Journal ArticleDOI
Coordination polymer networks with O- and N-donors: What they are, why and how they are made
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TLDR
A review on metal ion containing coordination polymer networks is given in this paper, where the authors highlight the current research in the field by giving a short overview on the concept of coordination polymers networks, how and why they are made.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2006-08-01. It has received 1361 citations till now. The article focuses on the topics: Coordination polymer & Coordination complex.read more
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Solid-state fluorescence of two zinc coordination polymers from bulky dicyano-phenylenevinylene and bis-azobenzene cores
TL;DR: In this article, two new coordination polymers (CPs) derived from small emissive molecules were investigated, which are respectively red and yellow emitters in the solid state, retaining the PLQY values of the fluorogenic ligands.
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Synthetic, structural and spectroscopic studies of copper(II) complexes derived from the combination of the succinamate(−1) ligand with aromatic N,N′-chelates
Katerina N. Lazarou,Iordanis Chadjistamatis,Aris Terzis,Spyros P. Perlepes,Catherine P. Raptopoulou +4 more
TL;DR: In this paper, the use of succinamic acid (H 2 sucm)/N,N′-chelate (2,2′-bipyridine, bpy; 4,4′-dimethyl-2, 2, 2′-binaridine, dmbpy; 1,10-phenanthroline, phen) "ligand blends" has yielded the new complexes [Cu 2 (Hsucm) 3 (bpy) 2 ](NO 3 )·0.5MeOH ( 1 ·0.6H
Journal ArticleDOI
Novel Coordination Polymers of Metal(II) Succinates with 4‐Aminopyridine: Synthesis, Spectroscopic, Thermal, and Fluorescent Properties
Selçuk Demir,Günay Kaya +1 more
TL;DR: In this article, four divalent transitional metal succinates with 4-aminopyridine (apy), [Mapy]2(H2O)2(μ-suc)]n [M = Ni (1), Co (2)] and [M(apy)2 (H 2O)(suc), were synthesized and characterized by elemental analyses, IR spectroscopy, and TG-DTA analyses.
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Coordination polymers for emerging molecular devices
TL;DR: In this article , the structure-function relationship of coordination polymers and how to characterize the resulting materials are examined and examples of how the promising properties of these materials have been exploited to accelerate the development of molecular devices.
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Synthesis of a New Interpenetrated Mixed Ligand Ni(II) Metal–Organic Framework: Structural, Thermal and Fluorescence Studies and its Thermal Decomposition to NiO Nanoparticles
TL;DR: In this paper, the reaction of terephthalic acid and pyrazine with nickel nitrate under hydrothermal conditions forms a 3D metal-organic framework with the composition of [Ni(μ3−−tp)(μ2−−pyz)]n (1), where H2tp = 1,4-benzenedicarboxylic acid (terephthalric acid) and pyz = pyrazinesine.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
MonographDOI
Supramolecular Chemistry: Concepts and Perspectives
TL;DR: From molecular to supramolescular chemistry: concepts and language of supramolecular chemistry, molecular recognition, information, complementarity molecular receptors - design principles and more.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.