Rensselaer Polytechnic Institute

About: Rensselaer Polytechnic Institute is a education organization based out in Troy, New York, United States. It is known for research contribution in the topics: Terahertz radiation & Finite element method. The organization has 19024 authors who have published 39922 publications receiving 1414699 citations. The organization is also known as: RPI & Rensselaer Institute.

Electrode models for electric current computed tomography

Abstract: A mathematical model for the physical properties of electrodes suitable for use in electric current computed tomography is discussed. The model includes the effects of discretization, shunt, and contact impedance. The complete model was validated by experiment. Bath resistivities of 284.0, 139.7, 62.3, and 29.5 Omega -cm were studied. Values of effective contact impedance used in the numerical approximations were 58.0, 35.0, 15.0, and 7.5 Omega -cm/sup 2/, respectively. Agreement between the calculated and experimentally measured values was excellent throughout the range of bath conductivities studied. It is desirable in electrical impedance imaging systems to model the observed voltages to the same precision as they are measured in order to be able to make the highest-resolution reconstructions of the internal conductivity that the measurement precision allows. The complete electrode model, which includes the effects of discretization of the current pattern, the shunt effect due to the highly conductive electrode material, and the effect of an effective contact impedance, allows calculation of the voltages due to any current pattern applied to a homogeneous resistivity field. >

A Composite from Poly(m‐phenylenevinylene‐co‐2,5‐dioctoxy‐p‐phenylenevinylene) and Carbon Nanotubes: A Novel Material for Molecular Optoelectronics

Abstract: As research progresses towards smaller and more efficient devices, the need to develop alternative molecular scale electronic materials becomes apparent. Integrated electronic component fabrication from organics has been recognized theoretically as the ultimate goal. In order to gain a comprehensive insight into these materials, extensive research has been carried out on conjugated carbon systems over the last few decades to optimize their optical and electrical properties. For example, doping polyacetylene with I2 has been shown to result in a large increase in conductivity compared to the pristine material. However, doping polymers tends to retard their optical properties as regards luminescence by reducing their bandgaps and introducing trapping sites such as solitons, polarons, or bipolarons. The simple lesson over the years is that if materials are to be considered for luminescence, doping should not be carried out despite the desire to improve charge transport properties. We report here the first physical adopingo, to use the traditional term, using small concentrations of multiwalled nanotubes in a conjugated luminescent polymer, poly(m-phenylenevinylene-co-2,5-dioctoxyp-phenylenevinylene) (PmPV), in a polymer/nanotube composite. This can increase electrical conductivity of the polymer by up to eight orders of magnitude. The nanotubes appear to act as nanometric heat sinks, preventing the buildup of large thermal effects, caused either optically (photobleaching) or electrically, which degrade these conjugated systems. We also report that electroluminescence was achieved from an organic light-emitting diode (LED) using the composite as the emissive layer in the device. Since initial work on conjugated systems, attempts have been made to find an area where polymers and/or fullerenes could be used as active semiconductor components. Although many new and interesting materials have been synthesized to this end, very few have found a practical application. One exception is polyphenylenevinylene (PPV), first reported by Burroughes et al. as being the light-emitting semiconductor in a Schottky diode. This encouraged scientists to study a wide variety of conjugated systems, including derivatives of this polymer, in order to optimize the efficiency of light emission from such devices. Polymers for use in LEDs must possess a number of important qualities. A high quantum yield of photoluminescence is necessary and the material must remain undoped, as dopants act as trapping sites, quenching the radiative decay of excitons. It is essential therefore to find a polymer that is reasonably conductive while maintaining its luminescent properties. Most undoped polymers possess a very low conductivity and so require high aturn-ono fields to generate sufficient carriers in order to produce the excitons, which decay radiatively. This is, in practical terms, very inefficient as fields generally induce large thermal effects, consequently causing device breakdown. There are other problems that must be addressed, but elimination of these very basic ones should substantially improve efficiencies and soon lead to applications for these polymers. The polymer used in our studies is PmPV, whose structure is a variation of the more common PPV. In this case the substitution pattern leads to dihedral angles in the chain and, according to molecular mechanics energy minimization calculations, the polymer chain tends to coil, forming a helical structure. The calculated diameter of this helix in vacuum is ca. 20 Š, whilst the pitch is ca. 6 Š. Multiwalled nanotubes were produced by the arc discharge method, resulting in multiwalled nanotubes of 20 nm average diameter and lengths between 500 nm and 1.5 mm. The nanotube powder and PPV were mixed together in toluene and sonicated briefly. It is probable that the coiled polymer conformation allows it to surround layers of nanotubes, permitting sufficiently close intermolecular proximity for p±p interaction to occur. The color change was dramatic in that the polymer has a bright yellow color while the composite, at high nanotube concentrations, possesses a deep green color. Photoluminescence studies were carried out using an Ar laser at the pump wavelength of 457 nm. Electrical conductivity was measured using a twopoint probe sandwich geometry and Pt electrodes. The LED was fabricated by casting the composite onto indium tin oxide (ITO) then sputtering an aluminum electrode on top. As the polymer structure possesses helicity, it is not surprising that it is able to wrap itself around the nanotubes and keep them suspended in solution indefinitely. The actual texture of the composite can be observed in Figure 1,

Vapor-Liquid equilibrium: Part I. An appraisal of data reduction methods

Abstract: Correlations of the excess Gibbs function and the activity coefficients of a binary, liquid-phase system at constant temperature depend on reduction of P-x-y data taken for the system in vapor-liquid equilibrium. It is shown that use of a full P-x-y data set is for all practical purposes based on just the P-y values. Alternative procedures require only P-x or P-y data. In any case, effective use of a full P-x-y data set can be made only if redundent experimental values of Px,y or P are compared for consistency with calculated values. This cannot be accomplished by means of the popular area test for thermodynamic consistency.

Subduction zone coupling and tectonic block rotations in the North Island, New Zealand

Abstract: [1] The GPS velocity field in the North Island of New Zealand is dominated by the long-term tectonic rotation of the eastern North Island and elastic strain from stress buildup on the subduction zone thrust fault. We simultaneously invert GPS velocities, earthquake slip vectors, and geological fault slip rates in the North Island for the angular velocities of elastic crustal blocks and the spatially variable degree of coupling on faults separating the blocks. This approach allows us to estimate the distribution of interseismic coupling on the subduction zone interface beneath the North Island and the kinematics of the tectonic block rotations. In agreement with previous studies we find that the subduction zone interface beneath the southern North Island has a high slip rate deficit during the interseismic period, and the slip rate deficit decreases northward along the margin. Much of the North Island is rotating as several, distinct tectonic blocks (clockwise at 0.5-3.8 deg Myr -1 ) about nearby axes relative to the Australian Plate. This rotation accommodates much of the margin-parallel component of motion between the Pacific and Australian plates. On the basis of our estimation of the block kinematics we suggest that rotation of the eastern North Island occurs because of the southward increasing thickness of the subducting Hikurangi Plateau. These results have implications for our understanding of convergent margin plate boundary zones around the world, particularly with regard to our knowledge of mechanisms for rapid tectonic block rotations at convergent margins and the role of block rotations in the slip partitioning process.