Journal ArticleDOI
Coordination polymer networks with O- and N-donors: What they are, why and how they are made
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TLDR
A review on metal ion containing coordination polymer networks is given in this paper, where the authors highlight the current research in the field by giving a short overview on the concept of coordination polymers networks, how and why they are made.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2006-08-01. It has received 1361 citations till now. The article focuses on the topics: Coordination polymer & Coordination complex.read more
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One-dimensional metal atom chain [Ru(CO)4]n as a catalyst precursor—Hydroformylation of 1-hexene using carbon dioxide as a reactant
Maija-Liisa Kontkanen,Larisa Oresmaa,M. Andreina Moreno,Janne Jänis,Elina Laurila,Matti Haukka +5 more
TL;DR: In this article, the catalytic activity of the polymeric 1D metal atom chain [Ru(CO) 4 ] n was studied in the context of the hydroformylation of 1-hexene utilizing CO 2 as a source of CO.
Journal ArticleDOI
Sonochemical syntheses of a new fibrous-like nano-scale manganese(II) coordination supramolecular compound; precursor for the fabrication of octahedral-like Mn3O4 nano-structure.
Vahid Safarifard,Ali Morsali +1 more
TL;DR: Concentration of initial reagents effects on size and morphology of nano-structured compound 1, shows that low concentrations ofInitial reagents decreased particles size and also leaded to fibrous-like nanostructures morphology.
Journal ArticleDOI
Structural Investigation of Coordination Polymers Constructed from a Conformational Bis-triazole Ligand and V-Shaped Bridging Carboxylate Anions: Hydrothermal Syntheses, Crystal Structures, and Property Studies
TL;DR: The conformational bis-triazole ligand 4,4'-bis[(1,2,4)-triazol-1-yl)methyl]biphenyl (btmb, 1) was successfully synthesized, and seven new coordination polymers, namely {M(oba)-(btmb)} n [M = Cd 2+(2), Co 2+ (3), Ni 2+
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Tetrathiafulvalene-tetracarboxylate: an intriguing building block with versatility in coordination structures and redox properties.
TL;DR: Electrochemical study of the solid-state compounds attests to the redox activity of the coordination system, and Magnetic investigations reveal the existence of antiferromagnetic interactions between magnetic centers in complexes 3 and 4, while in 1, the paramagnetic metallic centers are isolated, in agreement with the solid state structure.
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A series of three-dimensional lanthanide metal–organic frameworks with biphenylethene-4,4′-dicarboxylic acid: Hydrothermal syntheses and structures
TL;DR: In this article, a series of lanthanide complexes was characterized by elemental analysis, IR, PL TG and single-crystal X-ray diffraction, which were characterized by isomorphous and 3-dimensional pillared layered frameworks.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
MonographDOI
Supramolecular Chemistry: Concepts and Perspectives
TL;DR: From molecular to supramolescular chemistry: concepts and language of supramolecular chemistry, molecular recognition, information, complementarity molecular receptors - design principles and more.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.