Palladium-catalyzed reactions of organic halides with olefins

doi:10.1021/AR50136A006

Journal ArticleDOI

Palladium-catalyzed reactions of organic halides with olefins

Richard F. Heck

- 01 Apr 1979 -

Accounts of Chemical Research

- Vol. 10, Iss: 37, pp 146-151

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This article is published in Accounts of Chemical Research.The article was published on 1979-04-01. It has received 818 citations till now. The article focuses on the topics: Palladium.

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Preparation of vinylogous 2-sulfonylindolines by the palladium-catalyzed heteroannulation of o-iodoanilines with dienyl sulfones and their further transformation to indoles and carbazoles.

Thomas G. Back, +3 more

- 15 Nov 2001 -

Journal of Organic Chemistry

TL;DR: The palladium-catalyzed heteroannulation of o-iodoanilines with dienyl sulfones provides a convenient route to vinylogous 2-sulfonylindolines and provides access to carbazoles with various substituents at the 3-, 4-, and 6-positions.

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TL;DR: An efficient iminyl radical-triggered 1,5-hydrogen-atom transfer/Heck-type coupling cascade has been achieved through visible-light photoredox catalysis, providing an elegant route to γ-alkenylated ketone.

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Palladium-Catalyzed Mizoroki-Heck-Type Alkenylation of Monoaryldialkylsulfoniums.

Daisuke Uno, +4 more

- 04 Sep 2018 -

Chemistry-an Asian Journal

TL;DR: Mizoroki-Heck-type alkenylation of monoaryldialkylsulfoniums has been accomplished by means of palladium catalysts through one-pot alkenYLation of aryl methyl sulfide.

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Palladium-catalyzed regioselective Heck arylation of electron-rich olefins in a molecular solvent-ionic liquid cocktail

Jun Mo, +2 more

- 10 Oct 2005 -

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TL;DR: In this article, it was shown that the benchmark electron-rich olefins vinyl ethers can be readily arylated by aryl bromides in a molecular solvent-ionic liquid cocktail with no compromise on regioselectivity.

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Inhibitory effect of cytotoxic stilbenes related to resveratrol on the expression of the VEGF, hTERT and c-Myc genes.

Rosa Martí-Centelles, +4 more

- 20 Oct 2015 -

European Journal of Medicinal Chemistry

TL;DR: One of the synthetic stilbenes, (E)-4-(4-methoxystyryl)aniline, showed strong cytotoxicity and proved able to cause a marked decrease both in the secretion of VEGF and in the expression of the hTERT and c-Myc genes, in all cases at concentrations in the low nanomolar range.

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