Palladium-catalyzed reactions of organic halides with olefins

doi:10.1021/AR50136A006

Journal ArticleDOI

Palladium-catalyzed reactions of organic halides with olefins

Richard F. Heck

- 01 Apr 1979 -

Accounts of Chemical Research

- Vol. 10, Iss: 37, pp 146-151

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This article is published in Accounts of Chemical Research.The article was published on 1979-04-01. It has received 818 citations till now. The article focuses on the topics: Palladium.

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Palladium-Mediated Three-Component Coupling Strategy for the Solid-Phase Synthesis of Tropane Derivatives(1).

Jong Sung Koh, +1 more

- 12 Jul 1996 -

Journal of Organic Chemistry

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Reactions of Cyclopalladated Benzylidene‐aniline Schiff's Base Complexes. Selective Synthesis of 2′‐Substituted Schiff's Base Derivatives and the X‐Ray Crystal Structure of the Dimer [Pd(μ‐OAc)(5′‐OCH3C6H3CHNC6H4‐4‐CH3)]2

Alberto Albinati, +2 more

- 13 Nov 1985 -

Helvetica Chimica Acta

TL;DR: In this paper, the X-ray crystal structure of [Pd(μ-OAc)(1a)]2 has been determined; relevant bond lengths [A] and bond angles [°] are: PdO(1), 2.139(6), PdN, 2.039(6, PdC(2′), 1.9(3), NPdO (1), 97.5(2), C(2')PdO, 91.7

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Mechanism and Kinetics of the Wacker Process: A Quantum Mechanical Approach

S. Ali Beyramabadi, +3 more

- 12 Mar 2008 -

Organometallics

TL;DR: This work has proposed a mechanism for nucleophilic addition which quantitatively and qualitatively will be in good agreement with the experimental evidence for the Wacker oxidation.

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Contributions to the Enantioselective Heck Reaction Using MeO−Biphep Ligands. The Case Against Dibenzylidene Acetone

Matthias Tschoerner, +2 more

- 27 Jan 1999 -

Organometallics

TL;DR: In this article, it was shown that the Pd-catalyzed enantioselective Heck reaction of p-XC6H4OTf, X = OMe, H, CO2Me, with dihydrofuran gives higher enanti-lectivities when the chelating diphosphine MeO−Biphep, 1a, is replaced with its disubstituted analogue 3,5-di-tert-butyl MeO+Biphesp, 2b, 1b.

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Pd-catalyzed C-C cross-coupling reactions within a thermoresponsive and pH-responsive and chelating polymeric hydrogel.

Yao Wang, +3 more

- 27 Jan 2009 -

Journal of Organic Chemistry

TL;DR: A porous, thermoresponsive and pH-responsive, and chelating hydrogel of poly(N-isopropylacrylamide)-co-poly[2-methacrylic acid 3-(bis-carboxymethylamino)-2-hydroxypropyl ester] (PNIPAM-co-PMACHE) is proposed as both a reaction medium and the Pd catalyst support for organic synthesis.

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