Journal ArticleDOI
Coordination polymer networks with O- and N-donors: What they are, why and how they are made
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TLDR
A review on metal ion containing coordination polymer networks is given in this paper, where the authors highlight the current research in the field by giving a short overview on the concept of coordination polymers networks, how and why they are made.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2006-08-01. It has received 1361 citations till now. The article focuses on the topics: Coordination polymer & Coordination complex.read more
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One-dimensional coordination polymer of copper(I) thiocyanate with the Schiff base ligand N,N′-bis(3,4-dimethoxybenzylidene)butane-1,4-diamine: synthesis, crystal structure, spectroscopic and thermal properties
TL;DR: In this paper, a one-dimensional polymeric copper-thiocyanate complex with the Schiff base ligand N,N′-bis(3,4-dimethoxybenzylidene)butane-1,4diamine, was synthesized and characterized by elemental analysis, 1H and 13C NMR, FT-IR spectroscopy, and thermal analysis.
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New cobalt and nickel thiocyanato coordination polymers with pyridazine: Synthesis, structure and desolvation/resolvation behavior
Susanne Wöhlert,Christian Näther +1 more
TL;DR: In this paper, the reaction of cobalt(II) thiocyanate and pyridazine in water under hydrothermal conditions leads to the formation of [Co2(NCS)4(pyridazines)2(H2O)]n (1-Co), whereas in the case of nickel(II), the reaction results in the formation [Ni2(NIC)4 (pyridine)2 (CH3OH)]n(1-Ni), which is an isotypic compound that exhibits powder patterns different from those of
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First use of 1,4-dihydro-2,3-quinoxalinedione in the chemistry of coordination polymers: A 3D copper(II) complex containing the 2,3-dioxyquinoxalinate(−2) ligand in a novel coordination mode
Konstantis F. Konidaris,Spyros P. Perlepes,Guillem Aromí,Simon J. Teat,Albert Escuer,Evy Manessi-Zoupa +5 more
TL;DR: In this paper, the 3D coordination polymer [Cu3L2Cl2(DMF)4]n (1) with an (82−·10)-a, lig (LiGe), topology, where L2− is 2,3-dioxyquinoxalinate(−2).
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Mixed Metal Multinuclear Cr(III) Cage Compounds and Coordination Polymers Based on Unsubstituted Phenolate: Design, Synthesis, Mechanism, and Properties
TL;DR: In this paper, the same authors showed that the controlled addition of water to the initial Cr(II) complex as well as variation of the stoichiometry lead to three new discrete chromium(III) aggregates, namely, [Cr(OPh)4(μ-OH)Li2(THF)3]2, Cr3Li3(Oph)9(μ3-OH), [Cr3-OPh](μ 3-Li), and [CrCl2(ThF)2.6]·2THF]·
Journal ArticleDOI
1D and 2D Zn–Ln coordination polymers based on compartment compounds: [ZnLn(L)(NO3)2(4-ppa)(EtOH)] and [ZnLn(L)(NO3)2(4-pca)(H2O)] (Ln = Eu, Tb; H2 L = 1,3-bis((3-methoxysalicylidene)amino)propane; 4-Hppa = 4-pyridinepropionic acid; 4-Hpca = 4-pyridinecarboxylic acid)
TL;DR: In this article, the preparation of four 3d-4f (3d = Zn; 4f = Eu, Tb) coordination polymers and their emission quenching of the lanthanide ions were described.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Supramolecular Chemistry: Concepts and Perspectives
TL;DR: From molecular to supramolescular chemistry: concepts and language of supramolecular chemistry, molecular recognition, information, complementarity molecular receptors - design principles and more.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.