Journal ArticleDOI
Coordination polymer networks with O- and N-donors: What they are, why and how they are made
Reads0
Chats0
TLDR
A review on metal ion containing coordination polymer networks is given in this paper, where the authors highlight the current research in the field by giving a short overview on the concept of coordination polymers networks, how and why they are made.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2006-08-01. It has received 1361 citations till now. The article focuses on the topics: Coordination polymer & Coordination complex.read more
Citations
More filters
Journal ArticleDOI
Catalytic properties of a cobalt metal–organic framework with a zwitterionic ligand synthesized in situ
T. A. Grigolo,S. D. de Campos,F. Manarin,G. V. Botteselle,Paula Brandão,Alexandra A. do Amaral,E. A. de Campos +6 more
TL;DR: This novel material showed catalytic properties in an electrophilic substitution reaction of indoles and aldehydes allowing the syntheses of bis(indolyl)methanes in high yields under mild reaction conditions and can be reused at least once with the same catalytic activity.
Journal ArticleDOI
Coordination polymers assembled from semirigid fluorene-based ligand: A couple of enantiomers
TL;DR: In this paper, a couple of Mg(II)-based coordination polymer enantiomers [MgL(DMF)(H2O)3]n and ZnL(ZnL) were synthesized by the solvothermal reactions between the achiral ligand 4,4′-(9,9-dimethyl-9H-fluorene-2,7-diyl)dibenzoic acid (H2L) and corresponding metal salts.
Journal ArticleDOI
A diamond metal-organic framework with in situ generated 1H-tetrazolate-5-butyric acid ligand: Crystal structure, photoluminescence and high thermal stability
TL;DR: In this article, a 3D noninterpenetrating diamond network was constructed for 1H-tetrazolate-5-butyrate coordination polymer, which exhibits a weak second-order nonlinear optical coefficient about 0.5 times that of potassium dihydrogen phosphate (KDP), and also displays strong blue photoluminescence at room temperature and a high thermal stability up to 400°C.
Journal ArticleDOI
Cadmium(II) Complexes with 2‐Hydroxy‐1‐naphthoate Ligand: Syntheses, Crystal Structures, and Emission Properties
TL;DR: In this paper, two new CdII complexes [Cd(L)2(phen)]2 (1) and {Cd[L]2(4bpy)1.5}∞ (2) were prepared by slow solvent evaporation from mixtures of 2-hydroxy-1-naphthoic acid (HL) and Cd(ClO4)2·6H2O in the presence of auxiliary phen and 4bpy co-ligands.
References
More filters
Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
MonographDOI
Supramolecular Chemistry: Concepts and Perspectives
TL;DR: From molecular to supramolescular chemistry: concepts and language of supramolecular chemistry, molecular recognition, information, complementarity molecular receptors - design principles and more.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.