Journal ArticleDOI
Coordination polymer networks with O- and N-donors: What they are, why and how they are made
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TLDR
A review on metal ion containing coordination polymer networks is given in this paper, where the authors highlight the current research in the field by giving a short overview on the concept of coordination polymers networks, how and why they are made.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2006-08-01. It has received 1361 citations till now. The article focuses on the topics: Coordination polymer & Coordination complex.read more
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Luminescent sensing and formation of mixed f-d metal ion complexes between a Eu(iii)-cyclen-phen conjugate and Cu(ii), Fe(ii), and Co(ii) in buffered aqueous solution
TL;DR: From these changes, the binding stoichiometry and the binding constant for the formation of novel supramolecular complexes between and Cu(ii, Co(ii) and Fe(ii), which showed that either two or three equivalents of complexed to each of these transition metal ions, giving rise to the formation either linear f-d-f or branched f(3)-d based mixed nuclear complexes in solution.
Journal ArticleDOI
Formation of 1 D and 3 D Coordination Polymers in the Solid State Induced by Mechanochemical and Annealing Treatments: Bis(3‐cyano‐pentane‐2,4‐dionato) Metal Complexes
TL;DR: New compounds, which clearly indicated the power of the combined mechanochemical/annealing method for the synthesis of varied metal coordination complexes, are new compounds.
Journal ArticleDOI
Temperature- and solvent-controlled dimensionality in a zinc 6-(1H-benzoimidazol-2-yl)pyridinecarboxylate system
TL;DR: Several 0D, 1D, and 3D metal-organic hybrid frameworks of ZnII have been synthesized by using the asymmetric ligand 6-(1H-benzoimidazol-2-yl)pyridinecarboxylic acid (HL) with control of the temperature and solvent in a solvothermal synthesis technique.
Journal ArticleDOI
Bis(catechol)salen]MnIII coordination polymers as support-free heterogeneous asymmetric catalysts for epoxidation
TL;DR: In this paper, the formation of coordination polymers by the reaction of [bis(catechol)salen]Mn III with several di- and trivalent metal ions is reported.
Journal ArticleDOI
Development of a Continuous-Flow System for Asymmetric Hydrogenation Using Self-Supported Chiral Catalysts
Lei Shi,Xing-Wang Wang,Christian A. Sandoval,Zheng Wang,Hongji Li,Jiang Wu,Liting Yu,Kuiling Ding +7 more
TL;DR: Well-designed, self-assembled, metal-organic frameworks were constructed by simple mixing of multitopic MonoPhos-based ligands, giving well-characterized, insoluble (in toluene) polymeric materials, which showed outstanding catalytic performance for the asymmetric hydrogenation of a number of alpha-dehydroamino acids and 2-aryl enamides.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
MonographDOI
Supramolecular Chemistry: Concepts and Perspectives
TL;DR: From molecular to supramolescular chemistry: concepts and language of supramolecular chemistry, molecular recognition, information, complementarity molecular receptors - design principles and more.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.