Nanjing University of Science and Technology

About: Nanjing University of Science and Technology is a education organization based out in Nanjing, China. It is known for research contribution in the topics: Catalysis & Computer science. The organization has 31581 authors who have published 36390 publications receiving 525474 citations. The organization is also known as: Nánjīng Lǐgōng Dàxué & Nánlǐgōng.

DFT studies on the four polymorphs of crystalline CL-20 and the influences of hydrostatic pressure on epsilon-CL-20 crystal.

Abstract: Based on density functional theory (DFT), four different methods with the generalized gradient approximation (GGA) have been employed to investigate the structural and electronic properties of the four polymorphs (alpha.H2O, beta, gamma, and epsilon phases) of CL-20, which is a well-known high energy density compound (HEDC). The relaxed crystal structures compare well with experimental data. According to the constitution of the frontier energy bands and the Mulliken population analyses, the N-NO2 bond is predicted to be the trigger bond during thermolysis. The density of states (DOS) of alpha-CL-20.H2O is somewhat different from those of the other three crystals for its inclusion of H2O molecules that contribute the frontier energy bands. The band gaps obtained from the four different methods are consistent with each other. According to the calculated values of band gaps, the sensitivity of the four polymorphs of CL-20 is predicted as epsilon < beta < gamma < alpha.H2O, which agrees well with the experimental result. The effects of hydrostatic compression on the most stable epsilon-CL-20 have also been investigated using the GGA-PBE method in the pressure range of 0-400 GPa. epsilon-CL-20 has anisotropic compressibility at low or high pressure. The band gap is found to decrease with increasing pressure, showing the corresponding sensitivity increase. Based on the changes of the band gap and DOS with pressure, 400 GPa is considered to be the critical pressure for the insulator-metal phase transition.

RISE-Based Adaptive Control of Hydraulic Systems With Asymptotic Tracking

Abstract: Parametric uncertainty associated with unmodeled disturbance always exist in physical hydraulic systems, and complicate the advanced nonlinear controller design. In this paper, an adaptive compensation with a robust integral of the sign of the error (RISE) feedback is developed for high precise tracking control of hydraulic motion system. To handle both payload and hydraulic unknown parameters in one controller, a chain of integrator nonlinear system model is first derived, and an adaptive RISE controller is then proposed, in which adaptive law is synthesized to handle parametric uncertainty and RISE robust term to attenuate unmodeled disturbance. The major feature of the proposed controller is that it can theoretically guarantee asymptotic tracking performance with a continuous control input, in the presence of various parametric uncertainties and unmodeled disturbances such as unconsidered dynamics as well as external disturbances via Lyapunov analysis. However, the proposed controller takes the acceleration as a system state, which usually suffers heavy noise pollution and thus cannot be utilized directly in actual control. To solve this practical issue, in this paper, a tracking differentiator is employed to extract high-quality acceleration signal and to make the proposed controller feasible execution. The effectiveness of the proposed nonlinear controller is demonstrated via comparative experimental results.