Journal ArticleDOI
Coordination polymer networks with O- and N-donors: What they are, why and how they are made
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TLDR
A review on metal ion containing coordination polymer networks is given in this paper, where the authors highlight the current research in the field by giving a short overview on the concept of coordination polymers networks, how and why they are made.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2006-08-01. It has received 1361 citations till now. The article focuses on the topics: Coordination polymer & Coordination complex.read more
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Bridging ligands comprising two or more di-2-pyridylmethyl or amine arms: Alternatives to 2,2′-bipyridyl-containing bridging ligands
TL;DR: The synthesis of bridging ligands incorporating 2,2′-bipyridine as a chelating component has been studied for several decades and is widely employed in coordination chemistry, supramolecular chemistry and materials synthesis.
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Cation exchange in metal-organic frameworks (MOFs): The hard-soft acid-base (HSAB) principle appraisal
TL;DR: In this article, the authors provide rationalization of cation exchange behaviors in stable and labile MOFs, based on the hardness or softness of cations and ligands, effect of solvents, temperature and exchange period using the HSAB principle.
Journal ArticleDOI
1D zigzag chain and 0D monomer Cd(II)/Zn(II) compounds based on flexible phenylenediacetic ligand: Synthesis, crystal structures and fluorescent properties
TL;DR: In this paper, three novel Cd(II)/Zn(II) compounds have been synthesized and characterized by IR, TG, fluorescent spectrum and single-crystal X-ray diffraction techniques.
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A permanently porous van der Waals solid by using phosphonate monoester linkers in a metal organic framework
TL;DR: A bis(phosphonatemonoester) is employed as a linker in a Zn(II) metal organic framework that is a layered structure pillared only by vdW interactions between alkyl groups.
Journal ArticleDOI
Of Chains and Rings: Synthetic Strategies and Theoretical Investigations for Tuning the Structure of Silver Coordination Compounds and Their Applications
Tünde Vig Slenters,Jorge L. Sagué,Priscilla S. Brunetto,Stefanie Zuber,Antoine Fleury,Laurent Mirolo,Adeline Y. Robin,Markus Meuwly,Oliver Gordon,Regine Landmann,Alma U. Daniels,Katharina M. Fromm +11 more
TL;DR: In this article, the polyethyleneglycol spacer between two (iso)-nicotinic groups of the ligand system was used to obtain a large structural variety of silver coordination compounds, starting with zero-dimensional ring systems via one-dimensional chains, helices and double-helices to two-dimensional polycatenanes.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
MonographDOI
Supramolecular Chemistry: Concepts and Perspectives
TL;DR: From molecular to supramolescular chemistry: concepts and language of supramolecular chemistry, molecular recognition, information, complementarity molecular receptors - design principles and more.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.