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Germanene: a novel two-dimensional germanium allotrope akin to graphene and silicene

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TLDR
In this article, an atom-thin, ordered, two-dimensional multi-phase film was grown in situ through germanium molecular beam epitaxy using a gold surface as a substrate.
Abstract
We have grown an atom-thin, ordered, two-dimensional multi-phase film in situ through germanium molecular beam epitaxy using a gold (111) surface as a substrate. Its growth is similar to the formation of silicene layers on silver (111) templates. One of the phases, forming large domains, as observed in scanning tunneling microscopy, shows a clear, nearly flat, honeycomb structure. Thanks to thorough synchrotron radiation core-level spectroscopy measurements and advanced density functional theory calculations we can identify it as a ?3????3 R(30?) germanene layer in conjunction with a ?7????7 R(19.1?) Au(111) supercell, presenting compelling evidence of the synthesis of the germanium-based cousin of graphene on gold.

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Journal ArticleDOI

Unique Landau-level structure of monolayer black phosphorus under an exponentially decaying magnetic field.

TL;DR: The Landau-level spectrum of a monolayer black phosphorus under an exponentially decaying magnetic field along one spatial dimension shows that the crossing of some Landau levels apparently occurs, and the accidental degeneracy points between the levels for the conduction and valence bands are highly an isotropic due to the anisotropic effective masses in monolayers black phosphorus.
Journal ArticleDOI

Epitaxial growth of massively parallel germanium nanoribbons by segregation through Ag(1 1 0) thin films on Ge(1 1 0)

TL;DR: In this paper, the epitaxial growth of low-dimensional nanostructures formed by surface segregation of germanium on single crystalline Ag(1/1/0) thin films supported by a Ge(1 /1 /0) template was investigated.
Journal ArticleDOI

Rashba-type spin splitting and transport properties of novel Janus XWGeN2 (X = O, S, Se, Te) monolayers.

TL;DR: In this paper , the stability, electronic properties, and transport characteristics of asymmetric monolayers XWGeN2 (X = O, S, Se, Te) using ab initio density functional theory were discussed and examined.
Book ChapterDOI

Germanene, Stanene and Other 2D Materials

TL;DR: Germanene and stanene are 2D materials composed of germanium and tin atoms respectively arranged in a honeycomb structure similarly to graphene and silicene as mentioned in this paper, and the atomic structure of freestanding germanene and Stanene is buckled like in the case of Silicene.
Journal ArticleDOI

Blue shift in the interband optical transitions of gated monolayer black phosphorus

TL;DR: In this article, the anisotropic frequency-dependent optical conductivity of single-layer puckered phosphorene is studied, and also its dependence on the electrostatic gating of the top and bottom sublayers.
References
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Journal ArticleDOI

Two- and one-dimensional honeycomb structures of silicon and germanium.

TL;DR: In this paper, first-principles calculations of structure optimization, phonon modes, and finite temperature molecular dynamics predict that silicon and germanium can have stable, two-dimensional, low-buckled, honeycomb structures.
Journal Article

Two- and one-dimensional honeycomb structures of silicon and germanium

TL;DR: First-principles calculations of structure optimization, phonon modes, and finite temperature molecular dynamics predict that silicon and germanium can have stable, two-dimensional, low-buckled, honeycomb structures, which show remarkable electronic and magnetic properties, which are size and orientation dependent.
Journal ArticleDOI

Quantum spin Hall effect in silicene and two-dimensional germanium.

TL;DR: It is demonstrated that silicene with topologically nontrivial electronic structures can realize the quantum spin Hall effect (QSHE) by exploiting adiabatic continuity and the direct calculation of the Z(2) topological invariant.
Journal ArticleDOI

Experimental Evidence for Epitaxial Silicene on Diboride Thin Films

TL;DR: It is shown that two-dimensional, epitaxial silicene forms through surface segregation on zirconium diboride thin films grown on Si wafers and that the buckling and thus the electronic properties of silicenes are modified by epitaxials strain.
Journal ArticleDOI

Low-energy effective Hamiltonian involving spin-orbit coupling in silicene and two-dimensional germanium and tin

TL;DR: In this article, the authors derived the low energy effective Hamiltonian involving spin-orbit coupling (SOC) for silicene, which is the analog to the graphene quantum spin Hall effect (QSHE) Hamiltonian.
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