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Germanene: a novel two-dimensional germanium allotrope akin to graphene and silicene

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TLDR
In this article, an atom-thin, ordered, two-dimensional multi-phase film was grown in situ through germanium molecular beam epitaxy using a gold surface as a substrate.
Abstract
We have grown an atom-thin, ordered, two-dimensional multi-phase film in situ through germanium molecular beam epitaxy using a gold (111) surface as a substrate. Its growth is similar to the formation of silicene layers on silver (111) templates. One of the phases, forming large domains, as observed in scanning tunneling microscopy, shows a clear, nearly flat, honeycomb structure. Thanks to thorough synchrotron radiation core-level spectroscopy measurements and advanced density functional theory calculations we can identify it as a ?3????3 R(30?) germanene layer in conjunction with a ?7????7 R(19.1?) Au(111) supercell, presenting compelling evidence of the synthesis of the germanium-based cousin of graphene on gold.

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Group IVB transition metal trichalcogenides: a new class of 2D layered materials beyond graphene

TL;DR: In this paper, the authors give an overview of the emerging area of 2D and 1D transition metal trichalcogenides and suggest future research directions related to these novel materials.
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High-pressure melt growth and transport properties of SiP, SiAs, GeP, and GeAs 2D layered semiconductors

TL;DR: In this article, the melting-growth of Germanium monopnictides SiP, SiAs, GeP, GeAs, and SiAs were successfully used as a precursor in the Chemical Vapor Transport growth of these compounds in the presence of I 2 as a transport agent.
Journal ArticleDOI

Emerging beyond-graphene elemental 2D materials for energy and catalysis applications.

TL;DR: In this article, the authors focus on the recent advances in emerging energy and catalysis applications based on beyond-graphene elemental 2D materials and discuss various applications in energy harvesting and storage, including solar cells, piezoelectric and nanogenerators.
Journal ArticleDOI

The super materials that could trump graphene.

Elizabeth Gibney
- 18 Jun 2015 - 
TL;DR: A wave of innovative flat materials is following in the wake of graphene - but the most exciting applications could come from stacking them into 3D devices.
Journal ArticleDOI

Interlayer coupling and electric field tunable electronic properties and Schottky barrier in a graphene/bilayer-GaSe van der Waals heterostructure

TL;DR: Using density functional theory, this work investigated systematically the electronic properties and Schottky barrier modulation in a multilayer graphene/bilayer-GaSe heterostructure by varying the interlayer spacing and by applying an external electric field.
References
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Journal ArticleDOI

Two- and one-dimensional honeycomb structures of silicon and germanium.

TL;DR: In this paper, first-principles calculations of structure optimization, phonon modes, and finite temperature molecular dynamics predict that silicon and germanium can have stable, two-dimensional, low-buckled, honeycomb structures.
Journal Article

Two- and one-dimensional honeycomb structures of silicon and germanium

TL;DR: First-principles calculations of structure optimization, phonon modes, and finite temperature molecular dynamics predict that silicon and germanium can have stable, two-dimensional, low-buckled, honeycomb structures, which show remarkable electronic and magnetic properties, which are size and orientation dependent.
Journal ArticleDOI

Quantum spin Hall effect in silicene and two-dimensional germanium.

TL;DR: It is demonstrated that silicene with topologically nontrivial electronic structures can realize the quantum spin Hall effect (QSHE) by exploiting adiabatic continuity and the direct calculation of the Z(2) topological invariant.
Journal ArticleDOI

Experimental Evidence for Epitaxial Silicene on Diboride Thin Films

TL;DR: It is shown that two-dimensional, epitaxial silicene forms through surface segregation on zirconium diboride thin films grown on Si wafers and that the buckling and thus the electronic properties of silicenes are modified by epitaxials strain.
Journal ArticleDOI

Low-energy effective Hamiltonian involving spin-orbit coupling in silicene and two-dimensional germanium and tin

TL;DR: In this article, the authors derived the low energy effective Hamiltonian involving spin-orbit coupling (SOC) for silicene, which is the analog to the graphene quantum spin Hall effect (QSHE) Hamiltonian.
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