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Coordination polymer networks with O- and N-donors: What they are, why and how they are made

Adeline Y. Robin, +1 more
- 01 Aug 2006 - 
- Vol. 250, Iss: 15, pp 2127-2157
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TLDR
A review on metal ion containing coordination polymer networks is given in this paper, where the authors highlight the current research in the field by giving a short overview on the concept of coordination polymers networks, how and why they are made.
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This article is published in Coordination Chemistry Reviews.The article was published on 2006-08-01. It has received 1361 citations till now. The article focuses on the topics: Coordination polymer & Coordination complex.

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Design and synthesis of metal-organic frameworks using metal-organic polyhedra as supermolecular building blocks.

TL;DR: This critical review highlights supermolecular building blocks (SBBs) in the context of their impact upon the design, synthesis, and structure of metal-organic materials (MOMs) by highlighting how the large size and high symmetry of such SBBs can afford improved control over the topology of the resulting MOM and a new level of scale to the resulting framework.
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MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)

TL;DR: In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.
Journal ArticleDOI

One-Dimensional Coordination Polymers: Complexity and Diversity in Structures, Properties, and Applications

TL;DR: The properties of Ladderlike Chains, and the role of Metal Cluster As Building Blocks for 1D CP 718, are described.
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Triazoles and tetrazoles: Prime ligands to generate remarkable coordination materials

TL;DR: In this article, the authors present a compendium of all relevant ligands that have been employed to generate coordination polymers and metal-Organic Frameworks (MOFs), and three representative examples for each category are described in detail.
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Organic Thermoelectric Materials: Emerging Green Energy Materials Converting Heat to Electricity Directly and Efficiently

TL;DR: In this review, thermoelectric properties of conducting polymers and small molecules are summarized, with recent progresses in materials, measurements and devices highlighted.
References
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Journal ArticleDOI

Pseudopolymorph: A Polemic

TL;DR: In this article, the authors argue against the use of pseudopolymorph, since the scientific community gains no new understanding by its introduction, its use is pedagogically misleading, and a long-established and well-understood term "solvate" already exists.
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Immobilization of a Soluble Metal Complex in an Organic Network. Remarkable Catalytic Performance of a Porous Dialkoxyzirconium Polyphenoxide as a Functional Organic Zeolite Analogue

TL;DR: The Zr host catalyzes the Diels−Alder reaction of acrolein with 1,3-cyclohexadiene in a remarkable manner as mentioned in this paper, and exhibits reversible Langmuir-type adsorption/desorption of N2 at 77 K and hexane at 298 K.
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First CuII Diamondoid Net with 2-Fold Interpenetrating Frameworks. The Role of Anions in the Construction of the Supramolecular Arrays

TL;DR: The synthesis and crystal structure of the three-dimensional coordination polymer of an angular dipyridyl ligand 2,5-bis(4-pyridol)-1,3,4-oxadiazole (L) and Cu(ClO(4))(2), exhibiting the first Cu(II) diamondoid network with 2-fold interpenetration, are reported.
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New Types of Layered and Pillared Layered Metal Carboxylate-Phosphonates Based on the 4,4‘-Bipyridine Ligand

TL;DR: In this paper, the synthesis of transition metal salts with HO2CCH2N(CH2PO3H2)2 (H5L) and 4,4‘-bipyridine (bipy) lead to two new metal carboxylate-diphosphonates, namely, Co3(H2L)2(H 2O)4(bipY)2·11H2O (1) with a layered structure, and a blue luminescent compound, Zn5L2(biby
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(H2O)12-containing infinite chain encapsulated in supramolecular open framework built of cadmium(II), 1,3-di(4-pyridyl)propane and 5-sulfoisophthalic acid monosodium salt

TL;DR: In this paper, self-assembly of Cd(II), 1,3-di(4-pyridyl)propane and 5-sulfoisophthalic acid monosodium salt in CH3OH-H2O solution produced a supramolecular open framework with 1D channels that encapsulates an infinite chain consisting of water decamers linked by Cd2+.
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