverberated through the international press and excited the imagination of humankind. Why? Because in the past few decades we have come to realize that where there is liquid water on Earth, virtually no matter what the physical conditions, there is life. What we previously thought of as insurmountable physical and chemical barriers to life, we now see as yet another niche harbouring 'extremophiles'. This realization, coupled with new data on the survival of microbes in the space environment and modelling of the potential for transfer of life between celestial bodies, suggests that life could be more common than previously thought. Here we examine critically what it means to be an extremophile, and the implications of this for evolution, biotechnology and especially the search for life in the Universe.

Mars Global Surveyor Thermal Emission Spectrometer experiment: Investigation description and surface science results

Abstract: The Thermal Emission Spectrometer (TES) investigation on Mars Global Surveyor (MGS) is aimed at determining (1) the composition of surface minerals, rocks, and ices; (2) the temperature and dynamics of the atmosphere; (3) the properties of the atmospheric aerosols and clouds; (4) the nature of the polar regions; and (5) the thermophysical properties of the surface materials. These objectives are met using an infrared (5.8- to 50-μm) interferometric spectrometer, along with broadband thermal (5.1- to 150-μm) and visible/near-IR (0.3- to 2.9-μm) radiometers. The MGS TES instrument weighs 14.47 kg, consumes 10.6 W when operating, and is 23.6×35.5×40.0 cm in size. The TES data are calibrated to a 1-σ precision of 2.5−6×10−8 W cm−2 sr−1/cm−1, 1.6×10−6 W cm−2 sr−1, and ∼0.5 K in the spectrometer, visible/near-IR bolometer, and IR bolometer, respectively. These instrument subsections are calibrated to an absolute accuracy of ∼4×10−8 W cm−2 sr−1/cm−1 (0.5 K at 280 K), 1–2%, and ∼1–2 K, respectively. Global mapping of surface mineralogy at a spatial resolution of 3 km has shown the following: (1) The mineralogic composition of dark regions varies from basaltic, primarily plagioclase feldspar and clinopyroxene, in the ancient, southern highlands to andesitic, dominated by plagioclase feldspar and volcanic glass, in the younger northern plains. (2) Aqueous mineralization has produced gray, crystalline hematite in limited regions under ambient or hydrothermal conditions; these deposits are interpreted to be in-place sedimentary rock formations and indicate that liquid water was stable near the surface for a long period of time. (3) There is no evidence for large-scale (tens of kilometers) occurrences of moderate-grained (>50-μm) carbonates exposed at the surface at a detection limit of ∼10%. (4) Unweathered volcanic minerals dominate the spectral properties of dark regions, and weathering products, such as clays, have not been observed anywhere above a detection limit of ∼10%; this lack of evidence for chemical weathering indicates a geologic history dominated by a cold, dry climate in which mechanical, rather than chemical, weathering was the significant form of erosion and sediment production. (5) There is no conclusive evidence for sulfate minerals at a detection limit of ∼15%. The polar region has been studied with the following major conclusions: (1) Condensed CO2 has three distinct end-members, from fine-grained crystals to slab ice. (2) The growth and retreat of the polar caps observed by MGS is virtually the same as observed by Viking 12 Martian years ago. (3) Unique regions have been identified that appear to differ primarily in the grain size of CO2; one south polar region appears to remain as black slab CO2 ice throughout its sublimation. (4) Regional atmospheric dust is common in localized and regional dust storms around the margin and interior of the southern cap. Analysis of the thermophysical properties of the surface shows that (1) the spatial pattern of albedo has changed since Viking observations, (2) a unique cluster of surface materials with intermediate inertia and albedo occurs that is distinct from the previously identified low-inertia/bright and high-inertia/dark surfaces, and (3) localized patches of high-inertia material have been found in topographic lows and may have been formed by a unique set of aeolian, fluvial, or erosional processes or may be exposed bedrock.

Calculating free energies using average force

Abstract: A new, general formula that connects the derivatives of the free energy along the selected, generalized coordinates of the system with the instantaneous force acting on these coordinates is derived. The instantaneous force is defined as the force acting on the coordinate of interest so that when it is subtracted from the equations of motion the acceleration along this coordinate is zero. The formula applies to simulations in which the selected coordinates are either unconstrained or constrained to fixed values. It is shown that in the latter case the formula reduces to the expression previously derived by den Otter and Briels. If simulations are carried out without constraining the coordinates of interest, the formula leads to a new method for calculating the free energy changes along these coordinates. This method is tested in two examples - rotation around the C-C bond of 1,2-dichloroethane immersed in water and transfer of fluoromethane across the water-hexane interface. The calculated free energies are compared with those obtained by two commonly used methods. One of them relies on determining the probability density function of finding the system at different values of the selected coordinate and the other requires calculating the average force at discrete locations along this coordinate in a series of constrained simulations. The free energies calculated by these three methods are in excellent agreement. The relative advantages of each method are discussed.

Precipitating Condensation Clouds in Substellar Atmospheres

Abstract: We present a method to calculate vertical profiles of particle size distributions in condensation clouds of giant planets and brown dwarfs. The method assumes a balance between turbulent diffusion and precipitation in horizontally uniform cloud decks. Calculations for the Jovian ammonia cloud are compared with previous methods. An adjustable parameter describing the efficiency of precipitation allows the new model to span the range of predictions from previous models. Calculations for the Jovian ammonia cloud are found to be consistent with observational constraints. Example calculations are provided for water, silicate, and iron clouds on brown dwarfs and on a cool extrasolar giant planet.

Aspect-oriented programming: Introduction

Abstract: Computer science has experienced an evolution in programming languages and systems from the crude assembly and machine codes of the earliest computers through concepts such as formula translation, procedural programming, structured programming, functional programming, logic programming, and programming with abstract data types. Each of these steps in programming technology has advanced our ability to achieve clear separation of concerns at the source code level. Currently, the dominant programming paradigm is object-oriented programming - the idea that one builds a software system by decomposing a problem into objects and then writing the code of those objects. Such objects abstract together behavior and data into a single conceptual and physical entity. Object-orientation is reflected in the entire spectrum of current software development methodologies and tools - we have OO methodologies, analysis and design tools, and OO programming languages. Writing complex applications such as graphical user interfaces, operating systems, and distributed applications while maintaining comprehensible source code has been made possible with OOP. Success at developing simpler systems leads to aspirations for greater complexity. Object orientation is a clever idea, but has certain limitations. We are now seeing that many requirements do not decompose neatly into behavior centered on a single locus. Object technology has difficulty localizing concerns invoking global constraints and pandemic behaviors, appropriately segregating concerns, and applying domain-specific knowledge. Post-object programming (POP) mechanisms that look to increase the expressiveness of the OO paradigm are a fertile arena for current research. Examples of POP technologies include domain-specific languages, generative programming, generic programming, constraint languages, reflection and metaprogramming, feature-oriented development, views/viewpoints, and asynchronous message brokering. (Czarneclu and Eisenecker s book includes a good survey of many of these technologies).

The β Pictoris Moving Group

Abstract: Following the 1983 IRAS detection and subsequent imaging of its extensive dusty circumstellar disk, β Pictoris became the prototypical and most studied example of a potential forming planetary system. Here we report the identification of 17 star systems, each with one or more characteristics indicative of extreme youth, that are moving through space together with β Pic. This diverse set of ~12 million yr old star systems, which includes a ~35 Jupiter mass brown dwarf, and a wide assortment of dusty circumstellar disks, is the comoving, youthful group closest to Earth. Their unique combination of youth and proximity to Earth makes group members—many of which have masses similar to that of the Sun—prime candidates for imaging of warm planets and dusty circumstellar disks with ground- and space-based telescopes.

Solar system objects observed in the Sloan Digital Sky Survey commissioning data

Abstract: We discuss measurements of the properties of D13,000 asteroids detected in 500 deg2 of sky in the Sloan Digital Sky Survey (SDSS) commissioning data. The moving objects are detected in the magnitude range 14 \ r* \ 21.5, with a baseline of D5 minutes, resulting in typical velocity errors of D3%. Extensive tests show that the sample is at least 98% complete, with a contamination rate of less than 3%. We —nd that the size distribution of asteroids resembles a broken power law, independent of the heliocentric distance: D~2.3 for 0.4 km, and D~4 for 5

Far-Infrared Spectroscopy of Normal Galaxies: Physical Conditions in the Interstellar Medium

Abstract: The most important cooling lines of the neutral interstellar medium (ISM) lie in the far-infrared (FIR). We present measurements by the Infrared Space Observatory Long Wavelength Spectrometer of seven lines from neutral and ionized ISM of 60 normal, star-forming galaxies. The galaxy sample spans a range in properties such as morphology, FIR colors (indicating dust temperature), and FIR/blue ratios (indicating star formation activity and optical depth). In two-thirds of the galaxies in this sample, the [C II] line flux is proportional to FIR dust continuum. The other one-third show a smooth decline in L[C II]/LFIR with increasing Fν(60 μm)/Fν(100 μm) and LFIR/LB, spanning a range of a factor of more than 50. Two galaxies at the warm and active extreme of the range have L[C II]/LFIR < 2 × 10-4 (3 σ upper limit). This is due to increased positive grain charge in the warmer and more active galaxies, which leads to less efficient heating by photoelectrons from dust grains. The ratio of the two principal photodissociation region (PDR) cooling lines L[O I]/L[C II] shows a tight correlation with Fν(60 μm)/Fν(100 μm), indicating that both gas and dust temperatures increase together. We derive a theoretical scaling between [N II] (122 μm) and [C II] from ionized gas and use it to separate [C II] emission from neutral PDRs and ionized gas. Comparison of PDR models of Kaufman et al. with observed ratios of (1) L[O I]/L[C II] and (L[C II] + L[O I])/LFIR and (2) L[O I]/LFIR and Fν(60 μm)/Fν(100 μm) yields far-UV flux G0 and gas density n. The G0 and n values estimated from the two methods agree to better than a factor of 2 and 1.5, respectively, in more than half the sources. The derived G0 and n correlate with each other, and G0 increases with n as G0 ∝ nα, where α ≈ 1.4 . We interpret this correlation as arising from Stromgren sphere scalings if much of the line and continuum luminosity arises near star-forming regions. The high values of PDR surface temperature (270-900 K) and pressure (6 × 104-1.5 × 107 K cm-3) derived also support the view that a significant part of grain and gas heating in the galaxies occurs very close to star-forming regions. The differences in G0 and n from galaxy to galaxy may be due to differences in the physical properties of the star-forming clouds. Galaxies with higher G0 and n have larger and/or denser star-forming clouds.

Biogenic methane, hydrogen escape, and the irreversible oxidation of early Earth.

Abstract: The low O2 content of the Archean atmosphere implies that methane should have been present at levels ∼102 to 103 parts per million volume (ppmv) (compared with 1.7 ppmv today) given a plausible biogenic source. CH4 is favored as the greenhouse gas that countered the lower luminosity of the early Sun. But abundant CH4 implies that hydrogen escapes to space (↑space) orders of magnitude faster than today. Such reductant loss oxidizes the Earth. Photosynthesis splits water into O2 and H, and methanogenesis transfers the H into CH4. Hydrogen escape after CH4 photolysis, therefore, causes a net gain of oxygen [CO2 + 2H2O → CH4 + 2O2 → CO2 + O2 + 4H(↑space)]. Expected irreversible oxidation (∼1012 to 1013 moles oxygen per year) may help explain how Earth9s surface environment became irreversibly oxidized.

Chemical-Kinetic Parameters of Hyperbolic Earth Entry

Abstract: Chemical-kinetic parameters governing the e ow in the shock layer over a heat shield of a blunt body entering Earth’ s atmosphere from a hyperbolic orbit are derived. By the use of the assumption that the heat shield is made of carbon phenolic and by allowing for an arbitrary rateof pyrolysis-gasinjection, chemical reactions occurring in the shock layer are postulated, and the collision integrals governing the transport properties, the rate coefe cients of the reactions, and the parameters needed for the bifurcation model and for the e nite-rate kinetic wall boundary conditions are determined using the best available techniques. Sample e owe eld calculations are performed using this set of parameters to show that the heating and surface removal rates are substantially smaller than calculated using theexisting setofsuch parameters and traditionalassumptionsof gas ‐surfaceequilibrium and quasi-steadystate ablation.

Size-selective Concentration of Chondrules and Other Small Particles in Protoplanetary Nebula Turbulence

Abstract: Size-selective concentration of particles in a weakly turbulent protoplanetary nebula may be responsible for the initial collection of chondrules and other constituents into primitive bodY precursors. This paper presents the main elements of this process of turbulent concentration. In the terrestrial planet region. both the characteristic size and size distribution of chondrules are explained. "Fluffier" particles would be concentrated in nebula regions which were at a lower density and/or more intensely turbulent. The spatial distribution of concentrated particle density obeys multifractal scaling, suggesting a close tie to the turbulent cascade process. This scaling behavior allows predictions of the probability distributions for concentration in the protoplanetary nebula to be made. Large concentration factors (less than 10(exp 5)) are readily obtained, implying that numerous zones of particle density significantly exceeding the gas density could exist. If most of the available solids were actually in chondrule sized particles, the ensuing particle mass density would become so large that the feedback effects on gas turbulence due to mass loading could no longer be neglected. This paper describes the process, presenting its basic elements and some implications, without including the effects of mass loading.

Spectroscopic and theoretical investigations of vibrational frequencies in binary unsaturated transition-metal carbonyl cations, neutrals, and anions.

Abstract: Figure 18 presents the C-O stretching vibrational frequencies of the first-row transition-metal monocarbonyl cations, neutrals, and anions in solid neon; similar diagrams have been reported for neutral MCO species in solid argon, but three of the early assignments have been changed by recent work and one new assignment added. The laser-ablation method produces mostly neutral atoms with a few percent cations and electrons for capture to make anions; in contrast, thermal evaporation gives only neutral species. Hence, the very recent neon matrix investigations in our laboratory provide carbonyl cations and anions for comparison to neutrals on a level playing field. Several trends are very interesting. First, for all metals, the C-O stretching frequencies follow the order cations > neutrals > anions with large diagnostic 100-200 cm-1 separations, which is consistent with the magnitude of the metal d to CO pi * donation. Second, for a given charge, there is a general increase in C-O stretching vibrational frequencies with increasing metal atomic number, which demonstrates the expected decrease in the metal to CO pi * donation with increasing metal ionization potential. Some of the structure in this plot arises from the extra stability of the filled and half-filled d shell and from the electron pairing that occurs at the middle of the TM row; the plot resembles the "double-humped" graph found for the variation in properties across a row of transition metals. For the anions, the variation with metal atom is the smallest since all of the metals can easily donate charge to the CO ligand. Third, for the early transition-metal Ti, V, and Cr families, the C-O stretching frequencies decrease when going down the family, but the reverse relationship is observed for the late transition-metal Fe, Co, and Ni families. In most of the present discussion, we have referred to neon matrix frequencies; however, the argon matrix frequencies are complementary, and useful information can be obtained from comparison of the two matrix hosts. In most cases, the neon-to-argon red shift for neutral carbonyls is from 11 to 26 cm-1, but a few (CrCO) lie outside of this range. In the case of FeCO and Fe(CO)2, it appears that neon and argon trap different low-lying electronic states. In general, the carbonyl neutrals and anions have similar shifts but carbonyl cations have larger matrix shifts. For example, the FeCO+ fundamental is at 2123.0 cm-1 in neon and 2081.5 cm-1 in argon, a 42.5 cm-1 shift, which is larger than those found for FeCO- (11.7 cm-1) and FeCO (11.7 cm-1). It is unusual for different low-lying electronic states to be trapped in different matrices, but CUO provides another example. The linear singlet state (1047.3, 872.2 cm-1) is trapped in solid neon, and a calculated 1.2 kcal/mol higher triplet state is trapped in solid argon (852.5, 804.3 cm-1) and stabilized by a specific interaction with argon. The bonding trends are well described by theoretical calculations of vibrational frequencies. Table 5 compares the scale factors (observed neon matrix/calculated) for the C-O stretching modes of the monocarbonyl cations, neutrals, and anions of the first-row transition metals observed in a neon matrix using the B3LYP and BP86 density functionals. Most of the calculated carbonyl harmonic stretching frequencies are within 1% of the experimental fundamentals at the BP86 level of theory, while calculations using the B3LYP functional give frequencies that are 3-4% higher as expected for these density functionals and calculations on saturated TM-carbonyls. For second- and third-row carbonyls using the BP86 density functional and the LANL effective core potential in conjunction with the DZ basis set, the agreement between theory and experiment is just as good. For example, the 16 M(CO)1-4 neutral and anion and 2 MCO+ cation (M = Ru, Os) carbonyl frequencies are fit within 1.5%. The 16 species (M = Rh, Ir) are fit within 1%, but the Rh(CO)1-4+ calculations are 2-3% too low and Ir(CO)1-4+ computations are 1-2% too low. In addition to predicting the vibrational frequencies, DFT can be used to calculate different isotopic frequencies, and isotopic frequency ratios can be computed as a measure of the normal vibrational mode in the molecule for an additional diagnostic. For diatomic CO, the 12CO/13CO ratio 1.0225 and C16O/C18O ratio 1.0244 characterize a pure C-O stretching mode. In a series of molecules such as RhCO+, RhCO, and RhCO-, where the metal-CO bonding varies, the Rh-C, C-O vibrational interaction is different and the unique isotopic ratios for the carbonyl vibration are characteristic of that particular molecule. Table 6 summarizes the isotopic ratios observed and calculated for the RhCO+,0,- species. Note that RhCO+ exhibits slightly more carbon-13 and less oxygen-18 involvement in the C-O vibration than CO itself and that this trend increases to RhCO and to RhCO- as the Rh-C bond becomes shorter and stronger. Note also how closely the calculated and observed ratios both follow this trend. In a molecule with two C-O stretching modes, for example, bent Ni(CO)2 exhibits a strong b2 mode at 1978.9 cm-1 and a weak a1 mode at 2089.7 cm-1 in solid neon, and these two modes involve different C and O participations. The symmetric mode shows substantially more C (1.0242) and less O (1.0217) participation than does the antisymmetric mode with C (1.0228) and O (1.0238) involvement, based on the given isotopic frequency ratios, which are nicely matched by DFT calculations (a1 1.0244, 1.0224 and b2 1.0232, 1.0241, respectively). These investigations of vibrational frequencies in unsaturated transition-metal carbonyl cations, neutrals, and anions clearly demonstrate the value of a close working relationship between experiment and theory to identify and characterize new molecular species.

Temperature dependence of the thermal conductivity of single-wall carbon nanotubes

Abstract: The thermal conductivity of several single-wall carbon nanotubes has been calculated over a temperature range of 100-500 K using molecular dynamics simulations with the Tersoff-Brenner potential for C-C interactions. In all cases, starting from similar values at 100 K, the thermal conductivities show a peaking behaviour before falling off at higher temperatures. The peak position shifts to higher temperatures for nanotubes with larger diameters and no significant dependence on the tube chirality is observed. It is shown that this phenomenon is due to the onset of Umklapp scattering, which shifts to higher temperatures for nanotubes with larger diameters.

A Pair of Resonant Planets Orbiting GJ 876

Abstract: Precise Doppler measurements during 6 yr from the Lick and Keck observatories reveal two planets orbiting GJ 876 (M4V). The orbital Ðt yields companion masses of M sin i \ 0.56 and 1.89 orbital M J , periods of P \ 30.1 and 61.0 days, semimajor axes of a \ 0.13 and 0.21 AU, and eccentricities of e \ 0.28 and 0.10, respectively. The orbital periods are nearly in the ratio of 2:1, unprecedented among major planets but common among moons and asteroids. Moreover, the axes of the elliptical orbits appear to be nearly aligned. The inner companion was not recognized previously owing to the 2:1 ratio of periods, which allowed its signature to masquerade as added orbital eccentricity of the outer planet. Dynamical simulations show that the system is stable within a subset of the observed orbital parameters. The stability may be provided by a mean-motion resonance and the apparent alignment of the major axes. These planets pose unsolved questions about their formation and dynamical evolution, which brought them within 0.08 AU of each other and locked them in resonance. Subject headings : planetary systems E stars : individual (GJ 876)

Evidence from the Pacific troposphere for large global sources of oxygenated organic compounds

Abstract: The presence of oxygenated organic compounds in the troposphere strongly influences key atmospheric processes. Such oxygenated species are, for example, carriers of reactive nitrogen and are easily photolysed, producing free radicals1,2,3—and so influence the oxidizing capacity and the ozone-forming potential of the atmosphere4,5,6—and may also contribute significantly to the organic component of aerosols7,8. But knowledge of the distribution and sources of oxygenated organic compounds, especially in the Southern Hemisphere, is limited. Here we characterize the tropospheric composition of oxygenated organic species, using data from a recent airborne survey9 conducted over the tropical Pacific Ocean (30° N to 30° S). Measurements of a dozen oxygenated chemicals (carbonyls, alcohols, organic nitrates, organic pernitrates and peroxides), along with several C2–C8 hydrocarbons, reveal that abundances of oxygenated species are extremely high, and collectively, oxygenated species are nearly five times more abundant than non-methane hydrocarbons in the Southern Hemisphere. Current atmospheric models are unable to correctly simulate these findings, suggesting that large, diffuse, and hitherto-unknown sources of oxygenated organic compounds must therefore exist. Although the origin of these sources is still unclear, we suggest that oxygenated species could be formed via the oxidation of hydrocarbons in the atmosphere, the photochemical degradation of organic matter in the oceans, and direct emissions from terrestrial vegetation.

A reconsideration of disk properties in Herbig Ae stars

Abstract: This paper presents state-of-the-art spectral energy distributions (SEDs) of four Herbig Ae stars, based in part on new data in the mid and far-infrared and at millimeter wavelengths. The SEDs are discussed in the context of circumstellar disk models. We show that models of irradiated disks provide a good fit to the observations over the whole range of wavelengths. We offer a possible solution to the long-standing puzzle caused by the excess emission of Herbig Ae stars, where a large fraction of the stellar luminosity is re-radiated between ~1.25 and 7 μ m, with a peak at about 3 μ m. We suggest that this general behaviour can be caused by dust evaporation in disks where the gas component is optically thin to the stellar radiation, as expected if the accretion rate is very low. The creation of a puffed-up inner wall of optically thick dust at the dust sublimation radius can account for the near-infrared characteristics of the SEDs. It can also naturally explain the H and K band interferometric observations of AB Aur (Millan-Gabet et al. [CITE]), which reveal a ring of emission of radius ~0.3 AU. Finally, irradiated disk models can easily explain the observed intensity of the 10 μ m silicate features and their variation from star to star.

Carbonaceous meteorites as a source of sugar-related organic compounds for the early Earth

Abstract: The much-studied Murchison meteorite is generally used as the standard reference for organic compounds in extraterrestrial material. Amino acids and other organic compounds important in contemporary biochemistry are thought to have been delivered to the early Earth by asteroids and comets, where they may have played a role in the origin of life. Polyhydroxylated compounds (polyols) such as sugars, sugar alcohols and sugar acids are vital to all known lifeforms-they are components of nucleic acids (RNA, DNA), cell membranes and also act as energy sources. But there has hitherto been no conclusive evidence for the existence of polyols in meteorites, leaving a gap in our understanding of the origins of biologically important organic compounds on Earth. Here we report that a variety of polyols are present in, and indigenous to, the Murchison and Murray meteorites in amounts comparable to amino acids. Analyses of water extracts indicate that extraterrestrial processes including photolysis and formaldehyde chemistry could account for the observed compounds. We conclude from this that polyols were present on the early Earth and therefore at least available for incorporation into the first forms of life.

Impact Event at the Permian-Triassic Boundary: Evidence from Extraterrestrial Noble Gases in Fullerenes

Abstract: The Permian-Triassic boundary (PTB) event, which occurred about 251.4 million years ago, is marked by the most severe mass extinction in the geologic record. Recent studies of some PTB sites indicate that the extinctions occurred very abruptly, consistent with a catastrophic, possibly extraterrestrial, cause. Fullerenes (C60 to C200) from sediments at the PTB contain trapped helium and argon with isotope ratios similar to the planetary component of carbonaceous chondrites. These data imply that an impact event (asteroidal or cometary) accompanied the extinction, as was the case for the Cretaceous-Tertiary extinction event about 65 million years ago.

Direct comparison of the impact of head tracking, reverberation, and individualized head-related transfer functions on the spatial perception of a virtual speech source.

Abstract: A study of sound localization performance was conducted using headphone-delivered virtual speech stimuli, rendered via HRTF-based acoustic auralization software and hardware, and blocked-meatus HRTF measurements. The independent variables were chosen to evaluate commonly held assumptions in the literature regarding improved localization: inclusion of head tracking, individualized HRTFs, and early and diffuse reflections. Significant effects were found for azimuth and elevation error, reversal rates, and externalization.

The CH out of plane bending modes of PAH molecules in astrophysical environments

Abstract: We present 10 15 m spectra of as ample of Hii regions, YSOs and evolved stars that show strong unidentied infrared emission features, obtained with the ISO/SWS spectrograph on-board ISO. These spectra reveal a plethora of emission features with bands at 11.0, 11.2, 12.0, 12.7, 13.5 and 14.2 m. These features are observed to vary considerably in relative strength to each-other from source to source. In particular, the 10{15m spectra of the evolved stars are dominated by the 11.2 m band while for H ii regions the 12.7 is typically as strong as the 11.2 m band. Analysing the ISO data we nd a good correlation between the 11.2 mb and and the 3.3 m band, and between the 12.7 ma nd the 6.2m band. There is also a correlation between the ratio of the UIR bands to the total dust emission and the 12.7 over 11.2 m ratio. Bands in the 10{15 ms pectral region are due to CH out of plane (OOP) bending modes of polycyclic aromatic hydrocarbons (PAHs). We summarise existing laboratory data and theoretical quantum chemical calculations of these modes for neutral and cationic PAHs. Due to mode coupling, the exact peak position of these bands depends on the number of adjacent CH groups and hence the observed interstellar 10 15 m spectra can be used to determine the molecular structure of the interstellar PAHs emitting in the dierent regions. We conclude that evolved stars predominantly inject compact 100 200 C-atom PAHs into the ISM where they are subsequently processed, resulting in more open and uneven PAH structures.

Digital video quality metric based on human vision

Abstract: The growth of digital video has given rise to a need for computational methods for evaluating the visual quality of digital video. We have developed a new digital video quality metric, which we call DVQ (digital video quality) (A. B. Watson, in Human Vision, Visual Processing, and Digital Display VIII, Proc. SPIE 3299, 139- 147 (1998)). Here, we provide a brief description of the metric, and give a preliminary report on its performance. DVQ accepts a pair of digital video sequences, and computes a measure of the magnitude of the visible difference between them. The metric is based on the discrete cosine transform. It incorporates aspects of early visual pro- cessing, including light adaptation, luminance, and chromatic chan- nels; spatial and temporal filtering; spatial frequency channels; con- trast masking; and probability summation. It also includes primitive dynamics of light adaptation and contrast masking. We have applied the metric to digital video sequences corrupted by various typical compression artifacts, and compared the results to quality ratings made by human observers. © 2001 SPIE and IS&T. (DOI: 10.1117/1.1329896)

Extraterrestrial amino acids in Orgueil and Ivuna: tracing the parent body of CI type carbonaceous chondrites.

Abstract: Amino acid analyses using HPLC of pristine interior pieces of the CI carbonaceous chondrites Orgueil and Ivuna have found that beta-alanine, glycine, and gamma-amino-n-butyric acid (ABA) are the most abundant amino acids in these two meteorites, with concentrations ranging from approx. 600 to 2,000 parts per billion (ppb). Other alpha-amino acids such as alanine, alpha-ABA, alpha-aminoisobutyric acid (AIB), and isovaline are present only in trace amounts (less than 200 ppb). Carbon isotopic measurements of beta-alanine and glycine and the presence of racemic (D/L 1) alanine and beta-ABA in Orgueil suggest that these amino acids are extraterrestrial in origin. In comparison to the CM carbonaceous chondrites Murchison and Murray, the amino acid composition of the CIs is strikingly distinct, suggesting that these meteorites came from a different type of parent body, possibly an extinct comet, than did the CM carbonaceous chondrites.

The detection of large HNO3-containing particles in the winter Arctic stratosphere.

Abstract: Large particles containing nitric acid (HNO3) were observed in the 1999/2000 Arctic winter stratosphere. These in situ observations were made over a large altitude range (16 to 21 kilometers) and horizontal extent (1800 kilometers) on several airborne sampling flights during a period of several weeks. With diameters of 10 to 20 micrometers, these sedimenting particles have significant potential to denitrify the lower stratosphere. A microphysical model of nitric acid trihydrate particles is able to simulate the growth and sedimentation of these large sizes in the lower stratosphere, but the nucleation process is not yet known. Accurate modeling of the formation of these large particles is essential for understanding Arctic denitrification and predicting future Arctic ozone abundances.

Monitoring Java Programs with Java PathExplorer

Abstract: We present recent work on the development of Java PathExplorer (JP a X), a tool for monitoring the execution of Java programs. JPaX can be used during program testing to gain increased information about program executions, and can potentially furthermore be applied during operation to survey safety critical systems. The tool facilitates automated instrumentation of a program's byte code, which will then emit events to an observer during its execution. The observer checks the events against user provided high level requirement specifications, for example temporal logic formulae, and against lower level error detection procedures, usually concurrency related such as deadlock and data race algorithms. High level requirement specifications together with their underlying logics are defined in rewriting logic using Maude, and then can either be directly checked using Maude rewriting engine, or be first translated to efficient data structures and then checked in Java.

Narrative and social tacit knowledge

Abstract: This paper discusses the role of narrative in the expression and transmission of social knowledge as a specific type of tacit knowledge. Narrative is a central mechanism by which social knowledge is conveyed. Narrative provides a bridge between the tacit and the explicit, allowing tacit social knowledge to be demonstrated and learned, without the need to propositionalize it. Institutions can best maintain their stock of stories by providing occasions on which they can be told. Archival systems such as databases, lessons learned systems, and video records are less effective, particularly when they attempt to store records or transcripts of oral stories. However, they can be improved by attention to key design dimensions, including appropriate allocation of the effort required from system administrators and users, and attention to translation between genres.

Alteration Assemblages in Martian Meteorites: Implications for Near-Surface Processes

Abstract: The SNC (Shergotty-Nakhla-Chassigny) meteorites have recorded interactions between martian crustal fluids and the parent igneous rocks. The resultant secondary minerals — which comprise up to ~1 vol.% of the meteorites — provide information about the timing and nature of hydrous activity and atmospheric processes on Mars. We suggest that the most plausible models for secondary mineral formation involve the evaporation of low temperature (25 – 150 °C) brines. This is consistent with the simple mineralogy of these assemblages — Fe-Mg-Ca carbonates, anhydrite, gypsum, halite, clays — and the chemical fractionation of Ca-to Mg-rich carbonate in ALH84001 “rosettes”. Longer-lived, and higher temperature, hydrothermal systems would have caused more silicate alteration than is seen and probably more complex mineral assemblages. Experimental and phase equilibria data on carbonate compositions similar to those present in the SNCs imply low temperatures of formation with cooling taking place over a short period of time (e.g. days). The ALH84001 carbonate also probably shows the effects of partial vapourisation and dehydration related to an impact event postdating the initial precipitation. This shock event may have led to the formation of sulphide and some magnetite in the Fe-rich outer parts of the rosettes.

Humans in space

Abstract: Many successful space missions over the past 40 years have highlighted the advantages and necessity of humans in the exploration of space. But as space travel becomes ever more feasible in the twenty-first century, the health and safety of future space explorers will be paramount. In particular, understanding the risks posed by exposure to radiation and extended weightlessness will be crucial if humans are to travel far from Earth.

Simulations of Trade Wind Cumuli under a Strong Inversion

Abstract: The fifth intercomparison of the Global Water and Energy Experiment Cloud System Studies Working Group 1 is used as a vehicle for better understanding the dynamics of trade wind cumuli capped by a strong inversion. The basis of the intercomparison is 10 simulations by 7 groups. These simulations are supplemented by many further sensitivity studies, including some with very refined grid meshes. The simulations help illustrate the turbulent dynamics of trade cumuli in such a regime. In many respects the dynamics are similar to those found in many previous simulations of trade cumuli capped by weaker inversions. The principal differences are the extent to which the cloud layer is quasi-steady in the current simulations, evidence of weak countergradient momentum transport within the cloud layer, and the development and influence of an incipient stratiform cloud layer at the top of the cloud layer. Although many elements of the turbulent structure (including the wind profiles, the evolution of cloud-base height, the statistics of the subcloud layer, and the nature of mixing in the lower and middle parts of the cloud layer) are robustly predicted, the representation of the stratiform cloud amount by the different simulations is remarkably sensitive to a number of factors. Chief among these are differences between numerical algorithms. These sensitivities persist even among simulations on relatively refined grid meshes. Part of this sensitivity is attributed to a physically realistic positive radiative feedback, whereby a propensity toward higher cloud fractions in any given simulation is amplified by longwave radiative cooling. The simulations also provide new insight into the dynamics of the transition layer at cloud base. In accord with observations, the simulations predict that this layer is most identifiable in terms of moisture variances and gradients. The simulations help illustrate the highly variable (in both height and thickness) nature of the transition layer, and we speculate that this variability helps regulate convection. Lastly the simulations are used to help evaluate simple models of trade wind boundary layers. In accord with previous studies, mass-flux models well represent the dynamics of the cloud layer, while mixing-length models well represent the subcloud layer. The development of the stratiform cloud layer is not, however, captured by the mass-flux models. The simulations indicate that future theoretical research needs to focus on interface rules, whereby the cloud layer is coupled to the subcloud layer below and the free atmosphere above. Future observational studies of this regime would be of most benefit if they could provide robust cloud statistics as a function of mean environmental conditions.