Journal ArticleDOI
Coordination polymer networks with O- and N-donors: What they are, why and how they are made
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TLDR
A review on metal ion containing coordination polymer networks is given in this paper, where the authors highlight the current research in the field by giving a short overview on the concept of coordination polymers networks, how and why they are made.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2006-08-01. It has received 1361 citations till now. The article focuses on the topics: Coordination polymer & Coordination complex.read more
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Directed synthesis of μ-1,3,5 bridged dicyanamides by thermal decomposition of μ-1,5 bridged precursor compounds.
Mario Wriedt,Christian Näther +1 more
TL;DR: Investigations by IR spectroscopy, and single crystal X-ray structure analysis, show that the intermediates of the ligand-deficient 1 : 1 intermediates form a more condensed layered structure in which half of the pristine μ-1,5 bridged dca anions become μ- 1,3, 5 bridging.
Journal ArticleDOI
A new luminescent 3D metal–organic framework possessing a rare (3,5)-connected net which can be transformed from a 2D double layer
Haiyan He,Fangna Dai,Daofeng Sun +2 more
TL;DR: A new 3D metal-organic framework possessing a rare (3,5)-connected net has been synthesized and characterized and complex can be formed from a 2D double layer by thermally liberating the coordinated water and dmf molecules, simultaneous with luminescence-increased changes.
Journal ArticleDOI
Self-assembly of Ag(I)-based complexes and layered coordination polymers bridged by (2-thiazolyl)sulfides
Maxim I. Rogovoy,Denis G. Samsonenko,Denis G. Samsonenko,Mariana I. Rakhmanova,Mariana I. Rakhmanova,Alexander V. Artem'ev,Alexander V. Artem'ev +6 more
TL;DR: In this paper, two metal atoms bridged by 2-Mt ligands (μ2-N,S) in head-to-tail (for 1 and 2) and headto-head (for 3) manner were used to self-assemble a nuclear complex.
Journal ArticleDOI
A novel oxalato bridged supramolecular ternary complex of Cu(II) involving energetically significant π-hole interaction: Experimental and theoretical studies
TL;DR: In this article, a novel oxalate bridged supramolecular ternary complex has been synthesized from purely aqueous media and characterized using elemental analysis, spectroscopic (IR, UV-Vis-NIR and ESR) and single crystal X-ray diffraction techniques.
Journal ArticleDOI
An Unprecedented Stimuli-Controlled Single-Crystal Reversible Phase Transition of a Metal–Organic Framework and Its Application to a Novel Method of Guest Encapsulation
Fangchang Tan,Ana M. López-Periago,Mark E. Light,Jordi Cirera,Eliseo Ruiz,Alejandro Borrás,Francesc Teixidor,Clara Viñas,Concepción Domingo,José Giner Planas +9 more
TL;DR: The flexibility and unexpected dynamic behavior of a third-generation metal-organic framework are described for the first time and encapsulation of C60 is achieved by trapping this molecule during the reversible 2D to 3D phase transition, whereas no adsorption is observed by straight solvent diffusion into the pores of the3D phase.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
MonographDOI
Supramolecular Chemistry: Concepts and Perspectives
TL;DR: From molecular to supramolescular chemistry: concepts and language of supramolecular chemistry, molecular recognition, information, complementarity molecular receptors - design principles and more.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.