Journal ArticleDOI
Coordination polymer networks with O- and N-donors: What they are, why and how they are made
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TLDR
A review on metal ion containing coordination polymer networks is given in this paper, where the authors highlight the current research in the field by giving a short overview on the concept of coordination polymers networks, how and why they are made.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2006-08-01. It has received 1361 citations till now. The article focuses on the topics: Coordination polymer & Coordination complex.read more
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Design and synthesis of metal-organic frameworks using metal-organic polyhedra as supermolecular building blocks.
TL;DR: This critical review highlights supermolecular building blocks (SBBs) in the context of their impact upon the design, synthesis, and structure of metal-organic materials (MOMs) by highlighting how the large size and high symmetry of such SBBs can afford improved control over the topology of the resulting MOM and a new level of scale to the resulting framework.
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MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
TL;DR: In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.
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One-Dimensional Coordination Polymers: Complexity and Diversity in Structures, Properties, and Applications
Wei Lee Leong,Jagadese J. Vittal +1 more
TL;DR: The properties of Ladderlike Chains, and the role of Metal Cluster As Building Blocks for 1D CP 718, are described.
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Triazoles and tetrazoles: Prime ligands to generate remarkable coordination materials
TL;DR: In this article, the authors present a compendium of all relevant ligands that have been employed to generate coordination polymers and metal-Organic Frameworks (MOFs), and three representative examples for each category are described in detail.
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Organic Thermoelectric Materials: Emerging Green Energy Materials Converting Heat to Electricity Directly and Efficiently
TL;DR: In this review, thermoelectric properties of conducting polymers and small molecules are summarized, with recent progresses in materials, measurements and devices highlighted.
References
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New Cd(II)-, Co(II)-, and Cu(II)-containing coordination polymers synthesized by using the rigid ligand 1,2-bis(3-pyridyl)ethyne (3,3'-DPA).
TL;DR: Four new organic/inorganic coordination polymers were synthesized by using the rigid ligand 1,2-bis(3-pyridyl)ethyne (3,3'-DPA) by showing a variety of structural architectures, ranging from sinusoidal and zigzag chains to two-dimensional channel-type architectures.
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Structural and magnetic properties of three copper(II) pyridine-2,3-dicarboxylate coordination polymers incorporating the same chain motif
TL;DR: In this article, two ligands occupied the equatorial plane of each tetragonally elongated octahedral Cu2+ coordination sphere, chelating through the pyridine nitrogen and one oxygen of the deprotonated 2-carboxylic acid group.
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Inclusion in Microporous β-Bis(1,1,1-trifluoro-5,5-dimethyl-5- methoxyacetylacetonato)copper(II), an Organic Zeolite Mimic†
TL;DR: This article showed that the porous β-form of the title complex preserves its host lattice pore structure in the presence of more than 100 guests, including gaseous and condensed hydrocarbons.
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Complexes of silver( I ), thallium( I ), lead( II ) and barium( II ) with bis[3-(2-pyridyl)pyrazol-1-yl]phosphinate: one-dimensional helical chains and discrete mononuclear complexes
TL;DR: In this paper, the reaction of 3-(2-pyridyl)pyrazole with POBr and POBr was shown to be polygonal and trigonal bipyramidal with a stereochemically active lone pair in an equatorial position.
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Assembled enantioselective catalysts for carbonyl-ene reactions
TL;DR: In this article, a new strategy for generating assembled polymeric chiral titanium complexes using linked bis-BINOL ligands was developed, and the assembled catalysts showed excellent enantioselectivity (up to 96.5% ee) for carbonyl-ene reaction under heterogeneous conditions to afford corresponding α-hydroxy esters in high yield.