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Coordination polymer networks with O- and N-donors: What they are, why and how they are made
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TLDR
A review on metal ion containing coordination polymer networks is given in this paper, where the authors highlight the current research in the field by giving a short overview on the concept of coordination polymers networks, how and why they are made.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2006-08-01. It has received 1361 citations till now. The article focuses on the topics: Coordination polymer & Coordination complex.read more
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Template synthesis of lanthanide (Pr, Nd, Gd) coordination polymers with 2-hydroxynicotinic acid exhibiting ferro-/antiferromagnetic interaction.
TL;DR: The variable-temperature magnetic susceptibility studies reveal ferromagnetic interactions between gadolinium(III) ions in 3 and 6 and antiferromagnetic interaction in 1, 2, 4, and 5.
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Four 2D metal–organic networks incorporating Cd-cluster SUBs: hydrothermal synthesis, structures and photoluminescent properties
TL;DR: In this paper, the second ligands of bpydo, bpe, bpp and bix (bpydo = 4,4′-bipyridine-N,N′-dioxide; bpe = 1,2-bis-(4-pyridyl)ethane; bpp = 1.4-bis(imidazol-1-yl-methyl)benzene); bix = bix, b.
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Isomeric Zinc(II) Triazolate Frameworks with 3-Connected Networks: Syntheses, Structures, and Sorption Properties
TL;DR: Thermogravimetric analysis shows that the stabilities of 2a and 2b are much better than those of 1a and 1b, which may be ascribed to different coordination numbers of zinc atoms.
Journal ArticleDOI
Structural modulation of polythreading and interpenetrating coordination networks with an elongated dipyridyl building block and various anionic co-ligands
TL;DR: In this paper, a series of coordination polymers with a dipyridyl-type building block bis[3,5-dimethyl-4-(4,4′-pyridis)pyrazol-1-yl]methane (pypz) and different anionic co-ligands is presented.
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Zinc and Cadmium Coordination Polymers with Bis(tetrazole) Ligands Bearing Flexible Spacers: Synthesis, Crystal Structures, and Properties
TL;DR: In this paper, seven new metal complexes with the formulas [Zn2(L1)2(H2O)]n (1), [Cd3(L3)2Cl4]·(H 2O)4}n (7), have been synthesized by the reactions of ZnII or CdII salts with three structurally related flexible bis(tetrazol-5-yl)alkanes, and characterized by single crystal X-ray diffraction analysis and thermogravimetric (TG) analysis.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
MonographDOI
Supramolecular Chemistry: Concepts and Perspectives
TL;DR: From molecular to supramolescular chemistry: concepts and language of supramolecular chemistry, molecular recognition, information, complementarity molecular receptors - design principles and more.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.