Journal ArticleDOI
Coordination polymer networks with O- and N-donors: What they are, why and how they are made
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TLDR
A review on metal ion containing coordination polymer networks is given in this paper, where the authors highlight the current research in the field by giving a short overview on the concept of coordination polymers networks, how and why they are made.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2006-08-01. It has received 1361 citations till now. The article focuses on the topics: Coordination polymer & Coordination complex.read more
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Heterogeneous Catalysis with Alkaline-Earth Metal-Based MOFs: A Green Calcium Catalyst
Ana E. Platero Prats,Victor A. de la Peña-O’Shea,Marta Iglesias,Natalia Snejko,Angeles Monge,Enrique Gutiérrez-Puebla +5 more
TL;DR: In this article, the authors presented a new metal-organic framework (MOF) based on calcium, one of the most abundant and cheap elements, which could provide an alternative to traditional precious metal-based hydrogenation catalysts.
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Zn(II) metal–organic frameworks (MOFs) derived from a bis-pyridyl-bis-urea ligand: effects of crystallization solvents on the structures and anion binding properties
TL;DR: In this paper, the reaction of N,N′-bis-(3-pyridyl)ethylene-bis-urea (BPEBU) with ZnSO4 in 2:1 ligand:metal ratio in various crystallization solvents afforded four metal-organic frameworks (MOFs), namely, [{Zn(H2O)3(SO4)(µ-bPEBU)}·EG·2H2
Journal ArticleDOI
Anion Influence on the Structure and Magnetic Properties of a Series of Multidimensional Pyrimidine-2-carboxylato-Bridged Copper(II) Complexes
José Suárez-Varela,Antonio J. Mota,Hakima Aouryaghal,Joan Cano,Antonio Rodríguez-Diéguez,Dominique Luneau,Enrique Colacio +6 more
TL;DR: Seven new polynuclear copper(II) complexes of formula [Cu(mu-pymca)2] (1) ( pymca(-) = pyrimidine-2-carboxylato) (2) (dca = dicyanamide) (7) have been synthesized by reactions of K-pylca with copper( II) ions in the presence of different counteranions.
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A 3D porous metal–organic framework constructed of 1D zigzag and helical chains exhibiting selective anion exchange
TL;DR: In this paper, a 3D-braided porous metal-organic framework via self-assembly of two series of 1D polymer chains through both braiding and interpenetrating complex 1 consists of two distinct kinds of channels with different sizes and shapes along a and b directions occupied by perchlorate anions and water molecules.
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Lanthanide–Organic Coordination Frameworks Showing New 5-Connected Network Topology and 3D Ordered Array of Single-Molecular Magnet Behavior in the Dy Case
TL;DR: The Dy(III) complex 1 is an organized array of single-molecular magnets (SMMs), with frequency-dependent out-of-phase ac susceptibility signals and magnetization hysteresis at 4 K.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
MonographDOI
Supramolecular Chemistry: Concepts and Perspectives
TL;DR: From molecular to supramolescular chemistry: concepts and language of supramolecular chemistry, molecular recognition, information, complementarity molecular receptors - design principles and more.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.