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Germanene: a novel two-dimensional germanium allotrope akin to graphene and silicene

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TLDR
In this article, an atom-thin, ordered, two-dimensional multi-phase film was grown in situ through germanium molecular beam epitaxy using a gold surface as a substrate.
Abstract
We have grown an atom-thin, ordered, two-dimensional multi-phase film in situ through germanium molecular beam epitaxy using a gold (111) surface as a substrate. Its growth is similar to the formation of silicene layers on silver (111) templates. One of the phases, forming large domains, as observed in scanning tunneling microscopy, shows a clear, nearly flat, honeycomb structure. Thanks to thorough synchrotron radiation core-level spectroscopy measurements and advanced density functional theory calculations we can identify it as a ?3????3 R(30?) germanene layer in conjunction with a ?7????7 R(19.1?) Au(111) supercell, presenting compelling evidence of the synthesis of the germanium-based cousin of graphene on gold.

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Giant Rashba spin splitting induced by heavy element adsorption at germanene

TL;DR: In this article, the structural and electronic properties of the Pb@germanene adsorption system were investigated by employing equilibrium ab initio atomistic thermodynamics and phonon spectra analysis.
Journal ArticleDOI

Localized surface plasmon resonances and electric field confinement in titanium carbide (Ti3C2) MXene nanoclusters

TL;DR: In this paper, the authors investigated the localized surface plasmon resonances and electric field confinement of pristine and surface-terminated [fluorinated (F) and/or oxidized (O)] mono-layered titanium carbide (Ti3C2) nanoclusters.
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Two-dimensional aluminum monoxide nanosheets: A computational study

TL;DR: By means of density functional theory (DFT) computations and particle-swarm optimization (PSO) structure searches, Wang et al. as discussed by the authors predict five low-lying energy structures of two-dimensional (2D) aluminum monoxide (AlO) nanosheets.
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First-principles study of adsorption of 3d and 4d transition metal atoms on aluminene

TL;DR: In this article, the structural, electronic, and magnetic properties of composite systems of first and second row transition metal (TM) atoms adsorbed aluminene were investigated using first principles calculations based on density functional theory.
References
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Journal ArticleDOI

Two- and one-dimensional honeycomb structures of silicon and germanium.

TL;DR: In this paper, first-principles calculations of structure optimization, phonon modes, and finite temperature molecular dynamics predict that silicon and germanium can have stable, two-dimensional, low-buckled, honeycomb structures.
Journal Article

Two- and one-dimensional honeycomb structures of silicon and germanium

TL;DR: First-principles calculations of structure optimization, phonon modes, and finite temperature molecular dynamics predict that silicon and germanium can have stable, two-dimensional, low-buckled, honeycomb structures, which show remarkable electronic and magnetic properties, which are size and orientation dependent.
Journal ArticleDOI

Quantum spin Hall effect in silicene and two-dimensional germanium.

TL;DR: It is demonstrated that silicene with topologically nontrivial electronic structures can realize the quantum spin Hall effect (QSHE) by exploiting adiabatic continuity and the direct calculation of the Z(2) topological invariant.
Journal ArticleDOI

Experimental Evidence for Epitaxial Silicene on Diboride Thin Films

TL;DR: It is shown that two-dimensional, epitaxial silicene forms through surface segregation on zirconium diboride thin films grown on Si wafers and that the buckling and thus the electronic properties of silicenes are modified by epitaxials strain.
Journal ArticleDOI

Low-energy effective Hamiltonian involving spin-orbit coupling in silicene and two-dimensional germanium and tin

TL;DR: In this article, the authors derived the low energy effective Hamiltonian involving spin-orbit coupling (SOC) for silicene, which is the analog to the graphene quantum spin Hall effect (QSHE) Hamiltonian.
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