Journal ArticleDOI
Coordination polymer networks with O- and N-donors: What they are, why and how they are made
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TLDR
A review on metal ion containing coordination polymer networks is given in this paper, where the authors highlight the current research in the field by giving a short overview on the concept of coordination polymers networks, how and why they are made.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2006-08-01. It has received 1361 citations till now. The article focuses on the topics: Coordination polymer & Coordination complex.read more
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Single-Strand Molecular Wheels and Coordination Polymers in Copper(II) Benzoate Chemistry by the Employment of α-Benzoin Oxime and Azides: Synthesis, Structures, and Magnetic Characterization
Theocharis C. Stamatatos,Gina Vlahopoulou,Gina Vlahopoulou,Catherine P. Raptopoulou,Vassilis Psycharis,Albert Escuer,George Christou,Spyros P. Perlepes +7 more
TL;DR: In this paper, the use of α-benzoin oxime (bzoxH2) in copper(II) benzoate chemistry, in the absence or presence of ancillary azido ligands, is reported.
Journal ArticleDOI
Towards full-color-tunable emission of two component Eu(III)-doped Gd(III) coordination frameworks by the variation of excitation light
Fengming Zhang,Fengming Zhang,Pengfei Yan,Hongfeng Li,Xiaoyan Zou,Guang-Feng Hou,Guangming Li +6 more
TL;DR: The isostructural two-component Eu(iii)-doped Gd(iii) complexes realize color-tunable luminescence from red to yellow, white, green and blue by the variation of excitation wavelengths, and represent the first example of full-color- Tunable emission in lanthanide coordination frameworks by the variations of excited light.
Journal ArticleDOI
Structural variability in Ag(I) and Cu(I) coordination polymers with thioether-functionalized bis(pyrazolyl)methane ligands.
Irene Bassanetti,Luciano Marchiò +1 more
TL;DR: The surface scans proved that the thioether function is preferably oriented on the opposite side of the bispyrazole N(2) chelate system, and results confirm that both ligand classes are suitable components for the construction of coordination polymers.
Journal ArticleDOI
The importance of C–H⋯N, C–H⋯π and π⋯π interactions in the crystal packing of the isomeric N1,N4-bis((pyridine-n-yl)methylene)-cyclohexane-1,4-diamines, n = 2, 3 and 4
TL;DR: In this article, the molecular structures of the isomeric N1,N4-bis((pyridine-n-yl)methylene)-cyclohexane-1,4-diamines, where n = 2 (1), 3 (2) and 4 (3).
Journal ArticleDOI
Self-assembly of organometallic Pd(II) complexes via CH3⋯π interactions: The first example of a cyclopalladated compound with herringbone stacking pattern
E.T. de Almeida,Antonio Eduardo Mauro,A. M. Santana,Sandra R. Ananias,A. V. G. Netto,J. G. Ferreira,Regina Helena de Almeida Santos +6 more
TL;DR: Two binuclear cyclometallated compounds [Pd2(C2,N-dmba)(μ-N3)]2 have been synthesized and characterized by elemental analysis, IR and NMR spectroscopies and single crystal X-ray diffraction crystallography as discussed by the authors.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Supramolecular Chemistry: Concepts and Perspectives
TL;DR: From molecular to supramolescular chemistry: concepts and language of supramolecular chemistry, molecular recognition, information, complementarity molecular receptors - design principles and more.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.