Nanjing University of Science and Technology

About: Nanjing University of Science and Technology is a education organization based out in Nanjing, China. It is known for research contribution in the topics: Catalysis & Computer science. The organization has 31581 authors who have published 36390 publications receiving 525474 citations. The organization is also known as: Nánjīng Lǐgōng Dàxué & Nánlǐgōng.

Excitation profile of surface-enhanced Raman scattering in graphene–metal nanoparticle based derivatives

Abstract: Understanding energy transfer mechanisms in graphene derivatives is strongly motivated by the unusually interesting electronic properties of graphene, which can provide a template for the creation of novel nanostructured derivatives. From a synthetic point of view, it is highly attractive to envision being able to synthesize pristine graphene from precursors such as graphene oxide (GO). While this goal may be challenging over large length-scales, it is possible to generate regions of graphene at the nanoscale, confirmed by Raman spectroscopy or other methods. We describe an in situ method of nucleating gold or palladium nanoparticles in the presence of ethylene glycol as a reducing agent, while simultaneously reducing GO to graphene. The Au nanoparticles aid in spectroscopic characterization by both quenching fluorescence, allowing the graphene D and G bands to be quantified, and yielding a surface enhancement of about two orders of magnitude. We observe the excitation profile (488–785 nm) of the surface enhanced Raman spectrum (SERS) of graphene with Au nanoparticles adsorbed on the surface. Both the D and G bands display a resonance at approximately 593 nm (2.09 eV). This resonance may be interpreted as a combination of the plasmon resonance at 548 nm and a likely contribution from charge transfer as well. In addition, we observe a stiffening of the G band compared with that of graphene. The mechanism of the SERS, whether plasmonic or charge transfer-based, enables insight into the electronic pathways available to the graphene–nanoparticle system. We discuss our results in the context of several existing studies of graphene-based nanostructure derivatives.

3-D Frequency Selective Rasorber: Concept, Analysis, and Design

Abstract: This paper introduces the concept, theory, and design of 3-D frequency selective rasorbers (FSRs), which have a transmission window transparent to the incident electromagnetic wave with two absorption bands located at both sides of the window. The proposed rasorber consists of a 2-D periodic array of parallel waveguides. The transmission characteristics with high selectivity are produced by lossless resonators implemented using a parallel waveguide with a metallic post in the center. On the other hand, the absorption bands are obtained by lossy resonators constructed by loading of lumped resistors at the entry port of short-circuited waveguides. Physical mechanism of the proposed FSRs is explained with the aid of an equivalent circuit model, and relevant design equations are formulated. Two prototypes of the designed FSRs are fabricated and measured as a proof of concept. The experimental results show that a bandwidth of 50% for the insertion loss less than 3 dB and two absorption bands with a high absorptance of around 90% can be achieved. Moreover, the simulated results also show that the proposed structure exhibits stable performance against the variation of the incident angle of an incoming plane wave.

Broadband Circularly Polarized Annular-Ring Microstrip Antenna

Abstract: A wideband circularly polarized (CP) annular-ring patch antenna with two proximity-coupled L-probe feeds orientated to have phases of 0deg and 90deg, using a broadband 90deg hybrid feed, is proposed. It is found that the current distribution for CP operation can be improved by cutting a smaller concentric circular slot on the original larger circular patch to form an annular-ring patch. With such an arrangement, the proposed antenna delivers a wider axial ratio (AR) bandwidth than that of the conventional circular patch with the identical feeding technique. Considering the common overlapped bandwidth limited by the impedance, AR and gain, the proposed annular-ring patch antenna exhibits an effective bandwidth of 38% from 1.5 to 2.2 GHz, which is wider than the corresponding bandwidth of 29.7% from 1.35 to 1.82 GHz for the conventional circular patch. Moreover, the effective bandwidth of 38% for the proposed annular-ring antenna is also much wider than those for the other annular-ring patch antennas in the literature.

Room-temperature production of silver-nanofiber film for large-area, transparent and flexible surface electromagnetic interference shielding

Abstract: A kind of pollution known as electromagnetic interference (EMI), which results from ubiquitous usage of various electronic communication and military radar equipment, has been receiving increasing attention recently. However, large-area EMI shielding on transparent and/or curved surfaces, including building windows, curved glass wall, and special requirements spaces (SRSs), remains hard to achieve. In this paper, a silver nanofiber (AgNF) based flexible and transparent EMI shielding film was successfully assembled via a room-temperature roll-to-roll production method. For transparent application scenario, AgNF with 89% transmittance in visible range and 1 μm thickness shows ~20 dB shielding efficiency (EMI SE). On the other hand, total shielding (>50 dB) is obtained when the thickness of AgNF increases to 10 μm, while its transmittance in visible range remains higher than 75%. Considering the facile and scale-free production technology, this material can be readily applied in large-scale, transparent, and/or SRSs EMI shielding.