Journal ArticleDOI
Coordination polymer networks with O- and N-donors: What they are, why and how they are made
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TLDR
A review on metal ion containing coordination polymer networks is given in this paper, where the authors highlight the current research in the field by giving a short overview on the concept of coordination polymers networks, how and why they are made.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2006-08-01. It has received 1361 citations till now. The article focuses on the topics: Coordination polymer & Coordination complex.read more
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Crystal structure, thermal stability and photoluminesence properties of five new Zn(II) coordination polymers constructed from mixed ligand; N-donor pyridine ligands and bis(4-carboxylphenyl)phosphinic acid
Jin-Ping Mo,Lida Hashemi,Jia-Li He,Wan-Lu Feng,Yue Yin,Wei-Bin Zhang,Xin-Hua Li,Hong-Ping Xiao,Ali Morsali +8 more
TL;DR: In this article, five new Zn(II) coordination polymers, constructed from mixed ligand; bis(4-carboxylphenyl)phosphinic acid (H3BPO) and N-donor pyridine ligands (phen, 4,4′-bipy, dpe and dpp), have been synthesized and characterized by single crystal X-ray diffraction, IR spectroscopy and elemental analyses.
Journal ArticleDOI
Influence of solvent on the structures of two copper(II) coordination polymers with tetraiodoterephthalate: syntheses, crystal structures, and properties
TL;DR: Two CuII coordination polymers with rigid periodinated ligand 2,3,5,6-tetraiodo-1,4-benzenedicarboxylic acid (H2BDC-I4) have been synthesized and characterized by elemental analysis, IR spectroscopy, and X-ray crystallography.
Journal ArticleDOI
Construction of coordination polymers from semirigid ditopic 2,2´-Biimidazole derivatives : synthesis, crystal structures and characterization
TL;DR: In this paper, the structure and properties of coordination polymers (CPs) were characterized with single crystal X-ray structure, mass spectrometry, and NMR spectroscopy.
Journal ArticleDOI
The roles of the coordination modes of bridging ligands for the formation of two 3D metal–organic coordination networks
TL;DR: In this article, the reaction of copper(II) or zinc (II) nitrate with pyridine-2,3,5,6-tetracarboxylic acid (H4pdtc) in the presence of 4,4-bipyridine (4,4′-bpy) allowed two 3D porous framework compounds, [Cu3(H2O)4(Hpdtc), 2(4, 4-bpyridine)2,4-, bpy)2] and [Zn4-(H2
Journal ArticleDOI
Unexpected Formation of the Cobalt-Formate Coordination Polymer [CO 3 (HCO 2 ) 6 ]·dmf from Co(NO3) 2 and 2,2'-Bipyridine-5,5'-dicarboxylic Acid in dmf-EtOH-H 2 O
Hyun Sue Huh,Soon W. Lee +1 more
Abstract: Under hydro(solvo)thermal conditions, the cobalt-formate coordination polymer [Co 3 (HCO 2 ) 6 ]·dmf (1·dmf) was formed from Co(NO 3 ) 2 and 2,2'-bipyridine-5,5'-dicarboxylic acid (bpdcH 2 ) in a mixed solvent of dmf, EtOH, and H 2 O. Polymer 1·dmf contains a formate ligand (HCO 2 - ), which may have been formed by decarboxylation of bpdcH 2 or hydrolysis of dmf. Heating up 1·dmf at 150°C removed the dmf guests to give crystalline [Co 3 (HCO 2 ) 6 ] (1), a guest-free form of 1·dmf. By immersing polymer 1 into several solvents (guests), we could obtain the corresponding guest-containing crystals of the formula of 1·guest (guest = CH 3 CN, acetone, or thf). The dimensions of the unit-cell volumes of these crystals depended on the contained guests in increasing order of 1·CH 3 CN < 1 < 1·thf < 1·acetone < 1·dmf.
References
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TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.