Journal ArticleDOI
Coordination polymer networks with O- and N-donors: What they are, why and how they are made
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TLDR
A review on metal ion containing coordination polymer networks is given in this paper, where the authors highlight the current research in the field by giving a short overview on the concept of coordination polymers networks, how and why they are made.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2006-08-01. It has received 1361 citations till now. The article focuses on the topics: Coordination polymer & Coordination complex.read more
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Photodimerization of a 1D hydrogen-bonded zwitter-ionic lead(II) complex and its isomerization in solution.
TL;DR: A pair of bpe-H(+) ligands in a zwitter-ionic complex undergoes photochemical cycloaddition quantitatively accompanied by proton transfer and the cyclobutane ring isomerizes slowly in solution to two more isomers, catalyzed by CF(3)CO(2)H acid.
Journal ArticleDOI
Preparation of stable and metastable coordination compounds : Insight into the structural, thermodynamic, and kinetic aspects of the formation of coordination polymers
TL;DR: The different compounds obtained by thermal decomposition and by crystallization from solution represent a snapshot of the species in solution and thus provide insight into the formation of coordination compounds.
Journal ArticleDOI
New microporous copper(II) coordination polymers based upon bifunctional 1,2,4-triazole/tetrazolate bridges
Oksana A. Bondar,Liliana V. Lukashuk,Andrey B. Lysenko,Harald Krautscheid,Eduard B. Rusanov,Alexander N. Chernega,Konstantin V. Domasevitch +6 more
TL;DR: In this paper, a series of Cu(II) coordination polymers, [Cu(μ2-L1)3]PO3F (1, 2, 3, 4), [Cu3-SO4] (2, 4, 5, 6, 7, 8, 9, 10, 11] and [Cu2(μ4-L2)-L1)-L2]-n (n = 2,3) axles, have been constructed under hydrothermal conditions and their structures have been established by X-ray diffraction.
Journal ArticleDOI
Structural Diversity, Luminescence, and Magnetic Properties of Eight Co(II)/Zn(II) Coordination Polymers Constructed from Semirigid Ether-Linked Tetracarboxylates and Bend Dipyridyl-Triazole Ligands
TL;DR: In this paper, eight coordination polymers based on H4L1/H4L2 (5,5′-(1,4/1,3-phenylenebis(methoxy))diisophthalic acid) and 3/4-abpt (4-amino-3,5-bis(3/4)-pyridyl)-1,2,4-triazole) ligands were synthesized.
Journal ArticleDOI
Ce(III) and Lu(III) metal–organic frameworks with Lewis acid metal sites: Preparation, sorption properties and catalytic activity in Knoevenagel condensation
TL;DR: In this article, two novel coordination polymers with composition {[Ln(BTC)(H2O)]·DMF}n (where Ln = Ce(III) (1) and Lu=III (2), BTC = benzene-1,3,5-tricarboxylate, DMF = N,N,N′-dimethylformamide) have been prepared under solvothermal conditions.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
MonographDOI
Supramolecular Chemistry: Concepts and Perspectives
TL;DR: From molecular to supramolescular chemistry: concepts and language of supramolecular chemistry, molecular recognition, information, complementarity molecular receptors - design principles and more.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.