Journal ArticleDOI
Coordination polymer networks with O- and N-donors: What they are, why and how they are made
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TLDR
A review on metal ion containing coordination polymer networks is given in this paper, where the authors highlight the current research in the field by giving a short overview on the concept of coordination polymers networks, how and why they are made.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2006-08-01. It has received 1361 citations till now. The article focuses on the topics: Coordination polymer & Coordination complex.read more
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Auxiliary ligand-directed synthesis of cadmium(II) and zinc(II) complexes from 1-D chains to 3-D architectures with 5-nitroisophthalate
TL;DR: In this paper, a series of cadmium-II and zinc-II metal-organic frameworks were synthesized by hydrothermal reactions of the corresponding Cd(II) and Zn(II)- salts with 5-nitroisophthalic acid (H2NIPH) in the presence of aminopyridine (apy) auxiliary ligands.
Journal ArticleDOI
Synthesis, spectroscopic characterization and X-ray studies of two novel double open cubane-like cadmium(II) complexes
TL;DR: In this paper, two novel azide cadmium(II) compounds [Cd4dafone)4Cl2(μ1, 1-N3)4(μ 1, 1, N3)2] were synthesized and characterized by spectroscopic and crystallographic methods.
Journal ArticleDOI
Coordination assemblies of the CdII–BDC/bpt mixed-ligand system: positional isomeric effect, structural diversification and luminescent properties
Fu-Ping Huang,Fu-Ping Huang,Zu-Mei Yang,Peng-Fei Yao,Qing Yu,Jin-Lei Tian,He-Dong Bian,Shi-Ping Yan,Dai-Zheng Liao,Peng Cheng +9 more
TL;DR: In this article, the influence of the positional isomeric ligands on the structures and properties of transition metal complexes was investigated, and it was shown that intermolecular forces have important effects on the formation and strengthening of the supra-molescular architecture in these complexes.
Journal ArticleDOI
Solvothermal assembly of a mixed-valence Cu(I,II) cyanide coordination polymer [Cu(II)Cu(I)2(µ-Br)2(µ-CN)2(bdmpp)]n by C–C bond cleavage of acetonitrile
TL;DR: In this paper, a mixed-valence Cu(I,II) cyanide coordination polymer was presented, which is involved in partial oxidation of CuI into Cu(II) via O2 in open air while in the case of 1, the cyanide may be generated in situ from the C-C cleavage of acetonitrile under solvothermal conditions.
Journal ArticleDOI
On-site sensors based on infinite coordination polymer nanoparticles: Recent progress and future challenge
TL;DR: In this article, the authors summarized the recent progress in preparation of functional ICP nanoparticles and their utility for on-site analysis, including fluorescent sensing, electrochemical monitoring and dual-responsive assay.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
MonographDOI
Supramolecular Chemistry: Concepts and Perspectives
TL;DR: From molecular to supramolescular chemistry: concepts and language of supramolecular chemistry, molecular recognition, information, complementarity molecular receptors - design principles and more.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.