Journal ArticleDOI
Coordination polymer networks with O- and N-donors: What they are, why and how they are made
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TLDR
A review on metal ion containing coordination polymer networks is given in this paper, where the authors highlight the current research in the field by giving a short overview on the concept of coordination polymers networks, how and why they are made.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2006-08-01. It has received 1361 citations till now. The article focuses on the topics: Coordination polymer & Coordination complex.read more
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White-light emission by selectively encapsulating single lanthanide metal ions into alkaline earth metal-organic coordination polymers
Danfeng He,Qun Tang,Shumei Liu,Fang Luo,Yiwei Liu,Ning Li,Jun Miao,Xingquan Wang,Xu-Gang Chen,Feng-Ji Ma,Shuxia Liu +10 more
TL;DR: In this article, a method to obtain white-light emitters by encapsulating a single lanthanide metal ion into an alkaline earth metal-organic coordination polymers is presented.
Journal ArticleDOI
Multiply Bonded Metal(II) Acetate (Rhodium, Ruthenium, and Molybdenum) Complexes with the trans-1,2-Bis(N-methylimidazol-2-yl)ethylene Ligand
Nico Fritsch,Christian R. Wick,Thomas Waidmann,Pavlo O. Dral,Johannes Tucher,Frank W. Heinemann,Tatyana E. Shubina,Timothy Clark,Nicolai Burzlaff +8 more
TL;DR: The synthesis and structural characterization of new coordination polymers with the N,N-donor ligand trans-1,2-bis(N-methylimidazol-2-yl)ethylene (trans-bie) are reported, finding that the acetate-bridged paddlewheel metal(II) complexes are linked by the trans-bie ligand to give a one-dimensional alternating chain.
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Investigation of the MSO4·xH2O (M=Zn, x=7; M=Cd, x=8/3)/methyl 2-pyridyl ketone oxime reaction system: A novel Cd(II) coordination polymer versus mononuclear and dinuclear Zn(II) complexes
Constantina Papatriantafyllopoulou,George E. Kostakis,Catherine P. Raptopoulou,Aris Terzis,Spyros P. Perlepes,John C. Plakatouras +5 more
TL;DR: In this article, the reactions of methyl 2-pyridyl ketone oxime, (py)C(Me)NOH, with MSO 4 ǫ x H 2 O (Mǫ = Zn, x  = 7; Mǫ= Cd, x ∞ = 8/3), in the absence of an external base, have been investigated.
Journal ArticleDOI
Metal Complexes of 2,2′-Bipyridine-4,4′-diamine as Metallo-Tectons for Hydrogen Bonded Networks
TL;DR: In this paper, the transition metal complexes of the ligand 2,2′-bipyridine-4,4′-diamine (bpy4da) form three-dimensional (3D) hydrogen bonding networks with the hydrogen donor metallo-tecton with carboxylate counteranions as hydrogen bond acceptors within the complexes.
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Crystallization Behavior of Coordination Polymers. 1. Kinetic and Thermodynamic Features of 1,3-Bis(4-pyridyl)propane/MCl2 Systems
Lucia Carlucci,Gianfranco Ciani,Juan Manuel García-Ruiz,Massimo Moret,Davide M. Proserpio,Silvia Rizzato +5 more
TL;DR: A series of one-, two-, and three-dimensional coordination polymers has been crystallized from solution as well as in gelled media, by controlled reaction of the flexible ligand 1,3-bis(4-pyridyl)propane with MCl2 salts (M = Mn, Fe, Co, Ni, Cu, Cd, Zn) as discussed by the authors.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Supramolecular Chemistry: Concepts and Perspectives
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.