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Journal ArticleDOI

Coordination polymer networks with O- and N-donors: What they are, why and how they are made

Adeline Y. Robin, +1 more
- 01 Aug 2006 - 
- Vol. 250, Iss: 15, pp 2127-2157
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TLDR
A review on metal ion containing coordination polymer networks is given in this paper, where the authors highlight the current research in the field by giving a short overview on the concept of coordination polymers networks, how and why they are made.
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This article is published in Coordination Chemistry Reviews.The article was published on 2006-08-01. It has received 1361 citations till now. The article focuses on the topics: Coordination polymer & Coordination complex.

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Metal–organic coordination frameworks assembled with the long flexible ligand 4,4′-bis(imidazol-1-ylmethyl)biphenyl

TL;DR: In this article, the self-assembly reactions of the flexible ligand 4,4′-bis (imidazol-1-ylmethyl)biphenyl (bimb) with different metal salts and their structures and supramolecular architectures have been characterized by single crystal X-ray analysis.
Journal ArticleDOI

Metal–Organic Rotaxane Frameworks Assembly by Cucurbit[6]uril-Based Pseudorotaxanes and Mixed Ligands

TL;DR: In this paper, four high-dimensional metal-organic rotaxane frameworks (MORFs) were successfully fabricated by cucurbit[6]uril-based pseudorotaxanes ([PR43]) and rigid carboxylate ligands by adjusting the synthesis temperature and the length of ligands.
Journal ArticleDOI

Semiconducting Tellurium-Iron-Copper Carbonyl Polymers

TL;DR: These two chain polymers, which can also be constructed from the precursor complex TeFe3(CO)9Cu2(MeCN)2, show semiconducting behaviors with low band gaps of 0.59 and 0.41 eV, respectively.
Journal ArticleDOI

A difunctional azido-cobalt(II) coordination polymer exhibiting slow magnetic relaxation behaviour and high-energy characteristics with good thermostability and insensitivity

TL;DR: Energetic characterization evidences that the resulting compound possesses satisfactory detonation properties, superior lack of sensitivity and thermostability owing to the high nitrogen content and a coherent intrachain configuration and it is noted that 1 has potential application prospects as a new generation of environmentally friendly high-energy materials based on this nitrogen-rich and oxygen-free system.
Journal ArticleDOI

Recent advances in block copolymer-assisted synthesis of supramolecular inorganic/organic hybrid colloids

TL;DR: In this paper, the authors review the recent progress of this area through highlighting a number of representative literature reports and highlight the possibilities for the development of inorganic/organic hybrid functional materials.
References
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Journal ArticleDOI

Functional porous coordination polymers.

TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
MonographDOI

Supramolecular Chemistry: Concepts and Perspectives

TL;DR: From molecular to supramolescular chemistry: concepts and language of supramolecular chemistry, molecular recognition, information, complementarity molecular receptors - design principles and more.
Journal ArticleDOI

Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage

TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI

Design and synthesis of an exceptionally stable and highly porous metal-organic framework

TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.
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