Journal ArticleDOI
Coordination polymer networks with O- and N-donors: What they are, why and how they are made
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TLDR
A review on metal ion containing coordination polymer networks is given in this paper, where the authors highlight the current research in the field by giving a short overview on the concept of coordination polymers networks, how and why they are made.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2006-08-01. It has received 1361 citations till now. The article focuses on the topics: Coordination polymer & Coordination complex.read more
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High-Connectivity Networks and Hybrid Inorganic Rod Materials Built from Potassium and Rubidium p-Halide-Substituted Aryloxides
TL;DR: A series of complex networks have been synthesized from the association of potassium and rubidium p-halide-substituted aryloxides using 1,4-dioxane molecules as neutral linkers, resulting in isolated, close-packed chains in the solid state.
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Coordination assemblies of CoII/NiII/MnII/ZnII with 1,1′-biphenyl-2,2′-dicarboxylic acid and three positional isomeric ligands: structural diversity and properties
Fu-Ping Huang,Fu-Ping Huang,He-Dong Bian,Qing Yu,Jin-Lei Tian,Hong Liang,Shi-Ping Yan,Dai-Zheng Liao,Peng Cheng +8 more
TL;DR: In this article, a series of supramolecular complexes, namely, [Co(dpa)(4,4′-bpt)(EtOH)(H2O)] (1), [Ni[dpa]-4, 4′ −bpt(H 2O)2]·2.5 H2O (2), [Cu(dpta)(4.4′−bpt)(EtO), [M[dpta]-3, 4, 4−2′-Bpt(3, 3, 4+bpt
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Cobalt(II), silver(I), and lead(II) tetrabromoterephthalates exhibiting the 1-D linear chain, 2-D CdCl2-type layer, and 3-D penta-nodal mixed-connecting coordination frameworks
TL;DR: In this article, the reaction of tetrabromoterephthalic acid (H2TBTA) with Co(OAc)2, AgNO3, or Pb(OAC)2 under similar conditions affords three new coordination polymers {[Co(TBTA)(DMF)2(H2O)2]-DMF2}n (1), [Ag(TBTa)0.5]n (2), and [Pb2(TBTTA)1.5(OH)( DMF)]n (3).
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Structural Diversity due to Amino Alcohol Ligands Leading to Rare μ4-Hydroxo-Bridged Tetranuclear and “Bicapped Cubane” Cores in Copper(II) Complexes: A Theoretical and Experimental Magnetostructural Study
TL;DR: Results from the synthetic studies leading to the formation of new copper(II) and silver(I) complexes (4-7) using Hae, 3-aminopropanol (Hap), and N,N-dimethylaminopropol (Hdmap) in similar reactions, which gave tetra- and hexanuclear complexes, are presented.
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Crystal structures and fluorescence properties of lanthanide complexes prepared with 2,2’-biphenyldicarboxylic acid and 2,2’:6’,2’’-terpyridine
TL;DR: In this article, five lanthanide complexes of Ln2(dpdc) 2(tpy)2(NO3)2 (H2O)2 [Ln=La (1), Ce (2), Pr (3), Sm (4), Gd (5), H2dpdc=2,2’-biphenyldicarboxylic acid and tpy=2.2′:6′,2″-terpyridine] were prepared at room temperature and characterized by X-ray diffraction, FT
References
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Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Supramolecular Chemistry: Concepts and Perspectives
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.